Synthesis, X-ray Structure and Spectral Propertiesof a Tetra-component Heteropoly Compound

Chemical Research in Chinese Universities ›› 1994, Vol. 10 ›› Issue (3): 227-235.

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Synthesis, X-ray Structure and Spectral Propertiesof a Tetra-component Heteropoly Compound

ZHANG Heng-bin¹, YANG Guang-di¹, QI Xing-yi¹, LI Shu-jia¹, XU Shan-peng²

1. Department of Chemistry, Jilin University, Changchun, 130023;
2. Department of chemistry, Heilongjiang University, Harbin, 150080

Received:1993-09-25 Online:1994-08-24 Published:2011-08-17

Abstract

Abstract: The single crystal of a tetra-component heteropoly compound Mo₂Co₃O₆₈(H₂O₂)₂ ] [MoO₆]·15(H₂O) was obtained in an aqueous solution with Na₂MoO₄, Na₂WO₄, Co (NO₃)₂ and H₃PO₄ as starting materials.The erystallo-graphic data determined by means of X-ray diffraction analysis are: triclinic sys-tem,space group Pl ,Z= 2:a =1.9227(9) nm,b=1.9359(7)nm, c=1.2565(3)nm .a = 91.43 (3), The Differential thermal and thermogravimetric analysis indicated the thermal stbility of the compound and its spectral properties were characterized by IR and XPS measurements .

Key words: Heteropoly compound, P-W-Mo-Co system, Synthesis, Structure

ZHANG Heng-bin, YANG Guang-di, QI Xing-yi, LI Shu-jia, XU Shan-peng. Synthesis, X-ray Structure and Spectral Propertiesof a Tetra-component Heteropoly Compound[J]. Chemical Research in Chinese Universities, 1994, 10(3): 227-235.

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Synthesis, X-ray Structure and Spectral Propertiesof a Tetra-component Heteropoly Compound

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