Synthesis, Structure and Characterization of Three Metal Molybdate Hydrates: Fe(H2O)2(MoO4)2·H3O, NaCo2(MoO4)2(H3O2) and Mn2(MoO4)3·2H3O

Abstract

Abstract: Three metal molybdate hydrates, Fe(H₂O)₂(MoO₄)₂·H₃O(FeMo), NaCo₂(MoO₄)₂(H₃O₂)(CoMo) and Mn₂(MoO₄)₃·2H₃O(MnMo), were synthesized by the mixed-solvent-thermal methods and characterized by single- crystal X-ray diffraction. X-Ray photoelectron spectroscopy and bond-valence sums were applied to confirming the valance of Fe, Co, Mn and Mo. Thermo-gravimetric analysis and X-ray powder diffraction measurements indicate that the samples were converted to different structural compounds upon heating in air at 600 °C for 1 h. The magnetic properties of these compounds were studied. The dominant magnetic interactions are antiferromagnetic in nature. However, different synthesis conditions led to the diversity of magnetic properties of compound CoMo.

Key words: Mixed-solvent-thermal synthesis, Crystal structure, Transition metal molybdate, Magnetic property

YU Yang, LIU Dan, HU Wei-wei, LI Jia, PENG Yu, ZHOU Qi, YANG Fen, LI Guang-hua, SHI Zhan, FENG Shou-hua. Synthesis, Structure and Characterization of Three Metal Molybdate Hydrates: Fe(H₂O)₂(MoO₄)₂·H₃O, NaCo₂(MoO₄)₂(H₃O₂) and Mn₂(MoO₄)₃·₂H₃O[J]. Chemical Research in Chinese Universities, 2012, 28(2): 186-190 .

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Synthesis, Structure and Characterization of Three Metal Molybdate Hydrates: Fe(H₂O)₂(MoO₄)₂·H₃O, NaCo₂(MoO₄)₂(H₃O₂) and Mn₂(MoO₄)₃·₂H₃O

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