Chemical Research in Chinese Universities ›› 1991, Vol. 7 ›› Issue (1): 18-21.

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Synthesis and Properties of Dinuclear Cu(Ⅱ) Complexes Derived from Oxamidobis(propionato)cuprate(Ⅱ)

Liao Daizheng, Lin Bing, Wang Genglin   

  1. Department of Chemistry, Nankai University, Tianjin
  • Received:1990-08-25 Online:1991-01-24 Published:2011-09-09
  • Supported by:

    Supported by the National Natural Science Foundation of China

Abstract: Three dinuclear complexes were synthesized and designated as Cu(obp)CuL where obp =oxamidobis(propionato), L=2,2'-bipyridyl(bpy) (1), 1 , 10-phenathroline(phen)(2) and 5-nitro-1, 10-phenathroline(NO2-phen)(3). The complexes were characterized by elemental analyses, in fared and electronic spectra, magnetic susceptibilities and ESR spectra, indicating antiferromagnetic spin exchange interactions between metal ions.

Key words: Oxamido bridge, Dicopper complex, Magnetic property