A Novel Metal-organic Framework Using Heterometallic Tetranuclear Cluster as Secondary Building Block and Isophthalic Acid as Ligand

doi:10.1007/s40242-016-6221-4

Abstract

Abstract:

A novel heterometallic-organic framework(HMOF), namely [ZnBa(1,3-BDC)₂(DMA)₂]_n(1)(DMA=N,N-dimethylacetamide), was synthesized by means of solvothermal method from isophthalic acid(1,3-BDC) ligand and relevant metal salts as raw materials. The single-crystal X-ray diffraction analysis result demonstrates that compound 1 is a three-dimensional(3D) framework including heterometallic tetranuclear[Zn₂Ba₂(COO)₈] clusters as building subunits, which could be simplified into an eight-connected body-centered cubic(bcu) topological net. At room temperature, compound 1 displays strong blue luminescence in solid state. Furthermore, the quantum yield and luminescent lifetime of compound 1 were also measured.

Key words: Barium, Isophthalic acid, Solvothermal, Luminescence property, Heterometallic-organic framework

BAI Helong, ZHANG Daojun, ZHANG Renchun, WANG Junjie, ZENG Shuangli, FAN Yong, XU Jianing, ZHANG Ping. A Novel Metal-organic Framework Using Heterometallic Tetranuclear Cluster as Secondary Building Block and Isophthalic Acid as Ligand[J]. Chemical Research in Chinese Universities, 2016, 32(5): 709-712.

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