Synthesis, Crystal Structure of Bis-terpyridinyl-calix[4]arene Derivatives and Fluorescent Sensor for Zn2+

doi:10.1007/s40242-013-3150-3

Chemical Research in Chinese Universities ›› 2013, Vol. 29 ›› Issue (5): 874-878.doi: 10.1007/s40242-013-3150-3

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Synthesis, Crystal Structure of Bis-terpyridinyl-calix[4]arene Derivatives and Fluorescent Sensor for Zn²⁺

LI Liang¹, DU Li-ting², SUN Jing², YAN Chao-guo²

1. School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418, P. R. China;
2. College of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou 225002, P. R. China

Received:2013-04-01 Revised:2013-04-24 Online:2013-10-01 Published:2013-09-17
Contact: YAN Chao-guo E-mail:cgyan@yzu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(No.20972132) and the Priority Academic Program Deve-lopment of Jiangsu Higher Education Institutions, China.

Abstract

Abstract:

The calix[4]arene-based podands which incorporates two terpyridinyl functional groups derived from the alkylation reactions of 4-(ω-chloroalkoxyphenyl)-2,2':6',2"-terpyridine in 1,3-alternate position at lower rim have been prepared in moderate yields. The structures of four pyridyl compounds were determined by X-ray single crystal diffraction method. The complexing properties of bis-terpyridinyl-calix[4]arenes for transition metal ions were investigated by fluorescence spectra. Bis-terpyridinyl-calix[4]arenes gave a more efficient fluorescent sensing ability to Zn²⁺.

Key words: Calixarene, Terpyridine, Ionic recognition, Crystal structure

LI Liang, DU Li-ting, SUN Jing, YAN Chao-guo. Synthesis, Crystal Structure of Bis-terpyridinyl-calix[4]arene Derivatives and Fluorescent Sensor for Zn²⁺[J]. Chemical Research in Chinese Universities, 2013, 29(5): 874-878.

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Synthesis, Crystal Structure of Bis-terpyridinyl-calix[4]arene Derivatives and Fluorescent Sensor for Zn²⁺

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