Solvothermal Synthesis of Magnetic Fe3O4 Nanospheres and Their Efficiency in Photo-Fenton Degradation of Xylenol Orange

doi:10.1007/s40242-017-6493-3

Chemical Research in Chinese Universities ›› 2017, Vol. 33 ›› Issue (4): 648-654.doi: 10.1007/s40242-017-6493-3

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Solvothermal Synthesis of Magnetic Fe₃O₄ Nanospheres and Their Efficiency in Photo-Fenton Degradation of Xylenol Orange

ZHENG Kai¹, DI Mingyu¹, ZHANG Jubo¹, BAO Wenhui¹, LIANG Daxin¹, PANG Guangsheng², FANG Zhenxing², LI Chunyuan¹

1. College of Materials Science and Engineering, Northeast Forestry University, Harbin 150040, P. R. China;
2. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China

Received:2016-12-16 Revised:2017-03-03 Online:2017-08-01 Published:2017-04-11
Contact: LIANG Daxin E-mail:daxin.liang@nefu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China（No.31400497），the Fundamental Research Funds for the Central Universities，China（No.2572017BB14），the Heilongjiang Postdoctoral Financial Assistance，China（No.LBH-Z13001），the General Financial Grant from the China Postdoctoral Science Foundation，China（No.2014M561311） and the Open Project of State Key Laboratory of Inorganic Synthesis and Preparative Chemistry，China（No.2016-24）.

Abstract

Abstract:

Magnetic Fe₃O₄ nanospheres with a average diameter of (201±0.5) nm were synthesized at 200℃ via a solvothermal method. The as-synthesized Fe₃O₄ nanospheres performed an efficiency in the Fenton degradation of xylenol orange with a degradation rate of 90%-95%. Additionally, the catalyst was easily recyclable and the recovery rate was greater than 90%. Moreover, the catalyst could be regenerated under an ultrasonic treatment, and the degradation performance remained essentially the same. More importantly, the degradation rate varied with respect to the amount of H₂O₂ and the pH of the best reaction process. And the reaction efficiency was achieved with 1.5 mL of H₂O₂ in an acidic environment.

Key words: Magnetic, Fe₃O₄ nanosphere, Fenton degradation, Solvothermal synthesis, Xylenol orange

ZHENG Kai, DI Mingyu, ZHANG Jubo, BAO Wenhui, LIANG Daxin, PANG Guangsheng, FANG Zhenxing, LI Chunyuan. Solvothermal Synthesis of Magnetic Fe₃O₄ Nanospheres and Their Efficiency in Photo-Fenton Degradation of Xylenol Orange[J]. Chemical Research in Chinese Universities, 2017, 33(4): 648-654.

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Solvothermal Synthesis of Magnetic Fe₃O₄ Nanospheres and Their Efficiency in Photo-Fenton Degradation of Xylenol Orange

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