A Novel Hollow Carbon@MnO2 Electrospun Nanofiber Adsorbent for Efficient Removal of Pb2+ in Wastewater

doi:10.1007/s40242-021-1085-7

Abstract

Abstract: Lead ion(Pb²⁺) is one of the most hazardous heavy metal ions in aquatic environments. Carbon materials and manganese dio-xide(MnO₂) have been shown to be prospective adsorbents to cope with the lead pollution. In this study, a novel hollow carbon@MnO₂ composite nanofiber adsorbent was prepared by the combination of electrospinning and carbonization. The PAN nanofiber membrane is subjected to a pre-oxidation and carbonization process, and then the obtained carbon nanofibers react with KMnO₄ solution during the hydrothermal process to develop the hollow carbon@MnO₂ nanofibers. The hollow carbon@MnO₂ nanofibers displayed a higher adsorption capacity of Pb²⁺ than carbon and MnO₂/PDA/PAN nanofibers. The maximum adsorption capacity toward Pb²⁺ by hollow carbon@MnO₂ nanofibers was 460.83 mg/g. After 5 adsorption-desorption cycles, the carbon@MnO₂nanofibers had a good recyclability and the removal efficiency remained 81.47%. Moreover, the removal efficiency of the hollow composite nanofibers for Pb²⁺ from real wastewater could reach 94.37%. This work shows a strategy for synthetics of the hollow carbon@MnO₂ nanofibers, which exhibits a promising potential in actual wastewater treatment.

Key words: Carbon@MnO₂ composite, Hollow nanofiber, Electrospinning, Lead adsorption

LI Wenyan, LI Yanzi, LIU Jiadi, CHAO Shen, YANG Tianyi, LI Lijuan, WANG Ce, LI Xiang. A Novel Hollow Carbon@MnO₂ Electrospun Nanofiber Adsorbent for Efficient Removal of Pb²⁺ in Wastewater[J]. Chemical Research in Chinese Universities, 2021, 37(3): 496-504.

References 42

[1]	Patil N. A., Gore P. M., Jaya Prakash N., Govindaraj P., Yadav R., Verma V., Shanmugarajan D., Patil S., Kore A., Kandasubramanian B., Chem. Eng. J., 2021, 416, 129152
[2]	Zhao R., Wang Y., Li X., Sun B., Wang, C., ACS Appl. Mater. Inter., 2015, 7, 26649
[3]	Rezania S., Taib S. M., Din M. F. M., Dahalan F. A., Kamyab H., J. Hazard. Mater., 2016, 318, 587
[4]	Zia Q., Tabassum M., Meng J. M., Xin Z. Y., Gong H., Li J. S., Int. J. Biol. Macrmol., 2021, 167, 1479
[5]	Luo C., Wang J., Jia P., Liu Y., An J., Cao B., Pan K., Chem. Eng. J., 2015, 262, 775
[6]	Zhao R., Li X., Sun B., Shen M., Tan X., Ding Y., Jiang Z., Wang C., Chem. Eng. J., 2015, 268, 290
[7]	Zhao R., Li X., Sun B., Ji H., Wang, C., J. Colloid. Interf. Sci., 2017, 487, 297
[8]	Sun B., Li X., Zhao R., Yin M., Wang Z., Jiang Z., Wang C., J. Taiwan. Inst. Chem. E., 2016, 62, 219
[9]	Zhao J., Liu J., Li N., Wang W., Nan J., Zhao Z., Cui F., Chem. Eng. J., 2016, 304, 737
[10]	Awual M. R., Chem. Eng. J., 2015, 266, 368
[11]	Vuković G. D., Marinković A. D., Škapin S. D., Ristić M. Đ., Aleksić R., Perić-Grujić A. A., Uskoković P. S., Chem. Eng. J., 2011, 173, 855
[12]	Huang J., Huang Z. L., Zhou J. X., Li C. Z., Yang Z. H., Ruan M., Li H., Zhang X., Wu Z. J., Qin X. L., Hu J. H., Zhou K., Chem. Eng. J., 2019, 374, 880
[13]	Gao J., Wang X. Y., Zhang Y. W., Liu J., Lu Q., Chen M. F., Bai Y. S., Electrochim. Acta, 2016, 192, 234
[14]	Torasso N., Vergara-Rubio A., Rivas-Rojas P., Huck-Iriart C., Larranaga A., Fernandez-Cirelli A., Cerveny S., Goyanes S., J. Environ. Chem. Eng., 2021, 9, 104664
[15]	Zhao R., Li X., Sun B., Li Y., Li Y., Wang C., Chem. Res. Chinese Universities, 2017, 33(6), 986
[16]	Haghdoost F., Bahrami S. H., Barzin J., Ghaee A., Sep. Purif Technol., 2021, 257, 117881
[17]	Xu Q., Kong Q., Liu Z., Wang X., Liu R., Zhang J., Yue L., Duan Y., Cui G., ACS Sustain. Chem. Eng., 2013, 2, 194
[18]	Luo C. J., Stoyanov S. D., Stride E., Pelan E., Edirisinghe M., Chem. Soc. Rev., 2012, 41, 4708
[19]	Li H., Gui L., Gao Z.Y., Ren F. P., Zhang H. L., Peng R. C., Nanotechnology, 2021, 32, 21
[20]	Ma Y., He D., Liu J., Wang Y., Yang M., Wang H., Qiu J., Li W., Li Y., Wang C., Chem. Res. Chinese Universities, 2021, 37(3), 428
[21]	Wang Y., Li W., Chao S., Li Y., Li X., He D., Wang C., Chem. Res. Chinese Universities, 2020, 36(6), 1292
[22]	Zhu F., Zheng Y. M., Zhang B. G., Dai Y. R., J. Hazard. Mater., 2021, 401, 123608
[23]	Ren T., Si Y., Yang J. M., Ding B., Yang X. X., Hong F., Yu J. Y., J. Mater. Chem., 2012, 22, 15919
[24]	Thamer B. M., Aldalbahi A., Moydeen A. M., Al-Enizi A. M., El-Hamshary H., El-Newehy M. H., Sci. Rep-UK, 2019, 9, 19467
[25]	Wang J. H., Cai C., Zhang Z. J., Li C. L., Liu R., Chemosphere, 2020, 239, 124833
[26]	Zhao L., Yu J., Li W., Wang S., Dai C., Wu J., Bai X., Zhi C., Nano Energy, 2014, 4, 39
[27]	Li Q. H., Dong M., Li R., Cui Y. Q., Xie G. X., Wang X. X., Long Y. Z., Carbohyd. Polym., 2021, 253, 117200
[28]	Julien C., Solid State Ionics, 2003, 159, 345
[29]	Bao L., Zang J., Li X., Nano Lett., 2011, 11, 1215
[30]	Yang P., Ding Y., Lin Z., Chen Z., Li Y., Qiang P., Ebrahimi M., Mai W., Wong C. P., Wang Z. L., Nano Lett., 2014, 14, 731
[31]	Salam M. A., Colloid. Surface. A, 2013, 419, 69
[32]	Mallakpour S., Motirasoul F., Prog. Org. Coat., 2017, 103, 135
[33]	Sridewi N., Lee Y. F., Sudesh K., Int. J. Photoenergy, 2011, 2011, 1
[34]	Wang S., Gong W., Liu X., Yao Y., Gao B., Yue Q., Sep. Purif. Technol., 2007, 58, 17
[35]	Abdullah N., Othman F. E. C., Yusof N., Matsuura T., Lau W. J., Jaafar J., Ismail A. F., Salleh W. N. W., Aziz F., J. Water Process Eng., 2020, 37, 101430
[36]	Buyukada-Kesici E., Gezmis-Yavuz E., Aydin D., Cansoy C. E., Alp K., Koseoglu-Imer D. Y., Mater. Sci. Eng. B:Adv., 2021, 264
[37]	Ren Y., Yan N., Feng J., Ma J., Wen Q., Li N., Dong Q., Mater. Chem. Phys., 2012, 136, 538
[38]	Lim S. F., Zheng Y. M., Chen J. P., Langmuir, 2009, 25, 4973
[39]	Zhang J., Han J., Wang M., Guo R., J. Mater. Chem. A, 2017, 5, 4058
[40]	Luo C., Wei R., Guo D., Zhang S., Yan S., Chem. Eng. J., 2013, 225, 406
[41]	Ding C., Cheng W., Wang X., Wu Z. Y., Sun Y., Chen C., Wang X., Yu S. H., J. Hazard. Mater., 2016, 313, 253
[42]	Liang H. W., Cao X., Zhang W. J., Lin H. T., Zhou F., Chen L. F., Yu S. H., Adv. Funct. Mater., 2011, 21, 3851

A Novel Hollow Carbon@MnO₂ Electrospun Nanofiber Adsorbent for Efficient Removal of Pb²⁺ in Wastewater

Knowledge

Abstract

Cite this article

share this article

References 42

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	SUN Bolun, CHAO Danming, WANG Ce. Piezoelectric Nanogenerator Based on Electrospun Cellulose Acetate/Nanocellulose Crystal Composite Membranes for Energy Harvesting Application [J]. Chemical Research in Chinese Universities, 2022, 38(4): 1005-1011.
[2]	YANG Siran, AI Feixue, LI Ziping, ZHAO Guiyan, BI Yanfeng. N-Doped Carbon Nanofibers Encapsulating CoO@Co₉S₈ Nanoparticles: Preparation from S-Rich Co₃₂ Coordination Cluster Precursors by Electrospinning and Application for Superior Li-ion Storage [J]. Chemical Research in Chinese Universities, 2022, 38(2): 603-608.
[3]	WANG Jun, FU Wanlin, XU Wanlin, WU Min, SUN Yueming, DAI Yunqian. Oxide Nanofibers as Catalysts Toward Energy Conversion and Environmental Protection [J]. Chemical Research in Chinese Universities, 2021, 37(3): 366-378.
[4]	HUANG Hedong, GUO Zeyu, YANG Pengyan, CHEN Peng, Wu Jie. Electrical Conductivity, Oil Absorption and Electric Heating of Carbon Black-modified Carbon Nanofibers [J]. Chemical Research in Chinese Universities, 2021, 37(3): 541-548.
[5]	BAI Shan, ZHANG Xiangyu, ZANG Leilei, YANG Songze, CHEN Xiaoqi, YUAN Xiaoyan. Electrospinning of Biomaterials for Vascular Regeneration [J]. Chemical Research in Chinese Universities, 2021, 37(3): 394-403.
[6]	QIN Mei, LIU Daqing, DAI Zhang, MENG Xin, LIU Guosai, LIU Hao, HUANG Xiaowei, YAN Xu, CHEN Shaojuan. One Step Fabrication and Application of Antibacterial Electrospun Zein/Cinnamon Oil Membrane Wound Dressing via In situ Electrospinning Process [J]. Chemical Research in Chinese Universities, 2021, 37(3): 464-469.
[7]	XIANG Huilin, ZHONG Lingling, REN Yongqing, LIU Dongmei, ZHU Zhigao, XU Ying, WANG Yu, WANG Wei. Superhydrophobized Polyacrylonitrile/Hierarchicall-FeOOH Nanofibrous Membrane for High-salinity Water Treatment in Membrane Distillation [J]. Chemical Research in Chinese Universities, 2021, 37(3): 470-479.
[8]	CAO Wenhao, WANG Caifeng, WANG Shuai, ZHANG Yang, ZHAO Ruisheng. Preparation of Photoresponsive PAN-NH₂@EPESP Fiber Films with Mechanical Stability for Regulating Wettability and Micro-environment Humidity [J]. Chemical Research in Chinese Universities, 2021, 37(3): 512-521.
[9]	FENG Zhendong, ZHANG Xiaopei, LIU Na, WANG Yue, ZHOU Ziyi, GLEBOV O. Oleg, WU Tong. Promotion of Neurite Outgrowth and Extension Using Injectable Welded Nanofibers [J]. Chemical Research in Chinese Universities, 2021, 37(3): 522-527.
[10]	LUO Yu, GONG Xiaoyan Shawn, XU Zhiwei, MENG Kai, ZHANG Ke-Qin, ZHAO Huijing. PTFE Electrospun Stent Graft——Preparation, Properties and Its Industrialization Prospect [J]. Chemical Research in Chinese Universities, 2021, 37(3): 589-597.
[11]	HOU Lanlan, LIU Jingchong, LI Dianming, GAO Yuan, WANG Yaqiong, HU Rongjun, REN Wen, XIE Shuixiang, CUI Zhimin, WANG Nü. Electrospinning Janus Nanofibrous Membrane for Unidirectional Liquid Penetration and Its Applications [J]. Chemical Research in Chinese Universities, 2021, 37(3): 337-354.
[12]	MA Yuying, HE Dayong, LIU Jiadi, WANG Yuannan, YANG Mei, WANG Hao, QIU Ju, LI Wenyan, LI Yongxin, WANG Ce. Adsorption and Visible Light Photocatalytic Degradation of Electrospun PAN@W₁₈O₄₉ Nanofibers [J]. Chemical Research in Chinese Universities, 2021, 37(3): 428-435.
[13]	JIAN Shaoju, TIAN Zhiwei, ZHANG Kaiyin, DUAN Gaigai, YANG Weisen, JIANG Shaohua. Hydrothermal Synthesis of Ce-doped ZnO Heterojunction Supported on Carbon Nanofibers with High Visible Light Photocatalytic Activity [J]. Chemical Research in Chinese Universities, 2021, 37(3): 565-570.
[14]	WANG Ruifang, YU Xi, LI Zhenyu, CHEN Jingyu, JIANG Tingting. Partial P-Type Metal Ions Doping Induced Variation of Both Crystal Structure and Oxygen Vacancy Within Cu/SnO₂ Metastable Solid Solution Nanofibers for Highly Sensitive C₂H₂ Sensor [J]. Chemical Research in Chinese Universities, 2021, 37(3): 584-588.
[15]	LI Haiyan, LIU Mingyue, WANG Xiaoyu, WANG Hongsheng, MO Xiumei, WU Jinglei. Nanofiber Configuration of Electrospun Scaffolds Dictating Cell Behaviors and Cell-scaffold Interactions [J]. Chemical Research in Chinese Universities, 2021, 37(3): 456-463.