A Multifunctional Cobalt (II) Metal-Organic Framework with Nanoporous Channels for Gas and Dye Absorption, and Magnetic Performance

doi:10.1007/s40242-022-2263-y

Abstract

Abstract: Coordination polymer {[Co(BTIA)(H₂O)_0.5]·1.5CH₃OH}_n (Co-1) was synthesized from Co(NO₃)₂·6H₂O and multidentate ligand 4,6-bis-(4H-1,2,4-triazol-1-yl)-isophthalic acid (H2BTIA) under solvothermal conditions. Crystal analysis found that Co-1 was a (4⁴·6²)2(4¹⁶·6¹²) 3D framework with one dimensional channels, which gives it good adsorption performance for greenhouse gas CO2 and anionic dyes CR^2- and TY^-. In particular for the large-size CR^2-, it behaves a very fast removal rate. In addition, magnetic analysis discloses that antiferromagnetic (AF) coupling exists in binuclear cobalt unit.

Key words: Co (II) ion, Metal-organic framework (MOF), Gas adsorption, Dye adsorption, Congo red

CAO Weiwei, MA Zhilong, and TIAN Li. A Multifunctional Cobalt (II) Metal-Organic Framework with Nanoporous Channels for Gas and Dye Absorption, and Magnetic Performance[J]. Chemical Research in Chinese Universities, 2023, 39(6): 915-920.

References

[1] Furukawa H., Ko N., Go Y. B., Aratani N., Choi S. B., Choi E., Yazaydin A. O., Snurr R. Q., O'Keeffe M., Kim J., Yaghi O. M., Science, 2010, 329, 424
[2] Li J. R., Sculley J., Zhou H. C., Chem. Rev., 2012, 112, 869
[3] Li B., Wen H. M., Cui Y. J., Zhou W., Qian G. D., Chen B. L., Adv. Mater., 2016, 28, 8819
[4] Feng L., Wang K. Y., Day G. S., Ryder M. R., Zhou H. C., Chem. Rev., 2020, 120, 13087
[5] Wang K. Y., Feng L. G., Yan T. H., Wu S. X., Joseph E. A., Zhou H. C., Angew. Chem. Int. Ed., 2020, 59, 11349
[6] Lian X. Z., Fang Y., Joseph E., Wang Q., Li J. L., Banerjee S., Lollar C., Wang X., Zhou H. C., Chem. Soc. Rev., 2017, 46, 3386
[7] Wu D., Zhang P. F., Yang G. P., Hou L., Zhang W. Y., Han Y. F., Liu P., Wang Y. Y., Coord. Chem. Rev., 2021, 434, 213709
[8] Li L. B., Lin R. B., Krishna R., Li H., Xiang S. C., Wu H., Li J. P., Zhou W., Chen B. L., Science, 2018, 362, 443
[9] Lan T. H., Li L. B., Chen Y., Wang X. Q., Yang J. F., Li J. P., Adv. Mater., 2021, 33, 2100866
[10] Cui W. G., Zhang G. Y., Hu T. L., Bu X. H., Coor. Chem. Rev., 2019, 387, 79
[11] Wang T., Lin E., Peng Y. L., Chen Y., Cheng P., Zhang Z. J., Coord. Chem. Rev., 2020, 423, 213485
[12] Liao P. Q., Huang N. Y., Zhang W. X., Zhang J. P., Chen X. M., Science, 2017, 356, 1193
[13] Yi J. D., Xie R., Xie Z. L., Chai G. L., Liu T. F., Chen R. P., Huang Y. B., Cao R., Angew. Chem. Int. Ed., 2020, 59, 23641
[14] Hou S. L., Dong J., Zhao B., Adv. Mater., 2020, 32, 1806163
[15] Ding M., Flaig R. W., Jiang H. L., Yaghi O. M., Chem. Soc. Rev., 2019, 48, 2783
[16] Peng D., Yin L., Hu P., Li B., Ouyang Z. W., Zhuan G. L., Wang Z. X., Inorg. Chem., 2018, 57, 2577
[17] Liu J. H., Li L. D., Li X. X, Zhao D., Sun Y. Q., Zheng S. T., Chem. Commun., 2019, 55, 7394
[18] Pinkowicz D., Southerland H. I., Avendaño C., Prosvirin A., Sanders C., Wernsdorfer W., Pedersen K. S., Dreiser J., Clérac R., Nehrkorn J., Simeoni G., Schnegg A., Holldack K., Dunbar K. R., J. Am. Chem. Soc., 2015, 137, 14406
[19] Liu X. Q., Feng X. W., Meihaus K. R., Meng X. X., Zhang Y., Li L., Liu J. L., Pedersen K. S., Keller L., Shi W., Zhang Y. Q., Cheng P., Long J. R., Angew. Chem. Int. Ed., 2020, 59, 10610
[20] Ma Y. J., Hu J. X., Han S. D., Pan J., Li J. H., Wang G. M., J. Am. Chem. Soc., 2020, 142, 2682
[21] Sumida K., Rogow D. L., Mason J. A., McDonald T. M., Bloch E. D., Herm Z. R., Bae T. H., Long J. R., Chem. Rev., 2012, 112, 724
[22] Xiang S., He Y., Zhang Z., Wu H., Zhou W., Krishna R., Chen B., Nat. Commun., 2012, 3, 954
[23] Zhang Z. J., Yao Z. Z., Xiang S. C., Chen B. L., Energy Environ. Sci., 2014, 7, 2868
[24] Okesola B. O., Smith D. K., Chem. Soc. Rev., 2016, 45, 4226
[25] Zeng M. H., Yin Z., Tan Y. X., Zhang W. X., He Y. P., Kurmoo M., J. Am. Chem. Soc., 2014, 136, 4680
[26] Zou C., Zhang Z., Xu X., Gong Q., Li J., Wu C. D., J. Am. Chem. Soc., 2012, 134, 87
[27] Jia Y. Y., Ren G. J., Li A. L., Zhang L. Z., Feng R., Zhang Y. H., Bu X. H., Cryst. Growth Des., 2016, 16, 5593
[28] Zhou Y., Yao S., Ma Y. L., Li G. H., Huo Q. S., Liu Y. L., Chem. Commun., 2018, 54, 3006
[29] Yang X. M., Yan C. Y., Li Z. Y., Li X., Yu Q., Sang T. T., Gai Y. L., Zhang Q. F., Xiong K. C., Inorg. Chem., 2021, 60, 5988
[30] Wang X. S., Liang J., Li L., Lin Z. J., Bag P. P., Ga S. Y., Huang Y. B., Cao R., Inorg. Chem., 2015, 55, 2641
[31] Wu M. K., Yi F. Y., Fang Y., Xiao X. W., Wang S. C., Pan L. Q., Zhu S. R., Tao K., Han L., Cryst. Growth Des., 2017, 10, 5458
[32] Rodriguez A., Sakiyama H., Masciocchi N., Galli S., Galez N., Lloret F., Colacio E., Inorg. Chem., 2005, 44, 8399
[33] Li J. P., Li B. J., Pan M. T., Liu B., Cheng J. J., Li R. Y., Gao X. L., Wang S. M., Hou H. W., Liu Z. Y., Cryst. Growth Des., 2017, 17, 2975
[34] Caballero A. B., Rodriguez-Dieguez A., Lezama L., Barea E., Salas J. M., Dalt. Trans., 2011, 40, 5180
[35] Caballero A. B., Rodriguez-Dieguez A., Barea E., Quiros M., Salas J. M., CrystEngComm., 2010, 12, 3038
[36] Chen W. M., Meng X. L., Zhuang G. L., Wang Z., Kurmoo M., Zhao Q. Q., Wang X. P., Shan B. R., Tung C. H., Sun D., J. Mater. Chem. A, 2017, 5, 13079
[37] Wang X. P., Chen W. M., Qi H., Li X. Y., Rajnák C., Feng Z. Y., Kurmoo M., Boča R., Jia C. J., Tung C. H., Sun D., Chem. Eur. J., 2017, 23, 7990
[38] Zhou X. J., Liu L. L., Tai X. S., Zhang H., Chem. Res. Chinese Universities, 2018, 34(5), 723
[39] Park J., Li J. R., Sañudo E. C., Yuan D. Q., Zhou H. C., Chem. Commun., 2012, 48, 883
[40] Liu Z. Y., Zhao H., Song W. C., Wang X. G., Liu Z. Y., Zhao X. J., Yang E. C., J. Mater. Chem. C, 2019, 7, 191
[41] Shi W. J., Li Y. Z., Hu Q. X., Wang G. D., Hou L., Wang Y. Y., J. Solid State Chem., 2020, 283, 121170
[42] Chen K. J., Lin R. B., Liao P. Q., He C. T., Lin J. B., Xue W., Zhang Y. B., Zhang J. P., Chen X. M., Cryst. Growth Des., 2013, 13, 2118
[43] Liu B., Zhao R. L., Yang G. P., Hou L., Wang Y. Y., Shi Q. Z., CrystEngComm, 2013, 15, 2057
[44] Zhai Q. G., Lin Q., Wu T., Zheng S. T., Bu X. H., Feng P. Y., Chem. Mater., 2012, 24, 2624
[45] Ling Y., Yang F. L., Deng M. L., Chen Z. X., Liu X. F., Weng L. H., Zhou Y. M., Dalton Trans., 2012, 41, 4007
[46] Song Y., Fan R. Q., Xing K., Du X., Su T., Wang P., Yang Y. L., Cryst. Growth Des., 2017, 17, 2549
[47] Zhou Y., Yao S., Ma Y. L., Li G. H., Huo Q. S., Liu Y. L., Chem. Commun., 2018, 54, 3006
[48] Rabu P., Rueff J. M., Huang Z. L., Angelov S., Souletie J., Drillon M., Polyhedron, 2021, 20, 1677
[49] Rueff J. M., Masciocchi N., Rabu P., Sironi A., Skoulios A., Chem.―Eur. J., 2002, 8, 1813
[50] Rueff J. M., Masciocchi N., Rabu P., Sironi A., Skoulios A., Eur. J. Inorg. Chem., 2001, 2001, 2843