Synthesis and Crystal Structure of Cu(Ⅱ) Adduct with N-(4-Chlorophenyl)aza 15-Crown-5

Chemical Research in Chinese Universities ›› 1991, Vol. 7 ›› Issue (1): 1-5.

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Synthesis and Crystal Structure of Cu(Ⅱ) Adduct with N-(4-Chlorophenyl)aza 15-Crown-5

Yan Shiping¹, Wang Genglin¹, Yao Xinkan², Wang Honggen²

1. Department of Chemistry, Nankin University, Tianjin;
2. Central Laboratory, Nankai University, Tianjin

Received:1990-05-14 Online:1991-01-24 Published:2011-09-09
Supported by:
This work was supported by the National Natural Science Foundation of China.

Abstract

Abstract: The title compound C₁₈H₂₅NC₄ClBr_{3/sub>Cu crystallizes in space group P 1with a = 1.0105(2)nm b=1.0821(1) nm, c=1. 1007(2) nm, a=80. 00(1)°,β=80. 26(1)° γ=77. 83(1)°. Z=2, D_s = 1. 831 g/cm³, μ=62. 658 cm^-1(Mok_u). The final refinement converged to R=0. 031 for 2547 independent observed reflections. The complex molecule consists of two cationic moieties (HL)⁺ and an anion which appears as a bromide-bridged copper dimer (Cu₂Br₆)^2-. This structural characterization seems to be rare in metal complexes with crown-ether.}

Key words: Crown-ether, Copper complex, Crystal structure

Yan Shiping, Wang Genglin, Yao Xinkan, Wang Honggen. Synthesis and Crystal Structure of Cu(Ⅱ) Adduct with N-(4-Chlorophenyl)aza 15-Crown-5[J]. Chemical Research in Chinese Universities, 1991, 7(1): 1-5.

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Synthesis and Crystal Structure of Cu(Ⅱ) Adduct with N-(4-Chlorophenyl)aza 15-Crown-5

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