Crystal Structure of a Novel Supramolecule Made Up of Bis(μ2-aqua)aqua(3-carboxy acrylate) monosodium(Ⅰ)

Chemical Research in Chinese Universities ›› 2002, Vol. 18 ›› Issue (3): 249-251.

• Articles • Previous Articles Next Articles

Crystal Structure of a Novel Supramolecule Made Up of Bis(μ₂-aqua)aqua(3-carboxy acrylate) monosodium(Ⅰ)

YUAN Ji-xin, HU Mao-lin, CHEN Di-mei, CHEN Li-chun

Department of Chemistry, Wenzhou Normal College, Wenzhou 325003, P. R. China

Received:2002-02-05 Online:2002-08-24 Published:2011-08-04
Supported by:
Supported by the Education Commission of Zhejiang Province(No.20010129) and "551" Distinguished Person Foundation of Wenzhou.

Abstract

Abstract: The title compound, bis(μ₂-aqua)(aqua)(3-carboxy acrylate) monosodium(Ⅰ), was synthesized in an ethanol-water solution and its crystal structure was determined by means of X-ray diffraction. The crystal is triclinic, space group P1 with the cell parameters a=0.592 4(2) nm, b=0.635 7(3) nm, c=1.117 7(6) nm, α=104.18°, β=91.53°, γ=100.19°, V=0.400 6(3) nm³, Z=2, the final R value is 0.033 5. The supramolecule is made up of coordination chains, which are further extended into a three-dimensional network via the hydrogen bonding interactions.

Key words: 3-Carboxy acrylate monosodium(Ⅰ), Chain, Intramolecular hydrogen, Supramolecule

YUAN Ji-xin, HU Mao-lin, CHEN Di-mei, CHEN Li-chun. Crystal Structure of a Novel Supramolecule Made Up of Bis(μ₂-aqua)aqua(3-carboxy acrylate) monosodium(Ⅰ)[J]. Chemical Research in Chinese Universities, 2002, 18(3): 249-251.

[1]	LI Yujie, CHEN Jie, DONG Yuanchen, LIU Huajie, LIU Dongsheng. Construction of pH-Triggered DNA Hydrogels Based on Hybridization Chain Reactions [J]. Chemical Research in Chinese Universities, 2020, 36(2): 243-246.
[2]	QIU Qiming, SUN Kening, YANG Guoyu. Two New Alkaline Metal Borates with Supramolecular Framework Constructed from 1D {B₅}/{B₆} Helical Chains [J]. Chemical Research in Chinese Universities, 2020, 36(1): 86-90.
[3]	DONG Yanying, YU Ping, SUN Qilong, LU Yang, TAN Zhenjiang, YU Xiaopeng. Grafting of MIPs from PVDF Membranes via Reversible Addition-fragmentation Chain Transfer Polymerization for Selective Removal of p-Hydroxybenzoic Acid [J]. Chemical Research in Chinese Universities, 2018, 34(6): 1051-1057.
[4]	ZHANG Hongmei, LIU Yan, MA Fangping, QIU Wei, LEI Bo, SHEN Jinyou, SUN Xiuyun, HAN Weiqing, LI Jiansheng, WANG Lianjun. Density Functional Theoretical Studies on Effect of Intramolecular Hydrogen Bonds on Reduction of Nitrophenols [J]. Chemical Research in Chinese Universities, 2017, 33(5): 785-793.
[5]	WANG Xiang, LIN Lin, LIN Hongyan, LIU Guocheng. Syntheses, Structure and Properties of a 3d-4d/2-ptz Heterometallic Organic Chain-modified POM-based Framework [J]. Chemical Research in Chinese Universities, 2017, 33(1): 7-11.
[6]	GAI Beibei, HE Hui, ZHAO Yanhui, MAO Zhu, FU Hai. Ionothermal Synthesis and Characterization of Two Polyoxometalate-based Supramolecules [J]. Chemical Research in Chinese Universities, 2016, 32(4): 527-529.
[7]	ZHAO Yanping, ZHAO Jingbo, ZHANG Zhiyuan, ZHANG Junying. Aliphatic Segmented Poly(ether ester amide)s Synthesized from Hexanediamine, Sebacic Acid and Poly(ethylene glycol)s [J]. Chemical Research in Chinese Universities, 2016, 32(3): 505-511.
[8]	YU Jingfeng, LI Zhiying, LIU Xiaoli, SONG Sanan, GAO Ge, ZHANG Qing, LIU Fengqi. Molecular Size and Morphology of Single Chains of Poly(sulfobetaine methacrylate) [J]. Chemical Research in Chinese Universities, 2016, 32(3): 499-504.
[9]	WANG Jing, LUO Xiaolong, YUAN Yang, ZHANG Lirong. Assembly of Two Coordination Polymers Based on 2,2'-Bipyridyl-4,4'-dicarboxylic Acid Ligand [J]. Chemical Research in Chinese Universities, 2015, 31(4): 503-507.
[10]	LIU Duo, CAI Shuanglian, LUAN Fangjian, WANG Qiu'an. Synthesis of Long Chain Fatty Acids Acylated Coumarin Glycoside Esters with Lipase as Catalyst [J]. Chemical Research in Chinese Universities, 2015, 31(4): 534-538.
[11]	LIANG Zi, GAO Tingting, XU Jianan, LI Zhiying, LIU Xiaoli, LIU Fengqi. Mechanical Properties and Network Structure of Hydrophobic Association Hydrogels Prepared from Octylphenol Polyoxyethylene(7) Acrylate and Sodium Dodecyl Sulfate [J]. Chemical Research in Chinese Universities, 2015, 31(4): 633-639.
[12]	YANG Xu, DU Fei, BIE Xiaofei, LI Malin, ZHANG Rongyu, WEI Yingjin, WANG Chunzhong, CHEN Gang. Effect of Nonmagnetic Impurity Doped on the Structural and Magnetic Properties of Quasi-one-dimensional Antiferromagnet LiCuVO₄ [J]. Chemical Research in Chinese Universities, 2015, 31(3): 457-460.
[13]	HAO Jiaojiao, LI Shushi, JIANG Xiaonan, HUANG Cuiying, WANG Changsheng. Rapid Evaluation of Individual Hydrogen Bonding Energies in Linear Water Chains [J]. Chemical Research in Chinese Universities, 2014, 30(3): 447-454.
[14]	SUN Huiyun, YIN Tiao, LI Yue, ZHAO Jingbo, ZHANG Zhiyuan, ZHANG Junying. Synthesis and Characterization of Biodegradable Alternating Polyesteramides from Mixed Diamidediols and Sebacic Acid [J]. Chemical Research in Chinese Universities, 2014, 30(1): 168-175.
[15]	LIU Gui-hua, QIU Xue-peng, SIDDIQ Mohammad, BO Shu-qin, JI Xiang-ling. Temperature Dependence of Chain Conformation and Local Rigidity of Isomerized Polyimides in Dimethyl Formamide [J]. Chemical Research in Chinese Universities, 2013, 29(5): 1022-1028.

Crystal Structure of a Novel Supramolecule Made Up of Bis(μ₂-aqua)aqua(3-carboxy acrylate) monosodium(Ⅰ)

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments