A Dual Read-out Molecularly Imprinted Composite Membrane Sensor Based on Zinc Porphyrin for the Detection of Dimethyl Methylphosphonate

doi:10.1007/s40242-016-6120-8

Chemical Research in Chinese Universities ›› 2016, Vol. 32 ›› Issue (5): 725-730.doi: 10.1007/s40242-016-6120-8

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A Dual Read-out Molecularly Imprinted Composite Membrane Sensor Based on Zinc Porphyrin for the Detection of Dimethyl Methylphosphonate

ZHANG Ya¹, QIAN Linlin¹, YIN Wei¹, HE Bin¹, LIU Fangmei¹, HOU Changjun², HUO Danqun², FA Huanbao¹

1. National-municipal Joint Engineering Laboratory for Chemical Process Intensification and Reaction, College of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044, P. R. China;
2. Key Laboratory of Biorheology Science and Technology, Ministry of Education, College of Bioengineering, Chongqing University, Chongqing 400044, P. R. China

Received:2016-03-30 Revised:2016-05-30 Online:2016-10-01 Published:2016-07-18
Contact: YIN Wei, FA Huanbao E-mail:yinweicqu@163.com;huanbaofa@cqu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(No.31101284), the Natural Science Foundation of Chongqing City, China(No.CSTC-2011BB1209), the Fundamental Research Funds for the Central Universities of China (Nos.CQDXWL-2012-034, CQDXWL-2012-035, CDJPY1222 0001) and the Student Research Training Program in Chongqing University, China(Nos.CQU-SRTP-2015497, CQU-SRTP-2015502).

Abstract

Abstract:

Molecularly imprinted membrane-zinc porphyrin-mathacrylate(MIM-Zn-MAA), a dual read-out sensor based on a molecularly imprinted membrane, was developed to recognize and detect dimethyl methylphosphonate (DMMP) as an intermediate molecule of organophosphorus pesticides. The membranes were prepared via thermal polymerization of two functional monomers(zinc porphyrin and mathacrylate) on the surface of a glass slide functionalized with ethylene glycol dimethacrylate and azobisisobutyronitrile. The morphology of the as-synthesized MIM-Zn-MAA was determined with scanning electronic microscopy. The composite membranes exhibited macrovoid morphologies, which were affected by the functional monomers. These membranes were selectively adsorbed onto the template molecule and displayed higher adsorbing capacity toward DMMP compared with their structural analogs. Changes in the fluorescent spectra were qualitatively and quantitatively monitored via fluorescence photometry. Difference maps were also obtained using colorimetry before and after the reaction between MIM-Zn-MAA and DMMP at various concentrations. The maps showed a wide linear range varying from 0.1 μmol/L to 10 mmol/L with a low detection limit of 0.1 μmol/L. These preliminary results demonstrate that the as-fabricated dual read-out sensor displays good sensitivity and selectivity toward DMMP, indicating its considerable potential in DMMP detection in practical applications.

Key words: Zinc porphyrin, Organophosphate, Molecularly imprinted polymer membrane, Fluorescence, Colorimetric detection

ZHANG Ya, QIAN Linlin, YIN Wei, HE Bin, LIU Fangmei, HOU Changjun, HUO Danqun, FA Huanbao. A Dual Read-out Molecularly Imprinted Composite Membrane Sensor Based on Zinc Porphyrin for the Detection of Dimethyl Methylphosphonate[J]. Chemical Research in Chinese Universities, 2016, 32(5): 725-730.

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A Dual Read-out Molecularly Imprinted Composite Membrane Sensor Based on Zinc Porphyrin for the Detection of Dimethyl Methylphosphonate

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