Stable Thiophene-sulfur Covalent Organic Frameworks for Oxygen Reduction Reaction(ORR)

doi:10.1007/s40242-022-1465-7

Abstract

Abstract: Exploring novel materials deriving from earth resources to substitute for platinum(Pt) electrocatalyst to promote oxygen reduction reaction(ORR) of fuel cell cathode is very important. Herein, we have exploited two crystallographic thiophene-sulfur covalent organic frameworks(COFs), termed JUC-607 and JUC-608, as electrocatalysts that exhibited good ORR performances. These thiophene-sulfur COFs exhibited high stability, and their functional groups acting as active centers in the ORR can be precisely determined. Notably, due to a larger aperture for mass transfer and electrons transport, JUC-608 displayed a growing electrochemical performance, leading to a better ORR activity. Thus, this study will provide a new strategy for designing heteroatom-based COF materials for high-performance electrochemical catalysis.

Key words: Covalent organic framework(COF), Oxygen reduction reaction, Thiophene-sulfur

CHANG Shunkai, LI Cuiyan, LI Hui, ZHU Liangkui, FANG Qianrong. Stable Thiophene-sulfur Covalent Organic Frameworks for Oxygen Reduction Reaction(ORR)[J]. Chemical Research in Chinese Universities, 2022, 38(2): 396-401.

References

[1] Li M., Zhao Z., Cheng T., Fortunelli A., Chen C.Y., Yu R., Zhang Q., Gu L., Merinov B. V., Lin Z., Zhu E., Yu T., Jia Q., Guo J., Zhang L., Goddard W. A. III, Huang Y., Duan X., Science, 2016, 354, 1414.
[2] Bu L., Zhang N., Guo S., Zhang X., Li J., Yao J., Wu T., Lu G., Ma J.-Y., Su D., Huang X., Science, 2016, 354, 1410.
[3] Guo D., Shibuya R., Akiba C., Saji S., Kondo T., Nakamura J., Science, 2016, 351, 361.
[4] Wan W., Wang Q., Zhang L., Liang H., Chen P., Yu S.-H., J. Mater. Chem. A,2016, 4, 8602.
[5] Fernandez J. L., Raghuveer V., Manthiram A., Bard A. J., J. Am. Chem. Soc., 2005, 127, 13100.
[6] Zhang J. L., Vukmirovic M. B., Sasaki K., Nilekar A. U., Mavrikakis M., Adzic R. R.,J. Am. Chem. Soc., 2005, 127, 12480.
[7] Zhang S., Shao Y., Yin G., Lin Y., J. Mater. Chem. A, 2013,1, 4631.
[8] Liang H. W., Zhuang X., Bruller S., Feng X., Mullen K., Nat. Commun.,2014, 5, 4973.
[9] Xia Z., An L., Chen P., Xia D., Adv. Ener. Mater., 2016, 6, 1600458.
[10] Wang W., Lv F., Lei B., Wan S., Luo M., Guo S., Adv. Mater., 2016, 28, 10117.
[11] Zhu Y.-N., Cao C.-Y., Jiang W.-J., Yang S.-L., Hu J.-S., Song W.-G., Wan L.-J., J. Mater. Chem. A, 2016, 4, 18470.
[12] Kone I., Xie A., Tang Y., Chen Y., Liu J., Chen Y., Sun Y., Yang X., Wan P., ACS Appl. Mater. Interfaces., 2017, 9, 20963.
[13] Amiinu I. S., Zhang J., Kou Z., Liu X., Asare O. K., Zhou H., Cheng K., Zhang H., Mai L., Pan M., Mu S., ACS Appl. Mater. Interfaces, 2016, 8, 29408.
[14] Li D., Jia Y., Chang G., Chen J., Liu H., Wang J., Hu Y., Xia Y., Yang D., Yao X., Chem, 2018, 4, 2345.
[15] Côte A. P., Benin A. I., Ockwig N. W., O'Keeffe M., Matzger A. J., Yaghi O. M., Science, 2005, 310, 1166.
[16] Ding S. Y., Wang W., Chem. Soc. Rev.,2013, 42, 548.
[17] Huang N., Wang P., Jiang D. L., Nat. Rev. Mater., 2016, 1, 16068.
[18] Diercks C. S., Yaghi O. M., Science, 2017, 355, 1585.
[19] Kuhn P., Antonietti M., Thomas A., Angew. Chem. Int. Ed., 2008, 47, 3450.
[20] Han S. S., Furukawa H., Yaghi O. M., Goddard W. A. III, J. Am. Chem. Soc., 2008, 130, 11580.
[21] Wang S., Wang Q., Shao P., Han Y., Gao X., Ma L., Yuan S., Ma X., Zhou J., Feng X., Wang B., J. Am. Chem. Soc., 2017, 139, 4258.
[22] Wan S., Guo J., Kim J., Ihee H., Jiang D., Angew. Chem. Int. Ed., 2008, 47, 8826.
[23] Du Y., Yang H., Whiteley J. M., Wan S., Jin Y., Lee S. H., Zhang W., Angew. Chem. Int. Ed., 2016, 55, 1737.
[24] Ding S. Y., Gao J., Wang Q., Zhang Y., Song W. G., Su C. Y., Wang W., J. Am. Chem. Soc.,2011, 133, 19816.
[25] Vyas V. S., Haase F., Stegbauer L., Savasci G., Podjaski F., Ochsenfeld C., Lotsch B. V., Nat. Commun., 2015, 6, 8508.
[26] Peng Y., Hu Z., Gao Y., Yuan D., Kang Z., Qian Y., Yan N., Zhao D., ChemSusChem., 2015, 8, 3208.
[27] Wang X., Han X., Zhang J., Wu X., Liu Y., Cui Y., J. Am. Chem. Soc., 2016, 138, 12332.
[28] Sun Q., Aguila B., Perman J., Nguyen N., Ma S. Q., J. Am. Chem. Soc., 2016, 138, 15790.
[29] Oh H., Kalidindi S. B., Um Y., Bureekaew S., Schmid R., Fischer R. A., Hirscher M., Angew. Chem. Int. Ed., 2013, 52, 13219.
[30] Chandra S., Kundu T., Kandambeth S., BabaRao R., Marathe M. Y., Kunjir S. M., Banerjee R.,J. Am. Chem. Soc., 2014, 136, 6570.
[31] Zhou T. Y., Xu S. Q., Wen Q., Pang Z. F., Zhao X., J. Am. Chem. Soc., 2014, 136, 15885.
[32] Cai S. L., Zhang Y. B., Pun A. B., He B., Yang J. H., Toma F. M., Sharp I. D., Yaghi O. M., Fan J., Zheng S. R., Zhang W. G., Liu Y., Chem. Sci., 2014, 5, 4693.
[33] Jin E. Q., Asada M., Xu Q., Dalapati S., Addicoat M. A., Brady M. A., Xu H., Nakamura T., Heine T., Chen Q. H., Jiang D. L., Scence, 2017, 357, 673.
[34] Guo Z. B., Zhang Y. Y., Dong Y., Li J., Li S. W., Shao P. P., Feng X., Wang B., J. Am. Chem. Soc., 2019, 141, 1923.
[35] Guan X. Y., Li H., Ma Y. C., Xue M., Fang Q. R., Yan Y. S., Valtchev V., Qiu S. L., Nat. Chem., 2019, 11, 587.
[36] Chang J. H., Xu G. J., Li H., Fang Q. R., Chem. J. Chinese Universities, 2020, 41(7), 1609.
[37] Li S. S., Zhao W. J., Li H., Fang Q. R.Chem. J. Chinese Universities, 2020, 41(6), 1384.
[38] Liang R. R., Cui F. Z., A R. H., Qi Q. Y., Zhao X., CCS Chem., 2020, 2, 139.
[39] Wang Z. T., Li H., Yan S. C., Fang Q. R., Acta Chimica Sinica, 2020, 78, 63.