A Nitrogen, Sulfur co-Doped Porphyrin-based Covalent Organic Framework as an Efficient Catalyst for Oxygen Reduction

doi:10.1007/s40242-021-1374-1

Abstract

Abstract: Oxygen reduction reaction(ORR) is a significant reaction for energy conversion systems(such as fuel cells, metal-air batteries, etc.). It is an urgent need to develop cheap, durable and highly-active catalysts for efficient ORR. Hence, we report a metal-free nitrogen and sulfur co-doped porphyrin-based covalent organic framework(COF) as a high-efficiency ORR catalyst[the onset potential(E_o) is 0.79 V and the half-wave potential(E_1/2) is 0.70 V]. The double doping of N and S atoms causes uneven charge distribution around carbon atoms, which can act as catalytic active centers, improving ORR activity. Compared with single-atom doping, double atoms doping exhibits a higher activity due to the synergistic effect between different elements. These results demonstrate that reasonable design of stable metal-free COFs with a high electrochemical activity can promote their wide applications.

Key words: Covalent organic framework(COF), Oxygen reduction reaction, co-Doped material

YU Xiaoming, MA Yunchao, LI Cuiyan, GUAN Xinyu, FANG Qianrong, QIU Shilun. A Nitrogen, Sulfur co-Doped Porphyrin-based Covalent Organic Framework as an Efficient Catalyst for Oxygen Reduction[J]. Chemical Research in Chinese Universities, 2022, 38(1): 167-172.

References

[1] Chu S., Cui Y., Nat. Mater., 2017, 16, 16
[2] Wang H. F., Xu Q., Matter., 2019, 1, 565
[3] Wang S. Y., Jiang S. P., Natl. Sci. Rev., 2017, 4, 163
[4] Dushina A., Schmies H., Schonvogel D., Int. J. Hydrog. Energy, 2020, 45, 35073
[5] Inoue H., Ishii T., Kannari N., Ozaki J. I., Chemistry Select, 2016, 1, 3189
[6] Fichtner J., Garlyyev B., Watzele S., El-Sayed H. A., Schwammlein J. N., Li W. J., Maillard F. M., Dubau L., Michaličkaet J., Macak J. M., Holleitner A., Bandarenka A. S., ACS Appl. Mater. Intefaces, 2019, 11, 5129
[7] Garapati M. S., Sundara R., Int. J. Hydrog. Energy, 2019, 44, 10951
[8] Wu D., Shen X., Pan Y., Yao L., Peng Z., CheNano-Mat., 2020, 6, 32
[9] Zhao Q., Wang C., Wang H., Wang J., Tang Y., Mao Z., Sasaki K., New J. Chem., 2020, 44, 3728
[10] Lu S., Huynh H. L., Lou F., Guo K., Yu Z., Nanoscale, 2021, 10,1039
[11] Wang Z., Zhao J., Cai Q., Li F., J. Mater. Chem. A, 2017, 5, 9842
[12] Liang H. W., Wei W., Wu Z. S., Feng X., Müllen K., J. Am. Chem. Soc., 2013, 135, 16002
[13] Wang X. X., Cullen D. A., Pan Y. T., Hwang S., Wang M., Feng Z., Wang J., Engelhard M. H., Zhang H., He Y., Shao Y., Su D., More K. L., Spendelow J. S., Wu G., Adv. Mater., 2018, 30, 1706758
[14] Dai L., Xue Y., Qu L., Choi H. J. Baek J. B., Chem. Rev., 2015, 115, 4823
[15] Liu X., Dai L., Nat. Rev. Mater., 2016, 1, 16064
[16] Frank B., Zhang J., Blume R., Schlӧgl R., Su D. D., Angew. Chem. Int. Ed., 2009, 48, 6913
[17] Zhao X., Wang A., Yan J., Sun G., Sun L., Zhang T., Chem. Mater., 2010, 22, 5463
[18] Chen S., Bi J., Zhao Y., Yang L., Zhang C., Ma Y., Wu Q., Wang X., Hu Z., Adv. Mater., 2012, 24, 5593
[19] Yu H., Shang L., Bian T., Shi R., Waterhouse G. I. N., Zhao Y., Zhou C., Wu L., Tung C. H., Zhang T., Adv. Mater., 2016, 28, 5080
[20] Jiang T., Jiang W., Li Y., Xu Y., Zhao M., Deng M., Wang Y., Carbon, 2021, 180, 92
[21] Cao Y., Zhu Y., Chen X., Abraha B. S., Peng W., Li Y., Zhang G., Zhang F., Fan X., Catal. Sci. Technol., 2019, 9, 6606
[22] Li D., Li C., Zhang L., Li H., Zhu L., Yang D., Fang Q., Qiu S., Yao X., J. Am. Chem. Soc., 2020, 142, 8104
[23] Liu Z., Nie H., Yang Z., Zhang J., Jin Z., Lu Y., Xiao Z., Huang S., Nanoscale, 2013, 5, 3283
[24] Wang Y., Lei Y., Wang H., RSC Adv., 2016, 6, 73560
[25] Zhang W., Wu Z. Y., Jiang H. L., Yu S. H., J. Am. Chem. Soc., 2014, 136, 14385
[26] Denisa H. J., Alexander M. P., Olga I. P., Fabian S. G., Tascón J. M. D., Gao Q. L., J. Am. Chem. Soc., 2009, 131, 5026
[27] Shi Q., Lei Y., Wang Y., Wang H., Jiang L., Yuan H., Fang D., Wang B., Wu N., Gou Y., Curr. Appl. Phys., 2015, 15, 1606
[28] Gong K., Du F., Xia Z., Michael D., Dai L., Science, 2009, 323, 760
[29] Liang J., Jiao Y., Jaroniec M., Qiao S. Z., Angew. Chem. Int. Ed., 2012, 51, 11496
[30] Zhu Y. N., Cao C. Y., Jiang W. J., Yang S. L., Hu J. S., Song W. G., Wan L. J., J. Mater. Chem., A, 2016, 4, 18470
[31] Yang C., Maenosono S., Duan J., Zhang X., ChemNanoMat, 2019, 5, 957
[32] Côté A. P., Benin A. I., Ockwig N. W., O' Keeffe M., Matzger A. J., Yaghi O. M., Science, 2005, 310, 1166
[33] Colson J. W., Dichtel W. R., Nat. Chem., 2013, 5, 453
[34] Huang N., Wang P., Jiang D. L., Nat. Rev. Mater., 2016, 1, 1
[35] Guan X., Chen F., Fang Q., Qiu S., Chem. Soc. Rev., 2020, 49, 1357
[36] Geng K., He T., Liu R., Dalapati S., Tan K. T., Li Z., Tao S., Gong Y., Jiang Q., Jiang D., Chem. Rev., 2020, 120, 8814
[37] Liang R. R., Cui F. Z., A R. H., Qi Q. Y., Zhao X., CCS Chem., 2020, 2, 139
[38] Kuhn P., Antonietti M., Thomas A., Angew. Chem. Int. Ed., 2008, 47, 3450
[39] Furukawa H., Yaghi O. M., J. Am. Chem. Soc., 2009, 131, 8875
[40] Li H., Pan Q., Ma Y., Guan X., Xue M., Fang Q., Yan Y., Valtchev V., Qiu S., J. Am. Chem. Soc., 2016, 138, 14783
[41] Chang J., Xu G., Li H., Fang Q., Chem. J. Chinese Universities., 2020, 41(7), 1609
[42] Fang Q., Zhuang Z., Gu S., Kaspar R. B., Zheng J., Wang J., Qiu S., Yan Y., Nat. Commun., 2014, 5, 4503
[43] Fang Q., Wang J., Gu S., Kaspar R. B., Zhuang Z., Zheng J., Guo H., Qiu S., Yan Y., J. Am. Chem. Soc., 2015, 137, 8352
[44] Wan S., Guo J., Kim J., Ihee H., Jiang D., Angew. Chem. Int. Ed., 2008, 47, 8826
[45] Guan X., Li H., Ma Y., Xue M., Fang Q., Yan Y., Valtchev V., Qiu S., Nat. Chem., 2019, 11, 587
[46] Li S., Zhao W., Li H., Fang Q., Chem. J. Chinese Universities., 2020, 41(6), 1384
[47] Wang Z. T., Li H., Yan S. C., Fang Q. R., Acta Chim. Sinica, 2020, 78, 63
[48] Keller N., Calik M., Sharapa D., Soni H. R., Zehetmaier P. M., Rager S., Auras F., Jakowetz A. C., Görling A., Clark T., Bein T., J. Am. Chem. Soc., 2018, 140, 16544
[49] Zou C., Wu C. D., Dalton Trans., 2012, 41, 3879
[50] Liang Z., Wang H. Y., Zheng H., Zhang W., Cao R., Chem. Soc. Rev., 2021, 50, 2540
[51] Accelrys Inc., Materials Studio Ver. 7.0, Accelrys Inc., San Diego, CA, 2013
[52] Sick T., Rotter J. M., Reuter S., Kandambeth S., Bach N. N., Döblinger M., Merz J., ClarkT., Marder T. B., Bein T., Medina D. D., J. Am. Chem. Soc., 2019, 141, 12570
[53] Pachfule P., Acharjya A., Roeser J., Sivasankaran R. P., Ye M., Brückner A., Schmidt J., Thomas A., Chem. Sci., 2019, 10, 8316
[54] Yang C., Tao S., Huang N., Zhang X., Duan J., Makiura R., Maenosono S., ACS Appl. Nano Mater., 2020, 3, 5481
[55] Royuela S., Martinez-Perinan E., Arrieta M. P., Chem. Commun., 2020, 56, 1267