Block Copolymer Supported Gold Nanoparticles Assemblies with Exposed Gold Surface

doi:10.1007/s40242-022-1485-3

Chemical Research in Chinese Universities ›› 2022, Vol. 38 ›› Issue (4): 1118-1122.doi: 10.1007/s40242-022-1485-3

• Articles • Previous Articles

Block Copolymer Supported Gold Nanoparticles Assemblies with Exposed Gold Surface

ZONG Chen, LIU Guangnan, XU Wenhao, CHEN Jie, TANG Yun

Department of Chemistry, Laboratory of Advanced Materials, Shanghai Key Laboratory of Molecular Catalysis, Collaborative Innovation Center of Chemistry for Energy Materials, Fudan University, Shanghai 200438, P. R. China

Received:2021-12-06 Revised:2022-02-07 Online:2022-08-01 Published:2022-02-17
Contact: TANG Yun E-mail:yuntang@fudan.edu.cn
Supported by:
This work was supported by the National Key Research and Development Program of China(Nos.2017YFA0207303, 2018YFA0209401) and the National Natural Science Foundation of China(Nos.22088101, 22175039).

Abstract

Abstract: Polymer-involved nanoparticles or nanoparticle assemblies are now facing a crossroad, where the exposure of nanoparticle and multiple nanoparticles cannot be obtained at the same time. Therefore, a new series of nanoparticle clusters is synthesized, where multiple gold nanoparticles assemble with amphiphilic block copolymers supporting inside. The exposure of gold nanoparticles of the structure is confirmed and increases the reduction rate of 4-nitrophenol by 60%. The assemblies can also be used as surface enhanced Raman scattering(SERS) probes with an enhancement factor(EF) as high as 3×10³.

Key words: Gold nanoparticle, Block copolymer, co-Assembly

ZONG Chen, LIU Guangnan, XU Wenhao, CHEN Jie, TANG Yun. Block Copolymer Supported Gold Nanoparticles Assemblies with Exposed Gold Surface[J]. Chemical Research in Chinese Universities, 2022, 38(4): 1118-1122.

References

[1] Xia Y., Xiong Y., Lim B., Skrabalak S. E. S., Angew. Chem. Int. Ed.,2009, 48,60
[2] Dong Q., Li G., Ho C., Faisal M., Leung C., Pong P. W., Liu K., Tang B., Manners I., Wong W., Adv. Mater., 2012,24,1034
[3] Meng Z., Ho C., Wong H., Yu Z., Zhu N., Li G., Leung C., Wong W.,Sci. China Mater.,2019,62, 566
[4] Meng Z., Xiao F., Wei Z., Guo X., Zhu Y., Liu Y., Li G., Yu Z., Shao M., Wong W., Nano Res.,2019,12, 2954
[5] Meng Z., Li G., Yiu S., Zhu N., Yu Z., Leung C., Manners I., Wong W., Angew. Chem. Int. Ed.,2020,59, 11521
[6] Jiang N., Zhuo X., Wang J., Chem. Rev.,2018, 118, 3054
[7] Wu X., Hao, C., Kumar J., Kuang H., Kotov N. A., Liz Marzan L. M., Xu C., Chem., Soc. Rev.,2018, 47, 4677
[8] Christopher P., Xin H., Linic S.,Nat. Chem.,2011, 3, 467
[9] Kelly K. L., Coronado E., Zhao L. L., Schatz G. C., J. Phys. Chem. B,2003, 107, 668
[10] Yi C., Yang Y. Q., Liu B., He J., Nie Z. H., Chem. Soc. Rev.,2020, 49,465
[11] Kao J., Throkelsson K., Bai P., Rancatore B. J., Chem. Soc. Rev.,2013, 42, 2654
[12] Dong Q., Meng Z., Ho C., Guo H., Yang W., Manners I., Xu L., Wong W.,Chem. Soc. Rev., 2018, 47, 4934
[13] Chen G., WangY., Chen H. Y., J. Am. Chem. Soc.,2010, 132(11), 3644
[14] Tan L. H., Xing S. X., Chen H. Y., ACS Nano, 2009,3(11),3469
[15] Ji X. H., Song X. N., Li J., Bai Y. B., Yang W. S., Peng X. G., J. Am. Chem. Soc.,2007, 129(45), 13939
[16] Tan L. H., Xing H., Xing H., Chen H. Y., Lu Y., J. Am. Chem. Soc.,2013, 135(47), 17675
[17] Kim H., Kim J., Jo S., Lee C., Lee W., Park S., Chung B., Yoo S., Soft Matter, 2015, 11, 4402
[18] Chen T., Yang M. X., Chen H. Y., J. Am. Chem. Soc.,2008, 130,11858
[19] Guo Z., Wang X., Angew. Chem., Int. Ed.,2018, 57, 5898
[20] Zhou T. Y., Zhu J. Y., Gong L. S., Nong L. T., Liu J. B., J. Am. Chem. Soc., 2019, 141, 7, 2852
[21] Aditya T., Pal A., Pal T., Chem. Commun.,2015, 51, 9410
[22] Praharaj S., Nath S., Ghosh S. K., Kundu S., Pal T.,Langmuir,2009,20, 9889
[23] Hayakawa K., Yoshimura T., Esumi K.,Langmuir, 2003,19, 5517
[24] Sun H., Xu W., Chen J., Zhang H., Yu J., Zong C., Yang J., Zhong Z., Tang Y., J. Colloid Interf. Sci.2021, 601, 773
[25] Larm N. E., Bhawawet N., Thon J. A., Baker G. A., New J. Chem.,2019, 43, 17932
[26] Alvarez-Puebla R. A., Dos Santos D. S., Aroca R. F., Analyst, 2004, 129,1251
[27] Yang M. X., Chen T., Lau W. S., Wang Y., Tang Q. H., Yang Y. H., Chen H. Y., Small,2009, 5, 198
[28] Kundu S., Yi S. I., Ma L., Chen Y. Y., Dai W., Sinyukov A. M., Liang H., Dalton Tans.,2017, 46, 9678

Block Copolymer Supported Gold Nanoparticles Assemblies with Exposed Gold Surface

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	YANG Shaobo, CAO Yuanyuan, WANG Shuqi, LI Yongsheng, SHI Jianlin. Understanding on the Surfactants Engineered Morphology Evolution of Block Copolymer Particles and Their Precise Mesoporous Silica Replicas [J]. Chemical Research in Chinese Universities, 2022, 38(1): 99-106.
[2]	LONG Qipeng, YU Hanyang, LI Zhe. Reconfigurable Plasmonic Nanostructures Controlled by DNA Origami [J]. Chemical Research in Chinese Universities, 2020, 36(2): 296-300.
[3]	DONG Pengfei, LI Na, ZHAO Haiyan, CUI Min, ZHANG Cong, HAN Hongyan, REN Jujie. POMs as Active Center for Sensitively Electrochemical Detection of Bisphenol A and Acetaminophen [J]. Chemical Research in Chinese Universities, 2019, 35(4): 592-597.
[4]	ZHENG Jingyi, FENG Rongrong, HE Caimei and LI Xiaoxia. Graphene-Gold Nanoparticle-modified Electrochemical Sensor for Detection of Kanamycin Based on Target-induced Aptamer Displacement [J]. Chemical Research in Chinese Universities, 2018, 34(6): 952-958.
[5]	WANG Shumin, YAN Xiaoxia, ZHU Yan, DENG Dongmei, HE Haibo, LUO Liqiang. Au Nanoparticles Loaded on Hollow TiO₂ Microspheres with (001) Exposed Facets: a Strategy for Promoting Photocatalytic Performance [J]. Chemical Research in Chinese Universities, 2018, 34(5): 705-710.
[6]	SUN Rui, WANG Ying, GOU Pengfei, ZUO Min, LI Xiaodong, ZHU Weipu, SHEN Zhiquan. Amphiphilic Seven-arm Star Triblock Copolymers with Diverse Morphologies in Aqueous Solution Induced by Crystallization and pH [J]. Chemical Research in Chinese Universities, 2018, 34(1): 132-137.
[7]	HUANG Hailiang, ZU Xihong, YI Guobin, ZHONG Benbin, LUO Hongsheng. Nanopattern Transformation of ABC Triblock Copolymer Thin Films Induced by Strong Solvent Selectivity and Annealing [J]. Chemical Research in Chinese Universities, 2017, 33(4): 684-688.
[8]	FENG Huiyun, GAO Lei, YE Xinhui, WANG Lei, XUE Zechun, KONG Jinming, LI Lianzhi. Synthesis of a Heptapeptide and Its Application in the Detection of Mercury(II) Ion [J]. Chemical Research in Chinese Universities, 2017, 33(2): 155-159.
[9]	MA Xiaoyu, YANG Jianmao, CAI Wenshu, ZHU Guodong, LIU Jianyun. Preparation of Au Nanoparticles Decorated Polyaniline Nanotube and Its Catalytic Oxidation to Ascorbic Acid [J]. Chemical Research in Chinese Universities, 2016, 32(4): 702-708.
[10]	ZHOU Chao, MU Ying, YANG Meng-chao, WU Qing-qing, XU Wei, ZHANG Ying, JIN Wei, SONG Qi, WU Zhong-yu, JIN Qin-han. Gold Nanoparticles Based Colorimetric Detection of Target DNA After Loop-mediated Isothermal Amplification [J]. Chemical Research in Chinese Universities, 2013, 29(3): 424-428.
[11]	WANG Hong, ZHU Yue-jun, REN Xiao-na, ZHANG Hong, TAN Ye-bang. Synthesis and Characterization of pH-Responsive Block Copolymers with Primary Amine Groups [J]. Chemical Research in Chinese Universities, 2013, 29(2): 389-395.
[12]	WU Shao-gui, DU Ting-ting. Dissipative Particle Dynamics Simulation of Onion Phase in Star-block Copolymer [J]. Chemical Research in Chinese Universities, 2013, 29(1): 171-176.
[13]	HOU Qiong, WANG Jin-e, LIU Xia, LI Xiao-kun, MA Li-na, DUAN Wu-biao, WANG Zhen-xin. Detection of Lectins by Saccharide-gold Nanoparticle Conjugates [J]. Chemical Research in Chinese Universities, 2012, 28(6): 947-952.
[14]	TENG Hong, LIU Yang and YOU Tian-yan*. Facile Synthesis of Gold Nanoparticle-loaded Carbon Nanofiber Composites and Their Electrocatalytic Activity Towards Dopamine, Ascorbic Acid and Uric Acid [J]. Chemical Research in Chinese Universities, 2011, 27(3): 496-499.
[15]	WANG Jin-e, WANG Cheng-ke, LIU Dian-jun and WANG Zhen-xin*. Lectin Conjugated Gold Nanoparticle-based Colorimetric Assay for Studying the Interactions of Antibiotic with Living Cell [J]. Chemical Research in Chinese Universities, 2011, 27(2): 193-197.