Design and Self-assembly of a Novel Tetranuclear Zinc(Ⅱ) Complex via Reaction of 1,3-Thiazolidine-2-thione(tzdtH) with Zn(NO3)2

Chemical Research in Chinese Universities ›› 2006, Vol. 22 ›› Issue (5): 665-668.doi:

• Research Notes • Previous Articles Next Articles

Design and Self-assembly of a Novel Tetranuclear Zinc(Ⅱ) Complex via Reaction of 1,3-Thiazolidine-2-thione(tzdtH) with Zn(NO₃)₂

WEI Xian-yin¹, HUANG Ru-dan¹, YU Li-qiong¹, ZHU Qin-lei¹, ZHANG Zhong-qiang²and LIU Li-ping¹

1. Department of Chemistry, School of Science, Beijing Institute of Technology, Beijing 100081, P. R. China;
2. Department of Chemistry, Hengshui University, Hengshui 053000, P. R. China

Received:2005-12-26 Revised:1900-01-01 Online:2006-09-25 Published:2006-09-25
Contact: HUANG Ru-dan E-mail:huangrd@bit.edu.cn

Abstract

Abstract:

In this study, 1,3-thiazolidine-2-thionate was chosen as the multifunctional coordination ligand on the basis of the considerations that it has exocyclic sulfur(S_exo) and endocyclic nitrogen(N_endo) donors that are at the meta position and allow tzdtH to form and support an isolated metal-ligand cluster in the coordination architecture. As a result, a blossomshaped tetranuclear zinc cluster [Zn₄(μ₄-O)(tzdt)₆] was synthesized by the reaction of tzdtH with Zn(NO₃)₂ under a mild condition for the first time. It was characterized by means of IR spectrometry and elemental analyses. The crystal structure of [Zn₄(μ₄-O)(tzdt)₆] was determined by X-ray diffraction(XRD).

Key words: Self assembly, Tetranuclear cluster, Zinc complex, Crystal structure

WEI Xian-yin , HUANG Ru-dan , YU Li-qiong , ZHU Qin-lei , ZHANG Zhong-qiang , LIU Li-ping . Design and Self-assembly of a Novel Tetranuclear Zinc(Ⅱ) Complex via Reaction of 1,3-Thiazolidine-2-thione(tzdtH) with Zn(NO₃)₂[J]. Chemical Research in Chinese Universities, 2006, 22(5): 665-668.

[1]	HUA Chen, YI Pin, LIU Wencong, WANG Mengfan, NIU Zheng, LANG Jianping. Coordination Polymers with Bipyridyl Diene and Triene Ligands: Synthesis, Structures and Luminescent Properties [J]. Chemical Research in Chinese Universities, 2022, 38(1): 209-216.
[2]	ZHANG Wenqi, LIN Zhengguo, CHI Yingnan, HONG Jie, YAN Li, HU Changwen. Assembly of Three Scandium-containing Heteropolytungstates Based on a Building-block Synthetic Strategy [J]. Chemical Research in Chinese Universities, 2020, 36(6): 1161-1167.
[3]	ZANG Jiahe, ZHANG Qing'an, SUN Dalin. Crystal Structures and Electrochemical Properties of R_1.5Ca_1.5MgNi₁₄(R=Nd, Gd and Er) Hydrogen Storage Alloys [J]. Chemical Research in Chinese Universities, 2019, 35(6): 1040-1045.
[4]	WANG Dongmei, LOU Shengjun, YING Yiting, GUO Zhiqi, WANG Lijun. Assembly of Two Isostructural Metal-organic Frameworks Based on Hetero-N,O Donor Ligand for Detecting Nitro Explosives [J]. Chemical Research in Chinese Universities, 2019, 35(5): 762-766.
[5]	MA Xiao, WANG Xiaohong, SHANG Fan, DING Zimei, HANG Xiaojing, HUANG Jie. Studies on 3-Amino-4-(1H-tetrazol-5-yl)-furazan: Crystal Structure, Thermal Behavior and Energetic Performance [J]. Chemical Research in Chinese Universities, 2019, 35(5): 848-853.
[6]	ZHONG Liangxuan, LIU Mingyue, ZHANG Bowei, SUN Yaqiu, XU Yanyan. Syntheses, Crystal Structures, Magnetic and Near-infrared Luminescence Properties of 3d-4f Coordination Polymers Cu₂Pr₂, Cu₂Eu₂ and Cu₄Tb₂ [J]. Chemical Research in Chinese Universities, 2019, 35(4): 693-699.
[7]	LI Xinhua, YUAN Caixia, LU Liping, ZHU Miaoli, XING Shu, FU Xueqi. Exploration of Zinc(II) Complexes as Potent Inhibitors Against Protein Tyrosine Phosphatase 1B [J]. Chemical Research in Chinese Universities, 2019, 35(2): 186-192.
[8]	YU Yanzhao, CAO Jiapeng, XU Yan. Two Pentavanadate-based Organic-inorganic Materials with Third-order NLO Properties [J]. Chemical Research in Chinese Universities, 2019, 35(1): 1-4.
[9]	DING Zimei, CAO Wenli, ZHENG Hui, HUANG Jie, XU Kangzhen, SONG Jirong. Synthesis, Structure Characteristic and Thermal Behavior of Two New Metal-organic Azo-triazole Compounds: [Zn(phen)₃]·ZTO·6H₂O and[Cu(phen)₃]·ZTO·6H₂O [J]. Chemical Research in Chinese Universities, 2018, 34(6): 1009-1013.
[10]	CHEN Xiang, ZENG Tian, ZHANG Cong, GUO Zhaoqi, LI Shuailei, MAI Tao, GAO Rong, MA Haixia. Crystal Structures, Thermal Behavior Analysis and Thermal Safety of Two Energetic Salts of Hydrazinyl-1,2,4,5-tetrazine with 3,5-Dinitrosalicylic Acid [J]. Chemical Research in Chinese Universities, 2018, 34(6): 959-964.
[11]	LIU Chao, LIU Yijie, ZHANG Lili, JIANG Kun, ZHANG Li. Two Coordination Compounds Bearing Bis(2-dimethylaminoethyl) Ether: Syntheses, Crystal Structures and Catalytic Application to the Henry Reaction [J]. Chemical Research in Chinese Universities, 2018, 34(3): 358-362.
[12]	WANG Jingyang, ZHANG Meng, XU Xiaodong, FENG Jing, WANG Yanli, ZHANG Milin, HAN Wei, CHEN Yitung, TIAN Guoxin. Synthesis and Characterization of [Cu(N-MeIm)₄(BF₄)₂] in Ionic Liquid [J]. Chemical Research in Chinese Universities, 2018, 34(1): 8-12.
[13]	ZHOU Jinhua, LI Jingjing, LI Jie, REN Guoyu, REN Yinghui, MA Haixia. Structure and Enhanced Antifungal Activity of a Divalent Cobalt(II) Complex with Hexaconazole [J]. Chemical Research in Chinese Universities, 2017, 33(6): 864-868.
[14]	WANG Xiang, LIN Lin, LIN Hongyan, LIU Guocheng. Syntheses, Structure and Properties of a 3d-4d/2-ptz Heterometallic Organic Chain-modified POM-based Framework [J]. Chemical Research in Chinese Universities, 2017, 33(1): 7-11.
[15]	HE Yuanchun, GUO Jiao, XU Na, YU Yang. Assembly of Five Coordination Polymers Based on 5,11,17,23-Tetra-tert-butyl-25-(carboxymethoxy)-calix[4]arene Ligand [J]. Chemical Research in Chinese Universities, 2017, 33(1): 44-48.

Design and Self-assembly of a Novel Tetranuclear Zinc(Ⅱ) Complex via Reaction of 1,3-Thiazolidine-2-thione(tzdtH) with Zn(NO₃)₂

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments