A Multifunctional {P2Mo5}-based Hybrid Applying to Catalysis, Electrocatalysis and Dye Adsorption

doi:10.1007/s40242-022-2129-3

Abstract

Abstract: As a common environmental pollutant, thioether can cause serious environmental pollution, so selective oxidation of thioether has become one of the current research hotspots. In this paper, an inorganic-organic hybrid based on a Standberg-type polyoxometalate,[Hbiz]₅[HP₂Mo₅O₂₃]·5H₂O(1)(biz=benzimidazole), was obtained by adjusting pH under hydrothermal conditions. The structure was characterized by infrared spectroscopy, thermogravimetric analysis, and single-crystal X-ray diffraction. Compound 1 can be used as an excellent catalyst for the oxidation of thioanisole. The experimental results showed that thioanisole could be catalytically oxidized to methyl phenyl sulfoxide by compound 1 as a catalyst within 40 min. The conversion rate and selectivity reached 99%. Compound 1 had good cycling stability as a heterogeneous catalyst. In addition, the electrocatalytic reduction of H₂O₂ and Cr₂O₇^2‒ for hybrid 1 was preliminarily investigated. In addition, the adsorption performance of hybrid 1 on cationic dye crystal violet and methylene blue was tested, and the adsorption efficiencies can reach 98.5% and 86.3%, respectively.

Key words: Polyoxometalate, Catalysis, Electrocatalysis, Dye adsorption

LIU Xiaodong, WANG Xiangchen, XU Na, ZHANG Zhong, LI Xiaohui, LIU Guocheng, WANG Xiuli. A Multifunctional {P₂Mo₅}-based Hybrid Applying to Catalysis, Electrocatalysis and Dye Adsorption[J]. Chemical Research in Chinese Universities, 2022, 38(6): 1553-1560.

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A Multifunctional {P₂Mo₅}-based Hybrid Applying to Catalysis, Electrocatalysis and Dye Adsorption

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