Synthesis and Crystal Structure of trans(N)-(1,10-Phenanthroline)-bis (DL-Al aninato)-Cobalt(Ⅲ) Chloridetrihydrate

Chemical Research in Chinese Universities ›› 1993, Vol. 9 ›› Issue (3): 220-224.

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Synthesis and Crystal Structure of trans(N)-(1,10-Phenanthroline)-bis (DL-Al aninato)-Cobalt(Ⅲ) Chloridetrihydrate

YE Bao-hui, ZENG Tian-xian, HAN Ping, JI Liang-nian

Department of Chemistry, Zhongshan University, Guangzhou, 510275

Received:1992-11-13 Online:1993-08-24 Published:2011-08-17
Supported by:
Supported by the National Natural Science Foundation of China,Doctoral Program Foundation of Institution of High Education;Research Foundation of State Key Laboratory of Coordination Chemistry,Nanjing University

Abstract

Abstract: The title compound was synthesized by the reaction of cis-[Co(phen)₂Cl₂]Cl·3H₂O with DL-alanine at pH = 8, and isolated using a column chromatographic method. Its crystal structure was determined. The crystal structure belongs to mono-clinic system, space group P2₁/c, with a = 0. 9549(6) nm, b=2.3746(8) nm, c= 1.0782(4) nm, β=114.13(3)°, Z = 4, D_c= 1. 50 g/cm³. The final refinement converged to R = 0. 047 for 3246 independent observed reflections. In the octahedral coordination sphere formed by the cobalt atom and the coordinate atoms, N, O of DL-alan-inato ligands are in the configuration of trans-N,N form.

Key words: Phenanthroline, Alanine, Cobalt(Ⅲ) complex, Crystal structure

YE Bao-hui, ZENG Tian-xian, HAN Ping, JI Liang-nian . Synthesis and Crystal Structure of trans(N)-(1,10-Phenanthroline)-bis (DL-Al aninato)-Cobalt(Ⅲ) Chloridetrihydrate[J]. Chemical Research in Chinese Universities, 1993, 9(3): 220-224.

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Synthesis and Crystal Structure of trans(N)-(1,10-Phenanthroline)-bis (DL-Al aninato)-Cobalt(Ⅲ) Chloridetrihydrate

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