Effect of Cu(Ⅱ) on Degradation and Decolorization of Rhodamine B in Subcritical Water

doi:10.1007/s40242-017-6501-7

Chemical Research in Chinese Universities ›› 2017, Vol. 33 ›› Issue (4): 643-647.doi: 10.1007/s40242-017-6501-7

• Articles • Previous Articles Next Articles

Effect of Cu(Ⅱ) on Degradation and Decolorization of Rhodamine B in Subcritical Water

CHENG Kai¹, YANG Wei¹, WANG Hui¹, ZHOU Jie¹, WU Shengji¹, YU Tianming², PAN Jianbo²

1. College of Materials and Environmental Engineering, Hangzhou Dianzi University, Hangzhou 310018, P. R. China;
2. Tianlu Environment Technology Co., Ltd., Quzhou 324000, P. R. China

Received:2016-12-23 Revised:2017-01-24 Online:2017-08-01 Published:2017-05-08
Contact: WU Shengji E-mail:wu_shengji@hotmail.com
Supported by:
Supported by the Natural Science Foundation of Zhejiang Province，China（No.LQ17B060006），the Science and Technology Planning Project of Zhejiang Province，China（No.2013C31016） and the National Natural Science Foundation of China（No.21406044）.

Abstract

Abstract:

In this paper, subcritical water, an environmentally friendly solvent, was employed to degrade rhodamine B, which served as a model dye in textile industrial effluents. The effect of Cu(Ⅱ) on the degradation of rhodamine B was evaluated. Further, the degradation kinetics of rhodamine B in subcritical water was evaluated via a Weibull model. The results show that subcritical water could efficiently degrade and decolorize rhodamine B. The addition of Cu(Ⅱ) into subcritical water could accelerate the degradation of rhodamine B and lower the temperature for its complete degradation. The Weibull equation could well express the degradation kinetics of rhodamine B. The calculated rate constants showed Arrhenius behavior and presented high correlation coefficients. The activation energy was 109.4 kJ/mol for subcritical water degradation of rhodamine B, whereas it became lower(93.4 kJ/mol) when Cu(Ⅱ) was added to the subcritical water. The frequency factors for the degradation of rhodamine B by subcritical water without and with Cu(Ⅱ) were calculated to be 1.0×10¹¹ and 3.2×10⁹ min^-1, respectively. The above results indicate that subcritical water treatment is a promising process for degrading and decolorizing textile dyes. The results will provide a theoretic support for the industrial application of subcritical water treatment.

Key words: Subcritical water, Degradation kinetics, Rhodamine B, Weibull equation, Copper ion

CHENG Kai, YANG Wei, WANG Hui, ZHOU Jie, WU Shengji, YU Tianming, PAN Jianbo. Effect of Cu(Ⅱ) on Degradation and Decolorization of Rhodamine B in Subcritical Water[J]. Chemical Research in Chinese Universities, 2017, 33(4): 643-647.

References

[1] Stylidi M., Kondarides D. I., Verykilos X. E., Appl. Catal. B:Environ., 2003, 40, 271
[2] Sun J., Qiao L., Sun S., Wang G., J. Hazard. Mater., 2008, 155, 312
[3] Hosseini S. D., Asghari F. S., Yoshida H., Water. Res., 2010, 44, 1900
[4] Yuksel A., Sasaki M., Goto M., J. Hazard. Mater., 2011, 190, 1058
[5] Kayan B., Gozmen B., J. Hazard. Mater., 2012, 201/202, 100
[6] Solis M., Solis A., Perez H. I., Manjarrez N., Flores M., Process Biochem., 2012, 47, 1723
[7] Ghoreishi S. M., Haghighi R., Chem. Eng. J., 2003, 95, 163
[8] Can H. K., Klrcl S., Guner A., Radiat. Phys. Chem., 2003, 68, 811
[9] Mall I. D., Srivastava V. C., Agrarwal N. K., Dyes Pigm., 2006, 69, 203
[10] Sogut O. O., Akgun M., J. Chem. Technol. Biotechnol., 2010, 85, 640
[11] Daskalaki V. M., Timotheatou E. S., Katsaounis A., Kalderis D., Desalination, 2011, 274, 200
[12] Cliddord T., Fundamental of Supercritical Fluids, Oxford University Press, New York, 1998
[13] Fujii T., Khuwijitjaru P., Kimura Y., Adachi S., Food Chem., 2006, 94, 341
[14] Omori T., Khajavi S. H., Kimura Y., Adachi S., Matsuno R., Biochem. Eng. J., 2004, 18, 143
[15] Khajavi S. H., Kimura Y., Omori T., Matsuno R., Adachi S., J. Food Eng., 2005, 68, 309
[16] Yang W., Shimanouchi T., Wu S. J., Kimura Y., Energy Fuels, 2014, 28, 6974
[17] Yang W., Shimanouchi T., Kimura Y., ACS. Sus. Chem. Eng., 2015, 3, 591
[18] Mekonnen T. H., Mussone P. G., EI-Thaher N., Choi P., Bressler D. C., J. Chem. Technol. Biotechnol., 2015, 90, 476
[19] Hori H., Tanaka H., Watanabe K., Tsuge T., Sakamoto T., Ind. Eng. Chem. Res., 2015, 54, 8650
[20] Liang X., Rahubadda A., Haynes B. S., Montoya A., Ind. Eng. Chem. Res., 2015, 54, 8437
[21] Ahluwalia S. S., Goyal D., Bioresour. Technol., 2007, 98, 2243
[22] Imran M., Arshad, M., Khalid, A., Hussain S., Mumtaz M. W., Crowley D. E., Water Environ. Res., 2015, 87, 579
[23] Bokare A. D., Choi W. Y., J. Hazard. Mater., 2014, 275, 121
[24] Byrappa K., Subramani A. K., Ananda S., Rai K. M. L., Dinesh R., Yoshimura M., Bull. Mater. Sci., 2006, 29, 433
[25] Ji F., Li C. L., Wei X. Y., Yu J., Chem. Eng. J., 2013, 231, 634
[26] Zhang X. S., Tian K., Hu J. Y., Jiang H., Chemosphere, 2015, 141, 127
[27] Liu S. M., Zhu J. L., Guo X. T., Ge J. H., Wu H. J., Colloid. Surf. A, 2015, 484, 434
[28] Bicker M., Endres S., Vogel O. H., J. Mol. Catal. A:Chem., 2005, 239, 151
[29] Coleman J. E., Curr. Opin. Chem. Biol., 1998, 2, 222

Effect of Cu(Ⅱ) on Degradation and Decolorization of Rhodamine B in Subcritical Water

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 12

Recommended Articles

Metrics

Comments

[1]	GU Liqiang, QIU Jianhui, SAKAI Eiichi. Effect of DOPO-containing Flame Retardants on Poly(lactic acid): Non-flammability, Mechanical Properties and Thermal Behaviors [J]. Chemical Research in Chinese Universities, 2017, 33(1): 143-149.
[2]	SUN Dandan, CAO Yanyan, XU Yanyan, ZHANG Guoying, SUN Yaqiu. Tunable Synthesis of Core-shell α-Fe₂O₃/TiO₂ Composite Nanoparticles and Their Visible-light Photocatalytic Activity [J]. Chemical Research in Chinese Universities, 2016, 32(6): 882-888.
[3]	CHEN Jiayi, SHU Wei, WANG Enju. A Fluorescent and Colorimetric Probe Based on Isatin-appended Rhodamine for the Detection of Hg²⁺ [J]. Chemical Research in Chinese Universities, 2016, 32(5): 742-745.
[4]	LIU Xuan, YANG Jiali, TONG Lanyan, ZHANG Qian, LI Xiaowei, CHEN Jida. Preparation of Cu(II)-imprinted Nanofibers from co-Electrospinning PVA and Imprinting Complex [J]. Chemical Research in Chinese Universities, 2015, 31(6): 1062-1065.
[5]	GUAN Jie, ZHANG Peng, WEI Taibao, LIN Qi, YAO Hong, ZHANG Youming. A Highly Selective Fluorescent Chemosensor for Cu²⁺ [J]. Chemical Research in Chinese Universities, 2015, 31(3): 347-351.
[6]	WU Yichao, DENG Xiuqing, MAO Yinchun, ZHANG Yan, LIU Jiaqin, RONG Li, XU Zhihong. Retention Mechanism of Phenolic Compounds in Subcritical Water Chromatography [J]. Chemical Research in Chinese Universities, 2015, 31(1): 103-106.
[7]	CAO Ben-nan, HU Qin, HUANG Yan, JIA Chun-man, ZHANG Qi. Highly Sensitive and Selective Chemosensor for Cu²⁺ Based on a Schiff Base [J]. Chemical Research in Chinese Universities, 2013, 29(3): 419-423.
[8]	FAN Cai-ling, DAI Xing, YANG Wu-min, WANG Xing-feng and YANG Yun-xu. A Quinoline Derivated Chemosensor for Cu²⁺ Recognition [J]. Chemical Research in Chinese Universities, 2009, 25(5): 620-623.
[9]	REN Yuan-lin , CHENG Bo-wen , ZHANG Jin-shu , JIANG Ai-bing , FU Wen-li . Thermal Degradation Kinetics of N,N’- Di(diethoxythiophosphoryl)-1,4-phenylenediamine [J]. Chemical Research in Chinese Universities, 2008, 24(5): 628-631.
[10]	JIAO Kui, LI Qing-jun, SUN Wei, WANG Zhen-yong. Studies on the Recognition Interaction of Rhodamine B and DNA by Voltammetry [J]. Chemical Research in Chinese Universities, 2005, 21(2): 145-148.
[11]	LIU Bin, WANG Hong-mei, LIAO Dai-zheng, YAN Shi-ping, JIANG Zong-hui, WANG Geng-lin, HUANG Xiao-ying . Crystal Structure of the Addition Compound of N,N'-Bi(2-pyridylmethyl)-Oxamide and the Complex of Copper with 1,10-Phenanthroline [J]. Chemical Research in Chinese Universities, 1998, 14(4): 387-390.
[12]	HE Zhi-ke, LIU Xing-lian, LUO Qing-yao, YU Xi-mao, ZENG Yun'e. Chemiluminescence Determination of 6-Mercaptopurine in Pharmaceuticals [J]. Chemical Research in Chinese Universities, 1995, 11(3): 266-270.