Synthesis, Structures and Properties of Two Complexes Based on Benzimidazole or Benzothiazole Ligand

doi:10.1007/s40242-014-3434-2

Abstract

Abstract:

Two complexes, Co(Hbim)₂(NCS)₂(Hbim=benzimidazole)(1) and [Cu(Hbzt)SCN]_n(Hbzt=benzothiazole) (2) were synthesized by the same synthesis method and characterized by elemental analysis, infrared spectroscopy(IR), thermogravimetric analysis(TGA), X-ray powder diffraction(XRPD) and single-crystal X-ray diffraction. The results from the single-crystal X-ray diffraction indicate that complex 1 is zero-dimensional(0D) framework and complex 2 is 2-dimensional(2D) framework. In complex 2, the 3-dimensional(3D) supermolecular architecture was built up by means of π-π stacking interaction, and two helical chains existed in its structure. The luminescence properties and the magnetic properties of the two complexes were investigated.

Key words: Chemical synthesis, Crystal structure, Luminescence property, Magnetic property

ZHANG Zhongqiang, DI Di, ZHAI Jingshuo, WU Lili, ZHU Qinlei, XU Yanqing, HUANG Rudan. Synthesis, Structures and Properties of Two Complexes Based on Benzimidazole or Benzothiazole Ligand[J]. Chemical Research in Chinese Universities, 2014, 30(2): 185-189.

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