Facile Synthesis of Mesoporous Si-containing γ-Al2O3Nanofiber with Enhanced Thermal Stability

doi:10.1007/s40242-015-4322-0

Chemical Research in Chinese Universities ›› 2015, Vol. 31 ›› Issue (1): 156-159.doi: 10.1007/s40242-015-4322-0

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Facile Synthesis of Mesoporous Si-containing γ-Al₂O₃Nanofiber with Enhanced Thermal Stability

HU Fang^1,3, WANG Yamin¹, LAI Xiaoyong², WU Yusheng¹, DU Fei³, WANG Chunzhong³

1. School of Materials Science and Engineering, Shenyang University of Technology, Shenyang 110870, P. R. China;
2. State Key Laboratory Cultivation Base of Natural Gas Conversion, Ningxia University, Yinchuan 750021, P. R. China;
3. Key Laboratory of Advanced Batteries Physics and Technology, Ministry of Education, College of Physics, Jilin University, Changchun 130012, P. R. China

Received:2014-08-28 Revised:2014-10-16 Online:2015-02-01 Published:2014-11-17
Contact: WANG Chunzhong, E-mail:wcz@jlu.edu.cn E-mail:wcz@jlu.edu.cn
Supported by:
Supported by the National Science and Technology Support Program of China(No.51362024), the Project of the Educational Department of Liaoning Province of China(No.201124124), the Program of Liaoning Excellent Talents in University, China(No. LR2014004) and the Development Program of Science and Technology of Jilin Province, China(No.20120310).

Abstract

Abstract:

Mesoporous γ-Al₂O₃ nanofiber was prepared via a simple reverse precipitation route using Si-containing Al(OH)₃ and HNO₃ as raw materials. The resultant Si-containing mesoporous γ-Al₂O₃ nanofiber exhibited high surface area of 320 m²/g, large pore volume of 1.17 cm³/g and large pore size of 10.5 nm. The introduction of Si element remarkably enhanced the thermal stability of mesoporous γ-Al₂O₃. The as-prepared nanofiber could maintain relative high surface area(110 m²/g) and pore volume(0.73 cm³/g) up to 1100 ℃. The effects of various experimental conditions, such as pH value, reaction temperature and aging temperature on the structural properties of the mesoporous γ-Al₂O₃ were also investigated.

Key words: Mesoporous γ-Al₂O₃, Reverse precipitation, Thermal stability, Nanofiber

HU Fang, WANG Yamin, LAI Xiaoyong, WU Yusheng, DU Fei, WANG Chunzhong. Facile Synthesis of Mesoporous Si-containing γ-Al₂O₃Nanofiber with Enhanced Thermal Stability[J]. Chemical Research in Chinese Universities, 2015, 31(1): 156-159.

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Facile Synthesis of Mesoporous Si-containing γ-Al₂O₃Nanofiber with Enhanced Thermal Stability

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