Synthesis and Investigation of Monoesters of Polymaleic Acids with Azo-Group

Chemical Research in Chinese Universities ›› 1997, Vol. 13 ›› Issue (4): 350-354.

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Synthesis and Investigation of Monoesters of Polymaleic Acids with Azo-Group

SU Feng-yu¹, LI Yan², TANG Jun², TIAN Yan-qing², ZHAO Ying-ying², ZHOU En-le¹

1. Polymer Physics Laboratory, Changchun Institute of Applied Chemistry 130022;
2. Department of Chemistry, Jilin University, Changchun 130023

Received:1996-09-17 Online:1997-12-24 Published:2011-08-17

Abstract

Abstract: A series of amphiphilic polymers, monoesters of polymaleic acid containing azo side groups (PMAN-A_n Me) was synthesized by the reaction of alcohol(A_n Me) with polymaleic anhydride (PMAN) for Langmuir-Blodgett assembly. The effects of the length of flexible spacer in the side chain on the π-A isotherms and LB films were investigated. The UV-Vis and infrared linear dichroism spectra showed that the azo-side groups were highly oriented in PMAN A-₆Me LB film deposited on silica or CaF₂ substrate.

Key words: Monoesters of polymaleic acids, LB film, Synthesis

SU Feng-yu, LI Yan, TANG Jun, TIAN Yan-qing, ZHAO Ying-ying, ZHOU En-le . Synthesis and Investigation of Monoesters of Polymaleic Acids with Azo-Group[J]. Chemical Research in Chinese Universities, 1997, 13(4): 350-354.

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Synthesis and Investigation of Monoesters of Polymaleic Acids with Azo-Group

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