Boron-doped Covalent Triazine Framework for Efficient CO2 Electroreduction

doi:10.1007/s40242-021-1384-z

Chemical Research in Chinese Universities ›› 2022, Vol. 38 ›› Issue (1): 141-146.doi: 10.1007/s40242-021-1384-z

• Articles • Previous Articles Next Articles

Boron-doped Covalent Triazine Framework for Efficient CO₂ Electroreduction

YI Jundong^2,3, LI Qiuxia^1,4, CHI Shaoyi^1,4, HUANG Yuanbiao^1,4,5, CAO Rong^1,4,5,6

1. College of Chemistry, Fuzhou University, Fuzhou 350108, P. R. China;
2. Institute of New Materials & Industry Technology, Wenzhou University, Wenzhou 325027, P. R. China;
3. School of Chemistry and Materials Science, Collaborative Innovation Center of Chemistry for Energy Materials(iChEM), University of Science and Technology of China, Hefei 230026, P. R. China;
4. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350025, P. R. China;
5. University of the Chinese Academy of Sciences, Beijing 100049, P. R. China;
6. Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou 350108, P. R. China

Received:2021-09-24 Revised:2021-10-22 Online:2022-02-01 Published:2021-11-15
Contact: HUANG Yuanbiao, CAO Rong E-mail:ybhuang@fjirsm.ac.cn；rcao@fjirsm.ac.cn
Supported by:
This work was supported by the National Key Research and Development Program of China(Nos.2018YFA0208600, 2018YFA0704502), the National Natural Science Foundation of China(Nos.21871263, 22071245, 22033008), the Fund of the Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China(No.2021ZZ103), and the Project of the Youth Innovation Promotion Association of the Chinese Academy of Sciences(No.Y201850).

Abstract

Abstract: Converting CO₂ into chemicals with electricity generated by renewable energy is a promising way to achieve the goal of carbon neutrality. Carbon-based materials have the advantages of low cost, wide sources and environmental friendliness. In this work, we prepared a series of boron-doped covalent triazine frameworks and found that boron doping can significantly improve the CO selectivity up to 91.2% in the CO₂ electroreduction reactions(CO₂RR). The effect of different doping ratios on the activity by adjusting the proportion of doped atoms was systematically investigated. This work proves that the doping modification of non-metallic materials is a very effective way to improve their activity, and also lays a foundation for the study of other element doping in the coming future.

Key words: Covalent triazine framework, CO₂ electroreduction, CO, B-doping

YI Jundong, LI Qiuxia, CHI Shaoyi, HUANG Yuanbiao, CAO Rong. Boron-doped Covalent Triazine Framework for Efficient CO₂ Electroreduction[J]. Chemical Research in Chinese Universities, 2022, 38(1): 141-146.

References

[1] Hepburn C., Adlen E., Beddington J., Carter E. A., Fuss S., MacDowell N., Minx J. C., Smith P., Williams C. K., Nature, 2019, 575(7781), 87
[2] Aresta M., Dibenedetto A., Angelini A., Chem. Rev., 2014, 114(3), 1709
[3] Goeppert A., Czaun M., Jones J. P., Surya Prakash G. K., Olah G. A., Chem. Soc. Rev., 2014, 43(23), 7995
[4] Bushuyev O. S., De Luna P., Dinh C. T., Tao L., Saur G., van de Lagemaat J., Kelley S. O., Sargent E. H., Joule, 2018, 2(5), 825
[5] Shah S. S. A., Najam T., Wen M., Zang S.-Q., Waseem A., Jiang H. L., Small Struct., 2021, 2100090
[6] Liang J., Wu Q., Huang Y. B., Cao R., EnergyChem, 2021, DOI:https://doi.org/10.1016/j.enchem.2021.100064
[7] Leow W. R., Lum Y., Ozden A., Wang Y., Nam D. H., Chen B., Wicks J., Zhuang T. T., Li F., Sinton D., Sargent E. H., Science, 2020, 368(6496), 1228
[8] Hou Y., Huang Y. B., Liang Y. L., Chai G. L., Yi J. D., Zhang T., Zang K. T., Luo J., Xu R., Lin H., Zhang S. Y., Wang H. M., Cao R., CCS Chem., 2019, 1(4), 384
[9] Yi J. D., Xie R., Xie Z. L., Chai G. L., Liu T. F., Chen R. P., Huang Y. B., Cao R., Angew. Chem. Int. Ed., 2020, 59(52), 23641
[10] Hou Y., Liang Y. L., Shi P. C., Huang Y. B., Cao R., Appl. Catal. B Environ., 2020, 271, 118929
[11] Zhang M. D., Si D. H., Yi J. D., Zhao S. S., Huang Y. B., Cao R., Small, 2020, 16(52), 2005254
[12] Jiao L., Yang W., Wan G., Zhang R., Zheng X., Zhou H., Yu S. H., Jiang H. L., Angew. Chem. Int. Ed., 2020, 59(46), 20589
[13] Zhu H. J., Lu M., Wang Y. R., Yao S. J., Zhang M., Kan Y. H., Liu J., Chen Y., Li S. L., Lan Y. Q., Nat. Commun., 2020, 11(1), 497
[14] Wu Q., Xie R. K., Mao M. J., Chai G. L., Yi J. D., Zhao S. S., Huang Y. B., Cao R., ACS Energy Lett., 2020, 5, 1005
[15] Yi J. D., Si D. H., Xie R., Yin Q., Zhang M. D., Wu Q., Chai G. L., Huang Y. B., Cao R., Angew. Chem. Int. Ed., 2021, 60(31), 17108
[16] Wu Q., Liang J., Xie Z. L., Huang Y. B., Cao R., ACS Mater. Lett., 2021, 3(5), 454
[17] Wu Q., Mao M. J., Wu Q. J., Liang J., Huang Y. B., Cao R., Small, 2021, 17(22), 2004933
[18] Zhang M. D., Si D. H., Yi J. D., Yin Q., Huang Y. B., Cao R., Sci. China Chem., 2021, 64(8), 1332
[19] Gong Y. N., Jiao L., Qian Y., Pan C. Y., Zheng L., Cai X., Liu B., Yu S. H., Jiang H. L., Angew. Chem. Int. Ed., 2020, 59(7), 2705
[20] Zhang Y., Jiao L., Yang W., Xie C., Jiang H. L., Angew. Chem. Int. Ed., 2021, 60(14), 7607
[21] Zhang L., Li X. X., Lang Z. L., Liu Y., Liu J., Yuan L., Lu W. Y., Xia Y. S., Dong L. Z., Yuan D. Q., Lan Y. Q., J. Am. Chem. Soc., 2021, 143(10), 3808
[22] Wang R., Liu J., Huang Q., Dong L. Z., Li S. L., Lan Y. Q., Angew. Chem. Int. Ed., 2021, 60(36), 19829
[23] Li Y., Zhou W., Wang H., Xie L., Liang Y., Wei F., Idrobo J. C., Pennycook S. J., Dai H., Nat. Nanotechnol., 2012, 7(6), 394
[24] Liu B., Shioyama H., Akita T., Xu Q., J. Am. Chem. Soc., 2008, 130(16), 5390
[25] Meng J., Niu C., Xu L., Li J., Liu X., Wang X., Wu Y., Xu X., Chen W., Li Q., Zhu Z., Zhao D., Mai L., J. Am. Chem. Soc., 2017, 139(24), 8212
[26] Qu L., Liu Y., Baek J. B., Dai L., ACS Nano, 2010, 4(3), 1321
[27] Huang H., Liang C., Sha H., Yu Y., Lou Y., Chen C., Li C., Chen X., Shi Z., Feng S., Chem. Res. Chinese Universities, 2019, 35(2), 171
[28] Yi J. D., Xu R., Wu Q., Zhang T., Zang K. T., Luo J., Liang Y. L., Huang Y. B., Cao R., ACS Energy Lett., 2018, 3(4), 883
[29] Wang Y., Tao L., Chen R., Li H., Su H., Zhang N., Liu Q., Wang S., Chem. Res. Chinese Universities, 2020, 36(3), 453
[30] He C., Liang J., Zou Y.-H., Yi J.-D., Huang Y.-B., Cao R., Natl. Sci. Rev., 2021, DOI 10.1093/nsr/nwab157
[31] Zou Y. H., Huang Y. B., Si D. H., Yin Q., Wu Q. J., Weng Z., Cao R., Angew. Chem. Int. Ed., 2021, 60(38), 20915
[32] Yi J. D., Xu R., Chai G. L., Zhang T., Zang K., Nan B., Lin H., Liang Y. L., Lv J., Luo J., Si R., Huang Y. B., Cao R., J. Mater. Chem. A, 2019, 7(3), 1252
[33] Yan B., Liu D., Feng X., Shao M., Zhang Y., Chem. Res. Chinese Universities, 2020, 36(3), 425
[34] Sun X., Kang X., Zhu Q., Ma J., Yang G., Liu Z., Han B., Chem. Sci., 2016, 7(4), 2883
[35] Song Y., Chen W., Zhao C., Li S., Wei W., Sun Y., Angew. Chem. Int. Ed., 2017, 56(36), 10840
[36] Liu T., Ali S., Lian Z., Si C., Su D. S., Li B., J. Mater. Chem. A, 2018, 6(41), 19998
[37] Chen C., Sun X., Yan X., Wu Y., Liu H., Zhu Q., Bediako B. B. A., Han B., Angew. Chem. Int. Ed., 2020, 59(27), 11123
[38] Zhang M. Di, Yi J. D., Huang Y. B., Cao R., Chinese J. Struct. Chem., 2021, 40(9), 1213
[39] Ma W., Xie S., Liu T., Fan Q., Ye J., Sun F., Jiang Z., Zhang Q., Cheng J., Wang Y., Nat. Catal., 2020, 3(6), 478
[40] Zhou Y., Che F., Liu M., Zou C., Liang Z., De Luna P., Yuan H., Li J., Wang Z., Xie H., Li H., Chen P., Bladt E., Quintero-Bermudez R., Sham T. K., Bals S., Hofkens J., Sinton D., Chen G., Sargent E. H., Nat. Chem., 2018, 10(9), 974
[41] Chen Y. Z., Wang C., Wu Z. Y., Xiong Y., Xu Q., Yu S. H., Jiang H. L., Adv. Mater., 2015, 27(34), 5010
[42] Wang M., Yang W., Li X., Xu Y., Zheng L., Su C., Liu B., ACS Energy Lett., 2021, 6(2), 379
[43] Kuhn P., Antonietti M., Thomas A., Angew. Chem. Int. Ed., 2008, 47(18), 3450
[44] Aijaz A., Akita T., Yang H., Xu Q., Chem. Commun., 2014, 50(49), 6498
[45] Huang Y. B., Pachfule P., Sun J. K., Xu Q., J. Mater. Chem. A, 2016, 4(11), 4273

Boron-doped Covalent Triazine Framework for Efficient CO₂ Electroreduction

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	WU Fan, LIU Pengxin. Surface Organometallic Chemistry for Single-site Catalysis and Single-atom Catalysis [J]. Chemical Research in Chinese Universities, 2022, 38(5): 1139-1145.
[2]	XU Guangyuan, LIU Qin, YAN Huan. Recent Advances of Single-atom Catalysts for Electro-catalysis [J]. Chemical Research in Chinese Universities, 2022, 38(5): 1146-1150.
[3]	BU Ran, LU Yingying, ZHANG Bing. Covalent Organic Frameworks Based Single-site Electrocatalysts for Oxygen Reduction Reaction [J]. Chemical Research in Chinese Universities, 2022, 38(5): 1151-1162.
[4]	WANG Guowei, KE Xiaoxing, SUI Manling. Advanced TEM Characterization for Single-atom Catalysts: from Ex-situ Towards In-situ [J]. Chemical Research in Chinese Universities, 2022, 38(5): 1172-1184.
[5]	MIAO Tianchang, DI Xin, HAO Feini, ZHENG Gengfeng, HAN Qing. Polymeric Carbon Nitride-based Single Atom Photocatalysts for CO₂ Reduction to C₁ Products [J]. Chemical Research in Chinese Universities, 2022, 38(5): 1197-1206.
[6]	LI Yang, WANG Xian, LIU Jie, JIN Zhao, LIU Changpeng, GE Junjie, XING Wei. Anode Catalytic Dependency Behavior on Ionomer Content in Direct CO Polymer Electrolyte Membrane Fuel Cell [J]. Chemical Research in Chinese Universities, 2022, 38(5): 1251-1257.
[7]	LIU Shuhui, ZHANG Fan, LIN Ronghe, LIU Wei. Full Metal Species Quantification of Metal Supported Catalysts Through Massive TEM Images Recognition [J]. Chemical Research in Chinese Universities, 2022, 38(5): 1263-1267.
[8]	QI Yuxue, LI Tingting, HU Yajie, XIANG Jiahong, SHAO Wenqian, CHEN Wenhua, MU Xueqin, LIU Suli, CHEN Changyun, YU Min, MU Shichun. Single-atom Fe Embedded Co₃S₄ for Efficient Electrocatalytic Oxygen Evolution Reaction [J]. Chemical Research in Chinese Universities, 2022, 38(5): 1282-1286.
[9]	GONG Yu, PAN Jing, ZHANG Lingling, WANG Xiao, SONG Shuyan, ZHANG Hongjie. Metal-Organic Frameworks-derived Indium Clusters/Carbon Nanocomposites for Efficient CO₂ Electroreduction [J]. Chemical Research in Chinese Universities, 2022, 38(5): 1287-1291.
[10]	WANG Wenyang, LIU Hanlin, YANG Caoyu, FAN Ting, CUI Chengqian, LU Xiaoquan, TANG Zhiyong, LI Guodong. Coordinating Zirconium Nodes in Metal-Organic Framework with Trifluoroacetic Acid for Enhanced Lewis Acid Catalysis [J]. Chemical Research in Chinese Universities, 2022, 38(5): 1301-1307.
[11]	HE Lulu, CHEN Xin, REN Yuanhang, YUE Bin, TSANG Shik Chi Edman, HE Heyong. Improving Catalytic Stability and Coke Resistance of Ni/Al₂O₃ Catalysts with Ce Promoter for Relatively Low Temperature Dry Reforming of Methane Reaction [J]. Chemical Research in Chinese Universities, 2022, 38(4): 1032-1040.
[12]	YU Yue, XI Zhixiang, ZHOU Bingjie, JIANG Binbo, LIAO Zuwei, YANG Yao, WANG Jingdai, HUANG Zhengliang, SUN Jingyuan, YANG Yongrong. Acidity Modification of ZSM-5 for Methane Conversion in Co-feeding Method with MTA Reaction [J]. Chemical Research in Chinese Universities, 2022, 38(4): 1012-1017.
[13]	XU Yanyan, LI Maogang, FENG Ting, JIAO Long, WU Fengtian, ZHANG Tianlong, TANG Hongsheng, LI Hua. Quantitative Analysis of Methanol in Methanol Gasoline by Calibration Transfer Strategy Based on Kernel Domain Adaptive Partial Least Squares(kda-PLS) [J]. Chemical Research in Chinese Universities, 2022, 38(4): 1057-1064.
[14]	ZONG Chen, LIU Guangnan, XU Wenhao, CHEN Jie, TANG Yun. Block Copolymer Supported Gold Nanoparticles Assemblies with Exposed Gold Surface [J]. Chemical Research in Chinese Universities, 2022, 38(4): 1118-1122.
[15]	SHI Rui, WEI Shuxian, CHENG Shiqi, ZENG Jinmin, WANG Yilin, SHU Xin. Colorimetric Detection of Glucose Using WO₃ Nanosheets as Peroxidase-mimetic Enzyme [J]. Chemical Research in Chinese Universities, 2022, 38(4): 985-990.