Novel Chiral Polyoxometalate: First Arginine Based Anderson-type Complex

Chemical Research in Chinese Universities ›› 2012, Vol. 28 ›› Issue (3): 375-378.

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Novel Chiral Polyoxometalate: First Arginine Based Anderson-type Complex

LIN Shi-wei^1,2, WU Qiong^1,3, WANG En-bo¹

1. Key Laboratory of Polyoxometalate Science, Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun 130024, P. R. China;
2. Department of Chemistry, Changchun Normal University, Changchun 130032, P. R. China;
3. Department of Chemistry Science & Technology, Kunming University, Kunming 650214, P. R. China

Received:2011-10-18 Revised:2011-11-29 Online:2012-05-25 Published:2012-05-03
Contact: WANG En-bo E-mail:wangeb889@nenu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.20701005, 20701006), the Science and Technology Development Project Foundation of Jilin Province, China(No.20060420), the Postdoctoral Station Foundation of Ministry of Education of China(No.20060200002), the Testing Foundation of Northeast Normal University of China and the Natural Science Foundation of Changchun Normal University of China(No.2010006).

Abstract

Abstract: A novel chiral polyoxometalate(POM), {[Na(Arg)₂]NaH}[AlMo₆(OH)₆O₁₈]·6H₂O(1, Arg=L-arginine) has been synthesized by the reaction between Na₃[AlMo₆(OH)₆O₁₈]·8H₂O and Arg in aqueous solution and was structurally characterized by single-crystal X-ray diffraction, elemental analyses and UV-Vis spectrometry. Compound 1 was an example of Arg based Anderson-type complex. Photocatalytic analysis indicates that compound 1 presents catalytic activity for photodegradation of rhodamine-B(RhB) under UV irradiation.

Key words: Polyoxometalate, Anderson-type, Chiral, Arginine, Photocatalysis property

LIN Shi-wei, WU Qiong, WANG En-bo. Novel Chiral Polyoxometalate: First Arginine Based Anderson-type Complex[J]. Chemical Research in Chinese Universities, 2012, 28(3): 375-378.

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Novel Chiral Polyoxometalate: First Arginine Based Anderson-type Complex

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