Highly Sensitive and Selective Chemosensor for Cu2+ Based on a Schiff Base

doi:10.1007/s40242-013-2449-4

Abstract

Abstract:

A new chemosensor based on a Schiff base has been designed and synthesized. Its sensing behavior toward various metal ions was investigated by fluorescence and UV-Vis spectroscopic methods. The fluorescence of the sensor was quenched and the color rapidly changed from canary yellow to brown after the addition of Cu²⁺, while no changes occurred after the addition of other metal ions, which contributes to the detection of Cu²⁺ with naked eyes. The fluorescence quantum yield of the ligand was calculated to be 0.52. The corresponding detection limit of Cu²⁺ was 5.721×10^-7mol/L, and the 1:1 binding mode of the sensor with Cu²⁺was revealed by Job's plot.

Key words: Chemosensor, Schiff base, Copper ion, Naked-eye detection, Quench

CAO Ben-nan, HU Qin, HUANG Yan, JIA Chun-man, ZHANG Qi. Highly Sensitive and Selective Chemosensor for Cu²⁺ Based on a Schiff Base[J]. Chemical Research in Chinese Universities, 2013, 29(3): 419-423.

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Highly Sensitive and Selective Chemosensor for Cu²⁺ Based on a Schiff Base

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