Synthesis of a Magnetic Core-shell Fe3O4@Cu3(BTC)2 Catalyst and Its Application in Aerobic Olefin Epoxidation

doi:10.1007/s40242-023-3106-1

Abstract

Abstract: Olefin epoxidation is a fundamental reaction in organic chemistry. Herein, a novel magnetic core-shell Fe₃O₄@Cu₃(BTC)₂ metal-organic framework (MOF) heterogeneous catalyst was synthesized for the use in olefin epoxidation. Additionally, the size selectivity of the Fe₃O₄@Cu₃(BTC)₂ catalyst in olefin epoxidation was investigated. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) results indicated that Fe₃O₄@Cu₃(BTC)₂ presented a microsphere morphology, and Cu₃(BTC)₂ MOFs were well dispersed on the Fe₃O₄(PAA) surface after 10 cycles of the synthesis process. The synthesized magnetic core-shell Fe₃O₄@Cu₃(BTC)₂ heterogeneous catalyst could facilitate efficient aerobic olefin epoxidation. Furthermore, the catalyst was used in the aerobic oxidation of alcohols and was found to exhibit excellent activity for primary alcohols.

Key words: Core-shell, Metal-organic framework (MOF), Heterogeneous catalyst, Molecular oxygen, Olefin epoxidation, Alcohol oxidation

HOU Junying, HOU Chuanyuan, LI Jianchang, and HAO Jianjun. Synthesis of a Magnetic Core-shell Fe₃O₄@Cu₃(BTC)₂ Catalyst and Its Application in Aerobic Olefin Epoxidation[J]. Chemical Research in Chinese Universities, 2023, 39(6): 1044-1050.

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Synthesis of a Magnetic Core-shell Fe₃O₄@Cu₃(BTC)₂ Catalyst and Its Application in Aerobic Olefin Epoxidation

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