Investigation on Ligand Exchange Kinetics on CdSe/ZnS Quantum Dot Surface Utilizing Pyrene as Flourescent Probe

doi:10.1007/s40242-015-5110-6

Chemical Research in Chinese Universities ›› 2015, Vol. 31 ›› Issue (4): 514-518.doi: 10.1007/s40242-015-5110-6

• Articles • Previous Articles Next Articles

Investigation on Ligand Exchange Kinetics on CdSe/ZnS Quantum Dot Surface Utilizing Pyrene as Flourescent Probe

CHANG Yulei^1,3, LIU Nian², LIU Huan¹, YANG Yanming⁴, ZHAO Yili¹, LI Yapeng¹, YUAN Hang²

1. Alan G. MacDiarmid Institute, College of Chemistry, Jilin University, Changchun 130012, P. R. China;
2. The First Hospital of Jilin University, Changchun 130021, P. R. China;
3. State Key Laboratory of Luminescence and Applications, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun 130033, P. R. China;
4. The Second Hospital of Jilin University, Changchun 130041, P. R. China

Received:2015-03-20 Revised:2015-04-21 Online:2015-08-01 Published:2015-07-22
Contact: LI Yapeng, YUAN Hang E-mail:liyapeng@jlu.edu.cn;hangyuan75@foxmail.com
Supported by:
Supported by the National Natural Science Foundation of China (No.21304084), the Youth Foundation of Jilin Province, China(No.20080119) and the Graduate Innovation Program of Jilin University, China(No.20091010).

Abstract

Abstract:

Direct ligand exchange kinetics between hydrophilic molecules and quantum dots(QDs) was investigated. Meanwhile, pyrene was exploited as probe to detect the efficiency of the ligand exchange reaction between octadecylamine-coated QDs(ODA-QDs) and different ligands[ligand 1: NH₂G3-OH, ligand 2: G4.5-PEG5-FA5, ligand 3: (COOH)₂G3-OH or ligand 4: G4.5-PEG1-FA1]. It was indicated that water-soluble QDs exhibit the same fluorescence and absorption spectra as ODA-QDs when they were dissolved in chloroform. Furthermore, the cellular experiments demonstrated that the folic acid(FA) targeting poly(amidoamine)(PAMAM) modified QD conjugates could be used as molecular targeting sensing systems for nanoparticle probes.

Key words: Fluorescent probe, Ligand exchange kinetic, Poly(amidoamine) dendrimer, Pyrene, Quantum dot

CHANG Yulei, LIU Nian, LIU Huan, YANG Yanming, ZHAO Yili, LI Yapeng, YUAN Hang. Investigation on Ligand Exchange Kinetics on CdSe/ZnS Quantum Dot Surface Utilizing Pyrene as Flourescent Probe[J]. Chemical Research in Chinese Universities, 2015, 31(4): 514-518.

References

[1] Michalet X., Pinaud F. F., Bentolila L.A ., Tsay J. M., Doose J. J., Li G., Sundaresan A. M., Wu S. S., Gambhir S., Weiss S., J. Polym. Sci., 2005, 307, 538
[2] Chan W. C. W., Nie S., J. Polym. Sci., 1998, 281, 2016
[3] Alivisatos A. P., Gu W., Larabell C., Annu. Rev. Biomed. Eng., 2005, 7, 55
[4] Xu Y. D., Zhang Z. Y., Kong J. L., Li G. D., Xiong H. M., Chem. J. Chinese Universities., 2013, 34(7), 1565
[5] Murray C. B., Norris D. J., Bawendi M. G., J. Am. Chem. Soc., 1993, 115, 8706
[6] Talapin D. V., Rogach A. L., Kornowski A., Haase M., Weller H., Nano Lett., 2001, 1, 207
[7] Zhao Y., Li Y., Song Y., Jiang W., Wu Z., Wang Y. A., Sun J., Wang J., J. Colloid Interface Sci., 2009, 339, 336
[8] Dubois F., Mahler B., Dubertret B., Doris E., Mioskowski C., J. Am. Chem. Soc., 2007,129, 482
[9] Zhao Y., Liu S., Li Y., Jiang W., Chang Y., Pan S., Fang X., Wang Y. A., Wang J., J. Colloid Interface Sci., 2010, 350, 44
[10] Wang Y. A., Li J. J., Chen H., Peng X., J. Am. Chem. Soc., 2002, 124, 2293
[11] Liu Y., Kim M., Wang Y., Wang Y. A., Peng X., Langmuir, 2006, 22, 6341
[12] Duan H., Nie S., J. Am. Chem. Soc., 2007, 129, 3333
[13] Guo W., Li J. J., Wang Y. A., Peng X., Chem. Mater., 2003, 15, 3125
[14] Wilhelm M., Zhao C., Wang W., Xu R., Winnik M. A., Macromolecules, 1991, 24, 1033
[15] Ringsdorf H., Venzmer J., Winnik F. M., Macromolecules, 1991, 24, 1678
[16] Tomalia D. A., Baker H., Dewald J., Hall M., Kallos G., Martin S., Roeck J., Ryder J., Smith P., Polym. J., 1985, 17, 117
[17] Tomalia D. A., Naylor A. M., Gaddard W. A., Angew. Chem. Int. Ed. Engl., 1990, 29, 138
[18] Li J. J., Wang Y. A., Guo W., Keay J. C., Mishima T. D., Johnson M. B., Peng X., J. Am. Chem. Soc., 2003, 125, 12567
[19] Duan H. W., Kuang M.., Wang X. X., Wang Y. A., Mao H., Nie S. M., J. Phys. Chem. C, 2008, 112, 8127
[20] Sahu A., Bora U., Kasoju N., Goswami P., Acta Biomaterialia, 2008, 4, 1752
[21] Corona G., Giannini F., Fabris M., Toffoli G., Boiocchi M., Int. J. Cancer, 1998, 75, 125

Investigation on Ligand Exchange Kinetics on CdSe/ZnS Quantum Dot Surface Utilizing Pyrene as Flourescent Probe

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	WANG Bingya, GUO Xiaomei, LIU Zuodong, WU Yongquan, HOU Ji-Ting. A Long-wavelength Emissive Phenothiazine Derived Fluorescent Probe for Detecting HOCl Upregulation in 5-FU Stimulated Living Cells [J]. Chemical Research in Chinese Universities, 2022, 38(2): 609-615.
[2]	LI Mingfeng, FANG Hongbao, JI Yifan, CHEN Yuncong, HE Weijiang, GUO Zijian. Rational Design of Ratiometric Fe³⁺ Fluorescent Probes Based on FRET Mechanism [J]. Chemical Research in Chinese Universities, 2022, 38(1): 67-74.
[3]	AN Qingqing, JIANG Yanglin, HE Huan, GAO Juan, WANG Peng, JIA Zhiyu. Architecting Pyrenyl-graphdiyne Nanowalls for High Capacity and Long-life Lithium Storage [J]. Chemical Research in Chinese Universities, 2021, 37(6): 1323-1327.
[4]	PAN Quan, MA Feiyan, PU Xinqing, ZHAO Manyi, WU Qiling, ZHAO Na, YANG Jun, TANG Ben Zhong. A Novel Fluorescent Probe for ATP Detection Based on Synergetic Effect of Aggregation-induced Emission and Counterion Displacement [J]. Chemical Research in Chinese Universities, 2021, 37(1): 166-170.
[5]	LI Long, HUANG Yan, ZHAO Pei, MIAO Haochi, ZHAO Ting. Deep Eutectic Solvent-assisted Synthesis of Nitrogen-doped Carbon Quantum Dots for Cell Imaging [J]. Chemical Research in Chinese Universities, 2020, 36(5): 955-961.
[6]	WANG Chengke, TAN Rong, LI Libo, LIU Dong. Dual-modal Colorimetric and Fluorometric Method for Glucose Detection Using MnO₂ Sheets and Carbon Quantum Dots [J]. Chemical Research in Chinese Universities, 2019, 35(5): 767-774.
[7]	ZOU Xiaohu, WEI Zhizhi, DU Jing, WANG Xiaotao, ZHANG Gaowen. Preparation and Properties of Magnetic-fluorescent Microporous Polymer Microspheres [J]. Chemical Research in Chinese Universities, 2018, 34(4): 684-690.
[8]	XUE Longqi, FENG Yusha, SONG Yan, WANG Rui, LIU Dahai, DU Jianshi, YANG Qingbiao, LI Yaoxian. A Highly Selective and Sensitive Ratiometric Fluorescent Probe for Hypochlorite and Its Application [J]. Chemical Research in Chinese Universities, 2018, 34(4): 536-540.
[9]	MI Zhiming, CHEN Yao, CHEN Xiaodong, YAN Liuqing, GU Qiang, ZHANG Hanqi, CHEN Chunhai, ZHANG Yumin. Synthesis of Highly Sensitive Fluorescent Probe Based on Tetrasubstituted Imidazole and Its Application for Selective Detection of Ag⁺ Ion in Aqueous Media [J]. Chemical Research in Chinese Universities, 2018, 34(3): 369-374.
[10]	WANG Yan'en, LI Xueyan, CHEN Hua, ZHU Mengyuan, LI Xiaoliu. Synthesis of Bisboronic Acids and Their Selective Recognition of Sialyl Lewis X Antigen [J]. Chemical Research in Chinese Universities, 2018, 34(3): 415-422.
[11]	SU Anmei, WANG Di, SHU Xin, ZHONG Qingmei, CHEN Yongren, LIU Jiachen, WANG Yilin. Synthesis of Fluorescent Carbon Quantum Dots from Dried Lemon Peel for Determination of Carmine in Drinks [J]. Chemical Research in Chinese Universities, 2018, 34(2): 164-168.
[12]	ZHOU Xuejiao, XU Liangyou. Insight into the Reaction Mechanism of Graphene Oxide with Oxidative Free Radical [J]. Chemical Research in Chinese Universities, 2017, 33(5): 689-694.
[13]	FANG Xiaoxing, ZHENG Ji, YAN Guiqin. A Convenient “Turn On-off” Phosphorescent Nanosensor for Detection of Biotin Based on Quantum Dots/CTAB [J]. Chemical Research in Chinese Universities, 2016, 32(6): 917-923.
[14]	CHEN Jiayi, SHU Wei, WANG Enju. A Fluorescent and Colorimetric Probe Based on Isatin-appended Rhodamine for the Detection of Hg²⁺ [J]. Chemical Research in Chinese Universities, 2016, 32(5): 742-745.
[15]	TANG Xiaojian, WANG Jianhui, ZHAO Ke, XUE Honghai, TA Chunhong. A Simple and Rapid Label-free Fluorimetric “Turn Off-on” Sensor for Cadmium Detection Using Glutathione-capped CdS Quantum Dots [J]. Chemical Research in Chinese Universities, 2016, 32(4): 570-575.