Hydrothermal Synthesis and Characterization of Double Perovskites RSrMnFeO6(R=La, Pr, Nd, Sm)

Abstract

Abstract: A series of double perovskites RSrMnFeO₆(R=La, Pr, Nd, Sm) was synthesized under mild hydrothermal conditions. Crystal growths of the samples were sensitive to alkalinity, temperature, filling fraction, and composition of initial reaction mixture. The desired series of compounds belongs to the class of AA′BB′O6 perovskites with a random distribution of Mn and Fe atoms over the B-cation sub-lattice. Their structures show the distorted orthorhombic symmetry with space group Pnma. The shapes and sizes of the crystals were analyzed on a Rigaku JSM-6700F by scanning electron microscopy. Analysis done by XPS, M?ssbauer spectroscopy and iodometric titration reveals that Mn and Fe ions have +4 and +3 oxidation states, respectively.

Key words: Double perovskites, Orthorhombic, Hydrothermal synthesis

ZHANG Gang-hua, YUAN Hong-ming, CHEN Yan, LI Wei-juan, YANG Mei-qi and FENG Shou. Hydrothermal Synthesis and Characterization of Double Perovskites RSrMnFeO₆(R=La, Pr, Nd, Sm)[J]. Chemical Research in Chinese Universities, 2010, 26(4): 517-521.

References

[1] Yamazoe N., Teraoka Y., Catal. Today, 1990, 8, 175 [2] Tejuca L. G., Fierro J. L. G., Properties and Applications of Perovskite Type Oxides, Marcel Dekker, NewYork, 1993 [3] Hong K. P., Choi Y. H., Kwon Y. U., Jung D. Y., Lee J. S., Lee C. H., J. Solid State Chem., 2000, 150, 383 [4] Ganguli A. K., Grover V., Thirumal M., Mater. Res. Bull., 2001, 36, 1967 [5] Kobayashi K. L., Kimura T., Sawada H., Terakura K., Tokura Y., Nature, 1998, 395, 677 [6] Kobayashi K. I., Kimura T., Tomioka Y., Sawada H., Terakura K., Tokura Y., Phys. Rev. B, 1999, 59, 11159 [7] Garcia-Landa B., Ritter C., Ibarra M. R., Blasco J., Algarabel P. A., Mahendiran R., Garcia J., Solid State Commun., 1999, 110, 435 [8] Zeng Z., Fawcett I. D., Greenblatt M., Croft M., Mater. Res. Bull., 2001, 36, 705 [9] Han H., Kim C. S., Lee B. W., J. Magn. Magn. Mater., 2003, 254/255, 574 [10] Anderson M. T., Greenwood K. B., Taylor G. A., Poeppelmeier K. R., Prog. Solid State Chem., 1993, 22, 197 [11] Attfield M. P., Battle P. D., Bollen S. K., Gibb T. C., Whitehead R. J., J. Solid State Chem., 1992, 100, 37 [12] Attfield M. P., Battle P. D., Bollen S. K., Kim S. H., Powell A. V., Workman M., J Solid State Chem., 1992, 96, 344 [13] Ramesha K., Thangadurai V., Sutar D., Subramanyam S. V., Subbanna G. N., Gopalakrishnan, Mater. Res. Bull., 2000, 35, 559 [14] Shaheen R., Bashir J., Rundl?f H., Rennie A. R., Mater. Lett., 2005, 59, 2296 [15] Battle P. D., Jones C. W., J. Solid State Chem., 1989, 18, 108 [16] Anderson M. T., Poeppelmeier K. R., Chem. Mater., 1991, 3, 476 [17] Abakumov A. M., Rossell M. D., Seryakov S. A., Antipov E. V., J. Mater. Chem., 2005, 15, 4899 [18] Tian S. Z., Zhao J. C., Qiao C. D., Ji X. L., Jiang B. Z., Mater. Lett., 2006, 60, 2747 [19] Chen Y., Yuan H., Tian G., Zhang G., Feng S., J. Solid State Chem., 2007, 180, 167 [20] Wang D., Yu R. B., Feng S. H., Zheng W. J., Pang G. S., Zhao H., Chem. J. Chinese Universities, 1998, 19(1), 165 [21] Li B., Hakuta Y., Hayashi H., Chem. Commun., 2005, 1732 [22] Mao Y. C., Li G. S., Xu W., Feng S. H., J. Mater. Chem., 2000, 10, 479 [23] Song Z., Li G. H., Yu Y., Shi Z., Feng S. H., Chem. Res. Chinese Universities, 2009, 25(1), 1 [24] Wang L., Zhang H., Dong W., Shi Z., Feng S. H., Chem. Res. Chinese Universities, 2008, 24(4), 389 [25] Feng S., Xu R., Acc. Chem. Res., 2001, 34, 239 [26] Feng S., Yuan H., Shi Z., Chen Y., Wang Y., Huang K., Hou C., Li J., Pang G., Hou Y., J. Mater. Sci., 2008, 43, 2131 [27] Marezio M., Remeika J. P., Dernier P. D., Acta Crystallogr., Sect. B, 1970, B26, 2008 [28] Nakamura T., Choy J. H., J. Solid State Chem., 1977, 20, 233 [29] Galasso F., Pyle J., Inorg. Chem., 1963, 2, 482 [30] Bernal S.,?Botana F. J.,?Laachir A., Moral P., Martin G. A., Perrichon V., Eur. J. Solid State Inorg. Chem., 1991, 28, 421 [31] Seyama H., Soma M., J. Electron Spectrosc. Relat. Phemon., 1987, 42, 97 [32] Da Costa F. M. A., Dos Santos A. J. C., Inorg. Chim. Acta, 1987, 140, 105 [33] Hernandez T., Plazaola F., Rojo T., Barandiaran H. M., J. Alloys Compd., 2001, 323/324, 440

Hydrothermal Synthesis and Characterization of Double Perovskites RSrMnFeO₆(R=La, Pr, Nd, Sm)

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	ZHANG Jiaqi, WANG Shan, YUAN Long, HOU Changmin. Hydrothermal Synthesis and Magnetic Properties ofSmCr_0.5M_0.5O₃(M=Fe and Mn) Micro-plates [J]. Chemical Research in Chinese Universities, 2018, 34(1): 1-7.
[2]	ZHANG Zaichao, HU Gonghao, XU Yan. Hydrothermal Synthesis, Structure and Properties of a New Phosphomolybdate Based on Novel [Co(H₂O)₄(HP₂Mo₅O₂₃)]^8- Anions and [H₈(H₂O)₁₆]⁸⁺ Water Cluster Cations [J]. Chemical Research in Chinese Universities, 2016, 32(3): 329-333.
[3]	WANG Xi, HAN Bin, GAO Yan, WANG Li, BAI Ming. HEDP-capped Terbium Orthophosphate Nanoparticles as Sensitive Luminescent Probes for the Detection of Pb²⁺ Ions [J]. Chemical Research in Chinese Universities, 2016, 32(3): 325-328.
[4]	DONG Zhaojun, YAN Yan, ZHANG Wenqing, WANG Yu, LI Jiyang. Hydrothermal Synthesis of a New Zinc Phosphite (C₅H₇N₂)₂·[Zn₃(HPO₃)₄] with Intersecting 8- and 12-Ring Channels [J]. Chemical Research in Chinese Universities, 2015, 31(4): 498-502.
[5]	FANG Weihui, YANG Guoyu. A Series of Lanthanide Coordination Polymers Constructed from 4-Pyridin-4-ylbenzoate [J]. Chemical Research in Chinese Universities, 2015, 31(2): 187-191.
[6]	Mouna SMIDA, Hager LITAIEM, Mohamed DAMMAK, Santiago GARCIA-GRANDA. Structure, Thermal Behavior and Characterization of a New Hybrid Iron Fluoride FeF₄(2,2'-bipyridine)(H₂O)₂ [J]. Chemical Research in Chinese Universities, 2015, 31(1): 16-20.
[7]	LIU Yabing, DUAN Weijie, CUI Xiaobing, XU Jiqing. Hydrothermal Syntheses and Characterization of Two 1D Chain Complexes and Tetra-capped Keggin Clusters [J]. Chemical Research in Chinese Universities, 2015, 31(1): 4-8.
[8]	WANG Xiuli, GONG Chunhua, QU Yun, LIU Guocheng, ZHANG Juwen. Syntheses, Structures and Properties of Three Transition Metal Coordination Polymers Based on Semi-rigid 3-Pyridylnicotinamide and S/N-Containing Dicarboxylate Mixed Ligands [J]. Chemical Research in Chinese Universities, 2014, 30(5): 709-714.
[9]	ZHANG Yu, CHEN Lei, JU Weiwei, XU Yan. Structural Characterization and Luminescence Properties of Two 4d-4f Ln-Ag Coordination Compounds Based on Dinuclear Lanthanide Clusters [J]. Chemical Research in Chinese Universities, 2014, 30(2): 194-199.
[10]	NAWAZ Faisal, WANG Liang, ZHU Long-feng, MENG Xiang-ju, XIAO Feng-Shou. Ascorbic Acid Assisted Green Route for Synthesis of Water Dispersible Carbon Dots [J]. Chemical Research in Chinese Universities, 2013, 29(3): 401-403.
[11]	HOU Chang-min, SONG Ming-dong, XUE Yun, GAO Xiao-xi, YU Kai-feng. Preparation and Characterization of Lepidocrocite Titanate Nanofibers [J]. Chemical Research in Chinese Universities, 2013, 29(2): 193-195.
[12]	ZHOU Guang-peng, YANG Yu-lin, FAN Rui-qing, XIE Jia-qing, QUAN Xue-jun. Hydrothermal Syntheses, Crystal Structures and Thermal Properties of Two New Organically Templated Open-framework Gallium Phosphites [J]. Chemical Research in Chinese Universities, 2013, 29(2): 201-205.
[13]	XU Zhen-he, GAO Yu, GE Xin, SUN Ya-guang. Facile Chemical Conversion Synthesis and Luminescence Properties of Uniform YF₃ Nanowires [J]. Chemical Research in Chinese Universities, 2013, 29(1): 1-5.
[14]	LIU Lian-li, HUANG Jing-jing, WANG Xiu-li, LIU Guo-cheng, YANG Song, MU Bao. Hydrothermal Synthesis, Structure and Characterization of a New 2D Co(II) Coordination Polymer Based on Flexible Double Imidazole Derivative and Oxalate [J]. Chemical Research in Chinese Universities, 2012, 28(6): 942-946.
[15]	HE Li-jie, ZHANG Dong, FENG Shou-hua, ZOU Bo, CHEN Gang. Hydrothermal Synthesis and Characterization of Perovskite Oxide AgTaO₃ [J]. Chemical Research in Chinese Universities, 2012, 28(5): 760-763 .