Glaser Coupling of Substituted Anthracene Diynes on a Non-metallic Surface at the Vapor-Solid Interface

doi:10.1007/s40242-021-1324-y

Chemical Research in Chinese Universities ›› 2021, Vol. 37 ›› Issue (5): 1143-1148.doi: 10.1007/s40242-021-1324-y

Glaser Coupling of Substituted Anthracene Diynes on a Non-metallic Surface at the Vapor-Solid Interface

FANG Yuan^1,2, HEYDARI Zahra², LIU Chenghao², ZHANG Nianyue¹, CUCCIA Louis A.⁴, IVASENKO Oleksandr^1,3, PEREPICHKA Dmitrii F.²

1. Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Institute of Functional Nano & Soft Materials(FUNSOM), Soochow University, Suzhou 215123, P. R. China;
2. Department of Chemistry, McGill University, 801 Sherbrooke Street West, Montreal, Québec, H3A 0B8, Canada;
3. Division of Molecular Imaging and Photonics, Department of Chemistry, KU Leuven-University of Leuven, Celestijnenlaan 200F, B-3001, Leuven, Belgium;
4. Department of Chemistry and Biochemistry, Concordia University, 7141 Sherbrooke St. W., Montreal, Québec, H4B 1R6, Canada

Received:2021-08-18 Revised:2021-09-07 Online:2021-10-01 Published:2021-09-07
Contact: PEREPICHKA Dmitrii F., FANG Yuan, IVASENKO Oleksandr E-mail:dmitrii.perepichka@mcgill.ca;yfang2000@suda.edu.cn;oleksandr.ivasenko@gmail.com
Supported by:
This work was supported by the Natural Sciences and Engineering Research Council of Canada(NSERC) Discovery Grants, the National Natural Science Foundation of China(No.22102110), the Natural Science Foundation of Jiangsu Province, China(No.SBK2021040457) and the NSERC Scholarship(No.PDF-532834-2019).

Abstract

Abstract: The direct polymerization via irreversible C-C coupling on inert substrates will give access to new low-dimensional advanced functional materials and simplify their industrial fabrication. In this work, we present our initial results in the application of Glaser coupling to the direct on-surface polymerization of a model diacetylene compound at the solid-vapor interface. The self-assembly of the monomer and polymerization products was characterized using scanning tunneling microscopy (STM). In addition, selected optical properties and the electronic structure of all compounds were investigated.

Key words: On-surface synthesis, Anthracene, Conjugated polymer, Molecular wire, Homocoupling of terminal alkynes

FANG Yuan, HEYDARI Zahra, LIU Chenghao, ZHANG Nianyue, CUCCIA Louis A., IVASENKO Oleksandr, PEREPICHKA Dmitrii F.. Glaser Coupling of Substituted Anthracene Diynes on a Non-metallic Surface at the Vapor-Solid Interface[J]. Chemical Research in Chinese Universities, 2021, 37(5): 1143-1148.

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Glaser Coupling of Substituted Anthracene Diynes on a Non-metallic Surface at the Vapor-Solid Interface

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