Chemical Research in Chinese Universities ›› 1993, Vol. 9 ›› Issue (2): 133-138.

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Synthesis, Structure and Properties of Co(NH2CSNHNH2)3Cl3·1/2HCl

LI Shu-jia,NIU Shu-yun, ZHANG Heng-bin, YANG Guang-di, LI Li, NIE Fu   

  1. Department of Chemistry, Institute of Theoretical Chemistry,Jilin University, Changchun 130023
  • Received:1992-04-13 Online:1993-04-24 Published:2011-08-17
  • Supported by:

    Supported by the National Natural Science Foundation of China

Abstract: The single crystal of title compound was obtained in the solution of DMFand CH3OHunder the radiation of IRlamp. The crystallographic parameters obtained are as follows: trigonal system, space group P31C, Z=4, a=b=1.0008(2)nm, c=2.4011 nm; final R=0.099, Rw=0.092. The properties of title compound were characterized by IR, UV, EPR, XPSand CVmeasurements.

Key words: Cobalt, Complex, Synthesis, Structure