Grafting of MIPs from PVDF Membranes via Reversible Addition-fragmentation Chain Transfer Polymerization for Selective Removal of p-Hydroxybenzoic Acid

doi:10.1007/s40242-018-8146-6

Chemical Research in Chinese Universities ›› 2018, Vol. 34 ›› Issue (6): 1051-1057.doi: 10.1007/s40242-018-8146-6

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Grafting of MIPs from PVDF Membranes via Reversible Addition-fragmentation Chain Transfer Polymerization for Selective Removal of p-Hydroxybenzoic Acid

DONG Yanying^1,2, YU Ping^1,2, SUN Qilong³, LU Yang^1,2, TAN Zhenjiang^1,2, YU Xiaopeng^1,2

1. School of Computer Science, Jilin Normal University, Siping 136000, P. R. China;
2. Key Laboratory of Numerical Simulation of Jilin Province, Jilin Normal University, Siping 136000, P. R. China;
3. School of Management, Jilin Normal University, Siping 136000, P. R. China

Received:2018-05-04 Online:2018-12-01 Published:2018-11-12
Contact: YU Ping E-mail:jlsdyp@126.com
Supported by:
Supported by the National Natural Science Foundation of China(No.21606099), the Natural Science Foundation of Jilin Province, China(No.20180623042TC) and the Science and Technology Research Foundation of the Department of Education of Jilin Province, China(Nos.JJKH20180782KJ, JJKH20180761KJ, JJKH20170376KJ).

Abstract

Abstract: Effective molecularly imprinted membranes(MIMs) were developed as an efficient adsorbent for the selective removal of p-hydroxybenzoic acid(p-HB) from acetylsalicylic acid(ASA, aspirin). The MIMs were grafted successfully from poly(vinylidene fluoride) microfiltration membranes via reversible addition-fragmentation chain transfer(RAFT) polymerization. The graft copolymerization of acrylic acid(AA) in the presence of template p-hydroxybenzoic acid led to molecularly imprinted polymer(MIP) film coated membranes. The obtained MIMs were characterized by scanning electron microscopy(SEM), Fourier transform infrared spectrophotometer(FTIR) and Raman spectra, and batch mode adsorption studies were carried out to investigate the specific adsorption equilibrium, kinetics and selective recognition properties of different MIMs. The kinetic properties of the MIMs could be well described by the pseudo-second-order rate equation. Selective permeation experiments were performed to evaluate the permeation selectivity of the p-HB imprinted membranes. The observed performances of the MIMs are applicable to the further purification of aspirin.

Key words: Acetylsalicylic acid, Reversible addition-fragmentation chain transfer, Molecularly imprinted membrane, p-Hydroxybenzoic acid, Selective adsorption

DONG Yanying, YU Ping, SUN Qilong, LU Yang, TAN Zhenjiang, YU Xiaopeng. Grafting of MIPs from PVDF Membranes via Reversible Addition-fragmentation Chain Transfer Polymerization for Selective Removal of p-Hydroxybenzoic Acid[J]. Chemical Research in Chinese Universities, 2018, 34(6): 1051-1057.

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Grafting of MIPs from PVDF Membranes via Reversible Addition-fragmentation Chain Transfer Polymerization for Selective Removal of p-Hydroxybenzoic Acid

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