Synthesis and Spectroscopic Characterization of Organothiophosphoryl Polyoxotungstates α-[C6H11P(S)]2Xn+W11O39(8-n)- (Xn+=P5+, Si4+, Ge4+, Ga3+)

Chemical Research in Chinese Universities ›› 2004, Vol. 20 ›› Issue (5): 517-520.

• Articles • Next Articles

Synthesis and Spectroscopic Characterization of Organothiophosphoryl Polyoxotungstates α-[C₆H₁₁P(S)]₂Xⁿ⁺W₁₁O₃₉^(8-n)- (Xⁿ⁺=P⁵⁺, Si⁴⁺, Ge⁴⁺, Ga³⁺)

SUN Zhen-gang¹, YOU Wan-sheng¹, ZHU Zai-ming¹, GU Yuan-peng¹, LIU Jing-fu²

1. Department of Chemistry, Liaoning Normal University, Dalian 116029, P. R. China;
2. Department of Chemistry, Northeast Normal University, Changchun 130024, P. R. China

Received:2003-09-24 Online:2004-10-24 Published:2011-08-06
Supported by:
Supported by the Natural Science Foundation of Liaoning Province of China(No.20032104).

Abstract

Abstract: Organothiophosphoryl polyoxotungstate derivatives α-C₆H₁₁P(S)]₂Xⁿ⁺W₁₁O₃₉^(8-n)- (X=P, Si, Ge, Ga)were obtained by the reactions of the monovacant α-[Xⁿ⁺W₁₁O₃₉]^(12-n)- (X=P, Si, Ge, Ga) anions with electrophilic C₆H₁₁P(S)Cl₂ in acetonitrile.These new organic-inorganic hybrid anions were characterized by elemental analyses, IR, ³¹P and ¹⁸³W NMR spectrometries.The six-line ¹⁸³W NMR spectrum indicates that [C₆H₁₁P(S)]₂Xⁿ⁺W₁₁O₃₉^(8-n)- (X= P, Si, Ge, Ga) anions possess true Cs symmetry in acetonitrile.According to the spectroscopic observation and the chemical analyses, it is known that each of the hybrid anions consists of an α-[XW₁₁O₃)] framework on which two equivalent C₆H₁₁P(S) groups are grafted through P-O-W bridges.

Key words: Polyoxotungstate, Organophosphorus, Synthesis, ³¹P NMR, ¹⁸³W NMR

SUN Zhen-gang, YOU Wan-sheng, ZHU Zai-ming, GU Yuan-peng, LIU Jing-fu. Synthesis and Spectroscopic Characterization of Organothiophosphoryl Polyoxotungstates α-[C₆H₁₁P(S)]₂Xⁿ⁺W₁₁O₃₉^(8-n)- (Xⁿ⁺=P⁵⁺, Si⁴⁺, Ge⁴⁺, Ga³⁺)[J]. Chemical Research in Chinese Universities, 2004, 20(5): 517-520.

[1]	FAN Kui, SUN Yining, XU Pengcheng, GUO Jian, LI Zhenhua, SHAO Mingfei. Single-atom Catalysts Based on Layered Double Hydroxides [J]. Chemical Research in Chinese Universities, 2022, 38(5): 1185-1196.
[2]	JI Yuancheng, XU Jiayun, SUN Hongcheng, and LIU Junqiu. Artificial Photosynthesis(AP): from Molecular Catalysts to Heterogeneous Materials [J]. Chemical Research in Chinese Universities, 2022, 38(3): 688-697.
[3]	CHEN Juan, WANG Jiajia, CHEN Chongan and YANG Guoyu. Two New Borates Built by Different Types of {B₉} Cluster Units [J]. Chemical Research in Chinese Universities, 2022, 38(3): 744-749.
[4]	Mohammad Javad TAGHIZADEH, Maryam Saleh MOHAMMADNIA, Masoumeh GHALKHANI, Esmail SOHOULI. Improved Method for the Total Synthesis of Azaperone and Investigation of Its Electrochemical Behavior in Aqueous Solution [J]. Chemical Research in Chinese Universities, 2022, 38(2): 546-551.
[5]	SUN Xiao-Shuang, QIN Dan, LI Xu-Yan, YANG Guo-Yu. A New Tubular Borate Built by[B₁₄O₂₄(OH) ₆]^12- Cluster Units [J]. Chemical Research in Chinese Universities, 2022, 38(1): 123-127.
[6]	WANG Zelin, LIU Guihao, SHEN Tianyang, TAN Ling, ZHAO Yufei, SONG Yu-Fei. Remote Synthesis of Layered Double Hydroxide Nanosheets Through the Automatic Chemical Robot [J]. Chemical Research in Chinese Universities, 2022, 38(1): 217-222.
[7]	ZHANG Xiaosi, YANG Miao, TIAN Peng, LIU Zhongmin. Progress in Seed-assisted Synthesis of (Silico) Aluminophosphate Molecular Sieves [J]. Chemical Research in Chinese Universities, 2022, 38(1): 1-8.
[8]	LUAN Huimin, WU Qinming, ZHANG Jian, WANG Yeqing, MENG Xiangju, XIAO Feng-Shou. Sustainable Synthesis of Core-Shell Structured ZSM-5@Silicalite-1 Zeolite [J]. Chemical Research in Chinese Universities, 2022, 38(1): 136-140.
[9]	FANG Yuan, HEYDARI Zahra, LIU Chenghao, ZHANG Nianyue, CUCCIA Louis A., IVASENKO Oleksandr, PEREPICHKA Dmitrii F.. Glaser Coupling of Substituted Anthracene Diynes on a Non-metallic Surface at the Vapor-Solid Interface [J]. Chemical Research in Chinese Universities, 2021, 37(5): 1143-1148.
[10]	ZHAO Lei, YANG Ge, GUO Hailing, WANG Chunzheng, WANG Lijuan, Svetlana MINTOVA. Effect of Sodium Concentration on the Synthesis of Faujasite by Two-step Synthesis Procedure [J]. Chemical Research in Chinese Universities, 2021, 37(5): 1137-1142.
[11]	ZHANG Ling, FU Yihong, DING Yue, MENG Jiao, WANG Zhenchao, WANG Peiyi. Antibacterial Activity of Novel 18β-Glycyrrhetinic Hydrazide or Amide Derivatives [J]. Chemical Research in Chinese Universities, 2021, 37(3): 662-667.
[12]	DONG Xin, CHEN Xi, ZHOU Zhaohui. Efficient Synthesis of p-Hydroxyphenyl Ethanol from Hydrogenation of Methyl p-Hydroxyphenylacetate with CNTs-promoted Cu-Zr Catalyst [J]. Chemical Research in Chinese Universities, 2021, 37(3): 745-750.
[13]	LI Yuan, LI Ruizhe, LI Zhenhua, WEI Weiqin, OUYANG Shuxin, YUAN Hong, ZHANG Tierui. Effect of Support on Catalytic Performance of Photothermal Fischer-Tropsch Synthesis to Produce Lower Olefins over Fe₅C₂-based Catalysts [J]. Chemical Research in Chinese Universities, 2020, 36(6): 1006-1012.
[14]	ZHANG Baochang, LI Yulei, SHI Weiwei, WANG Tongyue, ZHANG Feng, LIU Lei. Chemical Synthesis of Proteins Containing 300 Amino Acids [J]. Chemical Research in Chinese Universities, 2020, 36(5): 733-747.
[15]	ZHAO Yanhui, YU Haifeng, LIAO Peiqiu, WANG Wenju. Green and Efficient Synthesis of 3-Pyrazolyl Indoles in Water [J]. Chemical Research in Chinese Universities, 2020, 36(5): 847-852.

Synthesis and Spectroscopic Characterization of Organothiophosphoryl Polyoxotungstates α-[C₆H₁₁P(S)]₂Xⁿ⁺W₁₁O₃₉^(8-n)- (Xⁿ⁺=P⁵⁺, Si⁴⁺, Ge⁴⁺, Ga³⁺)

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments