Crystal Structure and Characterization of a Dye with Two-photon Pumoed Frequency-upconverted Lasing Properties

Chemical Research in Chinese Universities ›› 2002, Vol. 18 ›› Issue (2): 211-215.

• Articles • Previous Articles Next Articles

Crystal Structure and Characterization of a Dye with Two-photon Pumoed Frequency-upconverted Lasing Properties

TIAN Yu-peng^1,2, YU Wen-tao³, FANG Qi³, WU Jie-ying^1,2, JIANG Min-hua³, WANG He-zhou⁴, ZHENG Xi-guang⁴

1. Department of Chemistry, Anhui University, Hefei 230039, P. R. China;
2. State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, P. R. China;
3. Institute of Crystal Materials, State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, P.R. China;
4. Institute for Laser and Spectroscopy, Zhongshan University, Guangzhou 510275, P. R. China

Received:2000-04-04 Online:2002-04-24 Published:2011-08-04
Supported by:
Supported by Grant for State Key Program of China and the National Natural Science Foundation of China (No.29871001).

Abstract

Abstract: The title compound, trans-4-[ p-( N-ethyl-N-(hydroxyethyl ) amino) styryl ]-N-methylpyridiniumtetraphenylborate (abbreviated as ESMT, C₄₆H₄₉N₄O) crystallizes in a space group P1 with a= 0.983 23 (15)nm, b=1.410 73(16) nm, c=1.54 21(12) nm, a=95.252(13)°, β=91.959(17)°, γ= 107.421(12)°, Z=2, F(000)=712, μ= 0.1 mm^-1 Mo Ka radiation, R=0. 093 8. The result shows that the cation of themolecule almost lies in one plane, the hydroxyethyl group is perpendicular to the plane, the anion takes a slightdistorted tetrahedral geometry. Also the thermal stability, two-photon fluorescence, two-photon pumped lasingproperty for the title compound were studied.

Key words: Crystal structure, Methylpyridinium salt, Two-photon pumped lasing property

TIAN Yu-peng, YU Wen-tao, FANG Qi, WU Jie-ying, JIANG Min-hua, WANG He-zhou, ZHENG Xi-guang. Crystal Structure and Characterization of a Dye with Two-photon Pumoed Frequency-upconverted Lasing Properties[J]. Chemical Research in Chinese Universities, 2002, 18(2): 211-215.

[1]	HUA Chen, YI Pin, LIU Wencong, WANG Mengfan, NIU Zheng, LANG Jianping. Coordination Polymers with Bipyridyl Diene and Triene Ligands: Synthesis, Structures and Luminescent Properties [J]. Chemical Research in Chinese Universities, 2022, 38(1): 209-216.
[2]	ZHANG Wenqi, LIN Zhengguo, CHI Yingnan, HONG Jie, YAN Li, HU Changwen. Assembly of Three Scandium-containing Heteropolytungstates Based on a Building-block Synthetic Strategy [J]. Chemical Research in Chinese Universities, 2020, 36(6): 1161-1167.
[3]	ZANG Jiahe, ZHANG Qing'an, SUN Dalin. Crystal Structures and Electrochemical Properties of R_1.5Ca_1.5MgNi₁₄(R=Nd, Gd and Er) Hydrogen Storage Alloys [J]. Chemical Research in Chinese Universities, 2019, 35(6): 1040-1045.
[4]	WANG Dongmei, LOU Shengjun, YING Yiting, GUO Zhiqi, WANG Lijun. Assembly of Two Isostructural Metal-organic Frameworks Based on Hetero-N,O Donor Ligand for Detecting Nitro Explosives [J]. Chemical Research in Chinese Universities, 2019, 35(5): 762-766.
[5]	MA Xiao, WANG Xiaohong, SHANG Fan, DING Zimei, HANG Xiaojing, HUANG Jie. Studies on 3-Amino-4-(1H-tetrazol-5-yl)-furazan: Crystal Structure, Thermal Behavior and Energetic Performance [J]. Chemical Research in Chinese Universities, 2019, 35(5): 848-853.
[6]	ZHONG Liangxuan, LIU Mingyue, ZHANG Bowei, SUN Yaqiu, XU Yanyan. Syntheses, Crystal Structures, Magnetic and Near-infrared Luminescence Properties of 3d-4f Coordination Polymers Cu₂Pr₂, Cu₂Eu₂ and Cu₄Tb₂ [J]. Chemical Research in Chinese Universities, 2019, 35(4): 693-699.
[7]	YU Yanzhao, CAO Jiapeng, XU Yan. Two Pentavanadate-based Organic-inorganic Materials with Third-order NLO Properties [J]. Chemical Research in Chinese Universities, 2019, 35(1): 1-4.
[8]	DING Zimei, CAO Wenli, ZHENG Hui, HUANG Jie, XU Kangzhen, SONG Jirong. Synthesis, Structure Characteristic and Thermal Behavior of Two New Metal-organic Azo-triazole Compounds: [Zn(phen)₃]·ZTO·6H₂O and[Cu(phen)₃]·ZTO·6H₂O [J]. Chemical Research in Chinese Universities, 2018, 34(6): 1009-1013.
[9]	CHEN Xiang, ZENG Tian, ZHANG Cong, GUO Zhaoqi, LI Shuailei, MAI Tao, GAO Rong, MA Haixia. Crystal Structures, Thermal Behavior Analysis and Thermal Safety of Two Energetic Salts of Hydrazinyl-1,2,4,5-tetrazine with 3,5-Dinitrosalicylic Acid [J]. Chemical Research in Chinese Universities, 2018, 34(6): 959-964.
[10]	LIU Chao, LIU Yijie, ZHANG Lili, JIANG Kun, ZHANG Li. Two Coordination Compounds Bearing Bis(2-dimethylaminoethyl) Ether: Syntheses, Crystal Structures and Catalytic Application to the Henry Reaction [J]. Chemical Research in Chinese Universities, 2018, 34(3): 358-362.
[11]	WANG Jingyang, ZHANG Meng, XU Xiaodong, FENG Jing, WANG Yanli, ZHANG Milin, HAN Wei, CHEN Yitung, TIAN Guoxin. Synthesis and Characterization of [Cu(N-MeIm)₄(BF₄)₂] in Ionic Liquid [J]. Chemical Research in Chinese Universities, 2018, 34(1): 8-12.
[12]	ZHOU Jinhua, LI Jingjing, LI Jie, REN Guoyu, REN Yinghui, MA Haixia. Structure and Enhanced Antifungal Activity of a Divalent Cobalt(II) Complex with Hexaconazole [J]. Chemical Research in Chinese Universities, 2017, 33(6): 864-868.
[13]	WANG Xiang, LIN Lin, LIN Hongyan, LIU Guocheng. Syntheses, Structure and Properties of a 3d-4d/2-ptz Heterometallic Organic Chain-modified POM-based Framework [J]. Chemical Research in Chinese Universities, 2017, 33(1): 7-11.
[14]	HE Yuanchun, GUO Jiao, XU Na, YU Yang. Assembly of Five Coordination Polymers Based on 5,11,17,23-Tetra-tert-butyl-25-(carboxymethoxy)-calix[4]arene Ligand [J]. Chemical Research in Chinese Universities, 2017, 33(1): 44-48.
[15]	YAN Xia, ZHANG Jianxin. Copper(II) Complexes Based on 4'-R-Terpyridine: Synthesis, Structures, and Photocatalytic Properties [J]. Chemical Research in Chinese Universities, 2017, 33(1): 1-6.

Crystal Structure and Characterization of a Dye with Two-photon Pumoed Frequency-upconverted Lasing Properties

PDF (PC)

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments