A New Tubular Borate Built by[B14O24(OH) 6]12- Cluster Units

doi:10.1007/s40242-021-1183-6

Abstract

Abstract: Anew mixed alkali and alkaline-earth metal borate Na₄Ca₂[B₁₄O₂₂(OH)₆]·2H₂O(1) has been made under a mild solvothermal condition and characterized by single-crystal X-ray diffraction, infrared(IR) spectroscopy, UV-Vis diffuse reflectance spectroscopy, powder X-ray diffraction and thermogravimetric analysis, respectively. Compound 1 features a 1D tube based on[B₁₄O₂₄(OH)₆]^12-({B₁₄}-1) oxo-boron clusters. Such a tube built by {B₁₄}-1 units has been discovered for the first time in borate system. These tubes are arranged orderly to generate 2D layers and a further 3D supramolecular network through hydrogen bond interactions. UV-Vis diffuse reflectance spectrum reveals that compound 1 is a wide band-gap semiconductor and has potential application in UV region.

Key words: Alkali and alkaline-earth metal, Borate, Tube, Solvothermal synthesis, Cluster

SUN Xiao-Shuang, QIN Dan, LI Xu-Yan, YANG Guo-Yu. A New Tubular Borate Built by[B₁₄O₂₄(OH) ₆]^12- Cluster Units[J]. Chemical Research in Chinese Universities, 2022, 38(1): 123-127.

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A New Tubular Borate Built by[B₁₄O₂₄(OH) ₆]^12- Cluster Units

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