Preparation, Structure and Magnetic Properties of Lithium Substituted NiO by Molten Salt Method

doi:10.1007/s40242-013-2159-y

Chemical Research in Chinese Universities ›› 2013, Vol. 29 ›› Issue (2): 210-213.doi: 10.1007/s40242-013-2159-y

• Articles • Previous Articles Next Articles

Preparation, Structure and Magnetic Properties of Lithium Substituted NiO by Molten Salt Method

DU Fei¹, BIE Xiao-fei¹, BIAN Xiao-fei², HU Fang³, CHEN Gang¹, WANG Chun-zhong¹, WEI Ying-jin¹

1. Key Laboratory of Advanced Batteries Physics and Technology, Ministry of Education, College of Physics, Jilin University, Changchun 130012, P. R. China;
2. School of Materials Science and Engineering, Changchun University of Science and Technology, Changchun 130022, P. R. China;
3. School of Materials Science and Engineering, Shenyang University of Technology, Shenyang 110870, P. R. China

Received:2012-04-23 Revised:2012-06-25 Online:2013-04-01 Published:2013-03-20
Supported by:
Supported by the Special Funds for Major National Basic Research Project of China(No.2009CB220104), the National Natural Science Foundation of China(No.11004073) and the Research Fund for the Doctoral Program of Higher Education of China(New Teacher)(No.20090061120020) and Partially Supported by the Development Program of Science and Technology of Jilin Province, China(No.201205035).

Abstract

Abstract:

A typical Li⁺ substituted NiO compound, Li_0.29Ni_0.71O, was synthesized by molten nitrate method. The effects of Li⁺ substitution on the structure and magnetic properties of NiO were investigated. X-Ray diffraction(XRD), scanning electron microscope(SEM) and high-resolution transmission electron microscope(HRTEM) analyses confirm the cubic structure of Li_0.29Ni_0.71O, with a primary particle size of 150 nm. Analysis of the Ni X-ray photoelectron spectroscopy(XPS) shows the transformation from Ni²⁺ to Ni³⁺ induced by Li⁺ substitution. Two magnetic transitions were observed at 225 and 55 K which were assigned to the ferrimagnetic ordering and spin glass transition, respectively. The different magnetic behavior with respect to that of NiO was attributed to the break of superexchange interaction Ni²⁺-O-Ni²⁺ and the formation of different spin clusters after non-magnetic Li⁺ doping.

Key words: NiO, Magnetic property, Substitution effect

DU Fei, BIE Xiao-fei, BIAN Xiao-fei, HU Fang, CHEN Gang, WANG Chun-zhong, WEI Ying-jin. Preparation, Structure and Magnetic Properties of Lithium Substituted NiO by Molten Salt Method[J]. Chemical Research in Chinese Universities, 2013, 29(2): 210-213.

References

[1] Kanno R., Kubo H., Kawamoto Y., Kamiyama T., Izumi F., Takeda Y., Takano M., J. Solid State Chem., 1994, 110, 216

[2] Nagasaka Y., Ohta H., Kawakami K., Ueda A., Ono S., Ikeuchi Y., Nanba T., Hirano A., Kanno R., J. Phys. Chem. Solid, 2003, 64, 1949

[3] Morales J., Perez V. C., Tirado J. L., Mater. Res. Bull., 1990, 25, 623

[4] Li W., Reimers J. N., Dahn J. R., Phys. Rev. B, 1992, 46, 3236

[5] Wang C. W., Ma X. L., Li Z. C., Liang Y. G., Sun J. T., Zhou Y. H., Electrochem. Commun., 2006, 8, 289

[6] Huang X. H., Tu J. P., Zhang B., Zhang C. Q., Li Y., Yuan Y. F., Wu H. M., J. Power Sources, 2006,161, 541

[7] Huang X. H., Tu J. P., Zhang C. Q., Xiang J. Y., Electrochem. Commun., 2007, 9, 1180

[8] Sung W. O., Hyun J. B., Young C. B., Yang K. S., J. Power Sources, 2007, 173, 502

[9] Rahman M. M., Chou S. L., Zhong C., Wang J. Z., Wexler D., Liu H. K., Solid State Ionics, 2010, 180, 1646

[10] Belhomme C., Cassir M., Devynck J., Gregoire G., J. Mater. Sci., 2000, 35, 2683

[11] Bajpai A., Banerjee A., J. Phys.: Condens. Matter, 2001,13, 637

[12] Seehra M. S., Phys. Rev. B, 1988, 38, 11898

[13] Manna S., De S. K., Sol. Stat. Commun., 2009, 149, 297

[14] van Elp J., Eskes H., Kuiper P., Sawatzky G. A., Phys. Rev. B, 1992, 45, 1612

[15] Wu J., Nan C. W., Lin Y. H., Deng Y., Phys. Rev. Letts., 2002, 89, 217601

[16] Antolini E., Mater. Chem. Phys., 2003, 82, 937

[17] Arai H., Tsuda M., Saito K., Hayashi M., Takei H., Sakurai Y., J. Solid State Chem., 2002, 163, 340

[18] Soriano L., Preda I., Gutierrez A., Palacin S., Abbate M., Phys. Rev. B, 2007, 75, 233417

[19] Liu H. S., Li J., Zhang Z. R., Gong Z. L., Yang Y., Electrochem. Acta, 2004, 49, 1151

[20] Kim H. J., Lee J. B., Kim Y. M., Jung M. H., Jaglicic Z., Umek P., Dolinsek J., Nanoscale Res. Lett., 2007, 2, 81

[21] Pena O., Guilloux V. M., Antunes A. B., Peng W., Ma Y. W., Gao Z. S., Moure C., J. Magn. Magn. Mater., 2009, 321, 1723

[22] Auslous M., Elliot R. J., Magnetic Phase Transitions, Springer- Verlag, Berlin, 1983, 99

[23] Wang D. P., Chen. H., Du F., Bie X. F., Liu L. N., Wei Y. J., Chen G., Wang C. Z., Chem. Res. Chinese Universities, 2010, 26(2), 283

[24] Liu N., Yan G. Q., Xu S. J., Chem. Res. Chinese Universities, 2005, 21(6), 707

Preparation, Structure and Magnetic Properties of Lithium Substituted NiO by Molten Salt Method

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	DI Zhengyi, MAO Yining, YUAN Heng, ZHOU Yan, JIN Jun, LI Cheng-Peng. Covalent Organic Frameworks(COFs) for Sequestration of⁹⁹TcO₄^– [J]. Chemical Research in Chinese Universities, 2022, 38(2): 290-295.
[2]	LI Ru, ZHANG Mingjia, LI Xiaodong, MA Xiaodi, HUANG Changshui. Study of Graphdiyne-based Magnetic Materials [J]. Chemical Research in Chinese Universities, 2021, 37(6): 1257-1267.
[3]	LEI Huijin, ZHANG Xinlu, JIN Jiongke, WANG Shuhua, DING Shunmin, ZHANG Ning, CHEN Chao. Highly Uniform Alkali Doped Cobalt Oxide Derived from Anionic Metal-Organic Framework: Improving Activity and Water Tolerance for CO Oxidation [J]. Chemical Research in Chinese Universities, 2020, 36(5): 946-954.
[4]	ZHOU Rui, LI Tingting, ZHANG Lijian, JIAO Xinqian. Reduction Removal of Cr(VI) from Wastewater by CO₂^·- Deriving from Formate Anion Based on Activated Carbon Catalyzed Persulfate [J]. Chemical Research in Chinese Universities, 2020, 36(5): 870-876.
[5]	CUI Min, REN Jujie, WEN Xiaofang, LI Na, XING Yifei, ZHANG Cong, HAN Yuanyuan, JI Xueping. Electrochemical Detection of Superoxide Anion Released by Living Cells by Manganese(III) Tetraphenyl Porphine as Superoxide Dismutase Mimic [J]. Chemical Research in Chinese Universities, 2020, 36(5): 774-780.
[6]	KIPKORIR Peter, TAN Ling, REN Jing, ZHAO Yufei, SONG Yu-Fei. Intercalation Effect in NiAl-layered Double Hydroxide Nanosheets for CO₂ Reduction Under Visible Light [J]. Chemical Research in Chinese Universities, 2020, 36(1): 127-133.
[7]	LIU Yike, LONG Yanhui, TANG Yaqin, GU Zhenhua, LI Kongzhai. Effect of Preparation Method on the Structural Characteristics of NiO-ZrO₂ Oxygen Carriers for Chemical-looping Combustion [J]. Chemical Research in Chinese Universities, 2019, 35(6): 1024-1031.
[8]	ZHONG Liangxuan, LIU Mingyue, ZHANG Bowei, SUN Yaqiu, XU Yanyan. Syntheses, Crystal Structures, Magnetic and Near-infrared Luminescence Properties of 3d-4f Coordination Polymers Cu₂Pr₂, Cu₂Eu₂ and Cu₄Tb₂ [J]. Chemical Research in Chinese Universities, 2019, 35(4): 693-699.
[9]	ZHAO Shengxiang, ZHAO Ying, XING Xiaoling, JU Xuehai. Decomposition Mechanism of 5,5'-Bis(tetrazole)-1,1'-diolate(TKX-50) Anion Initiated by Intramolecular Oxygen Transfer [J]. Chemical Research in Chinese Universities, 2019, 35(3): 485-489.
[10]	HAN Donglai, LI Boxun, XING Guoliang, ZHANG Yuanyuan, CHEN Yue, SUN Yantao, ZHANG Yongjun, LIU Yang, YANG Jinghai. Facile Synthesis of Fe₃Pt-Ag Nanocomposites for Catalytic Reduction of Methyl Orange [J]. Chemical Research in Chinese Universities, 2018, 34(6): 871-876.
[11]	ZHANG Jiaqi, WANG Shan, YUAN Long, HOU Changmin. Hydrothermal Synthesis and Magnetic Properties ofSmCr_0.5M_0.5O₃(M=Fe and Mn) Micro-plates [J]. Chemical Research in Chinese Universities, 2018, 34(1): 1-7.
[12]	WU Jie, YUAN Long, WANG Shan, HOU Changmin. Nd_3-xAE_xFe₅O₁₂:Hydrothermal Synthesis, Structure and Magnetic Properties [J]. Chemical Research in Chinese Universities, 2017, 33(6): 869-875.
[13]	GUO Ximing, GUO Bin. Preparation of Fe₃O₄-porphyrin Nano-composited Particles and Their Optical and Magnetic Properties [J]. Chemical Research in Chinese Universities, 2017, 33(4): 530-533.
[14]	JIAO Qingze, WANG Yanfeng, HAO Liang, LI Hansheng, ZHAO Yun. Synthesis of Magnetic Nickel Ferrite Microspheres and Their Microwave Absorbing Properties [J]. Chemical Research in Chinese Universities, 2016, 32(4): 678-681.
[15]	SUN Xinyuan, DING Yiming, WEN Xiaoling, OUYANG Jianming. Differences in Adsorption of Anionic Surfactant AOT by Calcium Oxalate: Effect of Crystal Size and Crystalline Phase [J]. Chemical Research in Chinese Universities, 2016, 32(4): 682-688.