A Two-dimensional Covalent Organic Framework for Iodine Adsorption

doi:10.1007/s40242-022-1513-3

Abstract

Abstract: Radioactive iodine is a notorious pollutant in gas radioactive nuclear waste due to its radiation hazard, volatility, chemical toxicity, and high mobility. Therefore, developing a material with high efficiency-specific iodine capture is significant. Covalent organic framework(COF) has attracted significant attention as a new crystalline porous organic material. Due to its large specific surface and high chemical stability, it is an excellent alternative to adsorbents. Herein, we report a chemically stable two-dimensional COF(termed JUC-609) with specific adsorption of iodine. Adsorption experiments show that JUC-609 has an excellent iodine adsorption capacity as high as 5.9 g/g under 353 K and normal pressure condition, and iodine adsorption after multiple cycles is still maintained. Our study thus promotes the potential application of COFs in the field of environment-related applications.

Key words: Porous material, Covalent organic framework, Iodine adsorption, Mesoporous structure

ZHANG Jianhui, LIU Jianchuan, LIU Yaozu, WANG Yujie, FANG Qianrong, QIU Shilun. A Two-dimensional Covalent Organic Framework for Iodine Adsorption[J]. Chemical Research in Chinese Universities, 2022, 38(2): 456-460.

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