Thermal and Optoelectronic Properties of Anthracene and Dibenz[a,c]Anthracene

doi:10.1007/s40242-013-2264-y

Abstract

Abstract:

The basic characteristics of anthracene(AN) and dibenz[a,c]anthracene(D[a,c]A) derivatives, important semiconductors, were systematically studied. Differential scanning calorimetry(DSC) shows that D[a,c]A has the reversibility of solid and liquid phases. Thermalgravimetric analysis(TGA) shows that D[a,c]A exhibits higher T_d(decomposition temperature), which indicates D[a,c]A, as active layers, should be more suitable to being made into stable devices. D[a,c]A shows blue-shifted UV-Vis absorption and emission despite increased conjugation compared to anthracene due to different symmetries. Both the compounds are planar and show weak blue fluorescence in the tetrahydrofuran(THF) solution and higher fluorescence in the solid-state, due to different energy levels in solution and solid-state, explained via Jablonski diagram.

Key words: Anthracene, Dibenz[a,c]anthracene, Molecular property, Thermal, Electrochemistry

MUDDASIR Hanif, WANG Zhi-ming, YANG Bing, LU Ping, MA Yu-guang. Thermal and Optoelectronic Properties of Anthracene andDibenz[a,c]Anthracene[J]. Chemical Research in Chinese Universities, 2013, 29(1): 110-115.

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Thermal and Optoelectronic Properties of Anthracene andDibenz[a,c]Anthracene

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