Solvothermal Synthesis and Characterization of (NH3 CH2 CH2 NH3)HgSnS4 with a Column Structure

Chemical Research in Chinese Universities ›› 2006, Vol. 22 ›› Issue (4): 411-414.

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Solvothermal Synthesis and Characterization of (NH₃ CH₂ CH₂ NH₃)HgSnS₄ with a Column Structure

WANG Yan-yan¹, BAIYIN Meng-he¹, JI Shou-hua², LIU Xiao-yang³, AN Yong-lin¹, NING Gui-ling¹

1. Department of Chemistry, Dalian University of Technology, Dalian 116024, P. R. China;
2. Department of Materials, Dalian University of Technology, Dalian 116024, P. R. China;
3. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry,Jilin University, Changchun 130023, P. R. China

Received:2005-07-07 Online:2006-08-24 Published:2011-08-06
Supported by:
Supported by the National Natural Science Foundation of China(No. 20071006).

Abstract

Abstract: A compound (NH₃CH₂CH₂NH₃)HgSnS₄ with a column structure was synthesized solvothermally and characterized by X-ray single-crystal diffraction. This compound crystallizes in the monoclinic space group C2/c with a=1.3863(6) nm, b=0.6640(3) nm, c=2.3198(10) nm, β=106.168(7)° and Z=8. It consists of anionic columns of [HgSnS₄]_∞^2- that are interrupted by cationic columns of [EnH₂]²⁺ . Its thermal and optical properties were studied.

Key words: Solvothermal synthesis, Quaternary thiostannate, Crystal structure

WANG Yan-yan, BAIYIN Meng-he, JI Shou-hua, LIU Xiao-yang, AN Yong-lin, NING Gui-ling. Solvothermal Synthesis and Characterization of (NH₃ CH₂ CH₂ NH₃)HgSnS₄ with a Column Structure[J]. Chemical Research in Chinese Universities, 2006, 22(4): 411-414.

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Solvothermal Synthesis and Characterization of (NH₃ CH₂ CH₂ NH₃)HgSnS₄ with a Column Structure

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