Three New Polyoxometalates Derivatives Decorated by Phenanthroline and Transition-metal Cations(M=ZnII, CoII, NiII)

Chemical Research in Chinese Universities ›› 2010, Vol. 26 ›› Issue (5): 683-686.

• Articles • Previous Articles Next Articles

Three New Polyoxometalates Derivatives Decorated by Phenanthroline and Transition-metal Cations(M=ZnII, CoII, NiII)

ZHANG Yong-feng, JIA Yan-yan, NIE Hai-liang, YAN Xing-juan, WANG Li and HUANG Ru-dan*

Department of Chemistry, Beijing Institute of Technology, Beijing 100081, P. R. China

Received:2009-10-29 Revised:2010-03-09 Online:2010-09-25 Published:2010-11-26
Contact: HUANG Ru-dan. E-mail: huangrd@bit.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.20771013, 20476011 and 20371007).

Abstract

Abstract: Three new Keggin polyoxometalates, [Zn(phen)3]2[SiW12O40]·5H2O(1), [Co(phen)3]2[SiW12O40](2) and [Ni(phen)3]2[SiW12O40]·2H2O(3)(phen=1,10'-phenanthroline) have been hydrothermally synthesized and characterized by elemental analysis, IR, crystal X-ray diffraction, thermogravimetric analyses(TGA) and fluorescence techniques. Complex 1, crystallized in the triclinic space group P1??, consists of one [SiW12O40]4– anion, two discrete [Zn(phen)3]2+ cations and five crystal water molecules. Complexes 2 and 3 have the similar configuration to complex 1, but they crystallized in the monoclinic space group C2/c. Variable-temperature magnetic susceptibilities of complexess 2 and 3 reveal antiferromagnetism and ferromagnetism, respectively.

Key words: Polyoxometalate, Phen, Organic-inorganic compound, Hydrothermal synthesis

ZHANG Yong-feng, JIA Yan-yan, NIE Hai-liang, YAN Xing-juan, WANG Li and HUANG Ru-dan*. Three New Polyoxometalates Derivatives Decorated by Phenanthroline and Transition-metal Cations(M=ZnII, CoII, NiII)[J]. Chemical Research in Chinese Universities, 2010, 26(5): 683-686.

References

[1] Yaghi O. M., Li H., J. Am. Chem. Soc., 1996, 118, 295 [2] Hagrman D., Haushalter R. C., Zubieta J., Chem. Mater., 1998, 10, 361 [3] Cheetham A. K., Férey G., Loiseau T., Angew. Chem. Int. Ed., 1999, 38, 3268 [4] Peng Z. H., Angew. Chem. Int. Ed., 2004, 43, 930 [5] Hill C. L., Chem. Rev., 1998, 98, 1 [6] Ren Y. P., Kong X. J., Hu X. Y., Sun M., Long L. S., Huang R. B., Zheng L. S., Inorg. Chem., 2006, 45, 4016 [7] Niu J. Y., Wu Q., Wang J. P., J. Chem. Soc. Dalton Trans., 2002, 2512 [8] Lin Z. E., Zhang J., Zhao J. T., Zheng S. T., Pan C. Y., Wang G. M., Yang G. Y., Angew. Chem. Int. Ed., 2005, 44, 6881 [9] Sun Y. Q., Zhang J., Chen Y. M., Yang G. Y., Angew. Chem. Int. Ed., 2005, 44, 5814 [10] Zhang Z. M., Li Y. G., Wang Y. H., Qi Y. F., Wang E. B., Inorg. Chem., 2008, 47, 7615 [11] Bu X. H., Chen W., Du M., Biradha K., Wang W. Z., Zhang R. H., Inorg. Chem., 2002, 41, 437 [12] Hagrman P. J., Bridges C., Greedan J. E., Zubieta J., J. Chem. Soc. Dalton Trans., 1999, 2901 [13] Lu J., Shen E. H., Yuan M., Li Y. G., Wang E. B., Hu C. W., Xu L. Peng J., Inorg. Chem., 2003, 42, 6956 [14] Lu Y., Wang E. B., Yuan M., Luan G. Y., Li Y. G., Zhang H., Hu C. W., Yao Y. G., Qin Y. Y., Chen Y. B., J. Chem. Soc. Dalton Trans., 2002, 3029 [15] Sheldrick G. M., SHELXS 97, Program for Crystal Structure Solution, University of G?ttingen, G?ttingen, 1997 [16] Sheldrick G. M., SHELXL 97, Program for Crystal Structure Refinement, University of G?ttingen, G?ttingen, 1997 [17] Pope M. T., Müller A., Polyoxometalate Chemistry From Topology via Self-Assembly to Applications, Kluwer Academic Publishers, Dordrecht, 2001, 301 [18] Yu L. Q., Huang R. D., Xu Y. Q., Liu T. F., Chu W., Hu C. W., Inorganica Chimica Acta., 2008, 361, 2120 [19] King P., Clérac R., Wernsdorfer W., Anson C. E., Powell A. K., Dalton Trans, 2004, 2670 [20] Fondo M., Ocampo N., García-Deibe A. M., Vicente R., Corbella M., Bermejo M. R., Sanmartin J., Inorg. Chem., 2006, 45, 255 [21] Mbomekalle I. M., Keita B., Nierlich M., Kortzu U., Berthet P., Nadjo L., Inorg. Chem., 2003, 42, 5143

Three New Polyoxometalates Derivatives Decorated by Phenanthroline and Transition-metal Cations(M=ZnII, CoII, NiII)

PDF (PC)

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	ZHENG Xuelian, LIU Ling, YANG Cuicui, HE Yuanyuan, CHEN Jiu, TIAN Wei Quan. Modulation of the Second Order Nonlinear Optical Properties of Helical Graphene Nanoribbons Through Introducing Azulene Defects or/and BN Units [J]. Chemical Research in Chinese Universities, 2022, 38(4): 974-984.
[2]	LI Hongxiang, WANG Sichun, LIU Xinyu, WU Fan, ZHANG Qiang, YUAN Jian, MA Wei, HAN Yanchun. Crystals Array via Oriented Nucleation and Growth Induced by Smectic E Mesophase of C7-T-BTBT [J]. Chemical Research in Chinese Universities, 2022, 38(4): 1041-1049.
[3]	ZHU Junlun, CUI Qian, WEN Wei, ZHANG Xiuhua, WANG Shengfu. Cu/CuO-Graphene Foam with Laccase-like Activity for Identification of Phenolic Compounds and Detection of Epinephrine [J]. Chemical Research in Chinese Universities, 2022, 38(4): 919-927.
[4]	GAO Wei, LI Yufeng, ZHAO Jitao, ZHANG Zhe, TANG Weiwei, WANG Jun, WU Zhenyu, LI Zhenyu. Design and Preparation of Graphene/Fe₂O₃ Nanocomposite as Negative Material for Supercapacitor [J]. Chemical Research in Chinese Universities, 2022, 38(4): 1097-1104.
[5]	CHANG Shunkai, LI Cuiyan, LI Hui, ZHU Liangkui, FANG Qianrong. Stable Thiophene-sulfur Covalent Organic Frameworks for Oxygen Reduction Reaction(ORR) [J]. Chemical Research in Chinese Universities, 2022, 38(2): 396-401.
[6]	Hakan, AHAL, Gülben TORĞUT, Erdal CANPOLAT. Optimization of Electrical Conductivity of SA-graphene Nanocomposites Using Response Surface Methodology [J]. Chemical Research in Chinese Universities, 2022, 38(2): 596-602.
[7]	CHEN Kaichun, ZHENG Xuelian, YANG Cuicui, TIAN Wei Quan, LI Weiqi, YANG Ling. Theoretical Studies on the Electronic Structure of Nano-graphenes for Applications in Nonlinear Optics [J]. Chemical Research in Chinese Universities, 2022, 38(2): 579-587.
[8]	XIAO Jiapeng, ZHANG Wenhui, ZHANG Shujing, LI Yu. Molecular Modification of Benzophenone Derivatives for Lower Bioenrichment and Toxicity Through the Pharmacophore Model [J]. Chemical Research in Chinese Universities, 2022, 38(2): 535-545.
[9]	Mohammad Javad TAGHIZADEH, Maryam Saleh MOHAMMADNIA, Masoumeh GHALKHANI, Esmail SOHOULI. Improved Method for the Total Synthesis of Azaperone and Investigation of Its Electrochemical Behavior in Aqueous Solution [J]. Chemical Research in Chinese Universities, 2022, 38(2): 546-551.
[10]	WANG Bingya, GUO Xiaomei, LIU Zuodong, WU Yongquan, HOU Ji-Ting. A Long-wavelength Emissive Phenothiazine Derived Fluorescent Probe for Detecting HOCl Upregulation in 5-FU Stimulated Living Cells [J]. Chemical Research in Chinese Universities, 2022, 38(2): 609-615.
[11]	ZHANG Yunzhe, DAI Weili, WU Guangjun, GUAN Naijia, LI Landong. Catalytic Hydration of Aromatic Alkynes to Ketones over H-MFI Zeolites [J]. Chemical Research in Chinese Universities, 2022, 38(1): 173-180.
[12]	RONG Xin, LU Xiuli, LU Tongbu. Three-dimensional Pyrenyl Graphdiyne Supported Pd Nanoparticle as an Efficient and Easily Recyclable Catalyst for Reduction of 4-Nitrophenol [J]. Chemical Research in Chinese Universities, 2021, 37(6): 1296-1300.
[13]	SONG Yang, TAO Lei, ZHANG Yanfang, PAN Jinbo, DU Shixuan. A DFT Investigation on the Electronic Structures and Au Adatom Assisted Hydrogenation of Graphene Nanoflake Array [J]. Chemical Research in Chinese Universities, 2021, 37(5): 1110-1115.
[14]	GUO Ruihua, QIAN Fei, AN Shengli, ZHANG Jieyu, CHOU Kuo-Chih, YE Jinyu, ZHOU Zhiyou. Effect of Acid Treatment on Electrocatalytic Performance of PtNi Catalyst [J]. Chemical Research in Chinese Universities, 2021, 37(3): 686-695.
[15]	LI Meng, WU Mingwei, PAN Biwei, XU Dandan, LVSONG Zhuopu, LI Dongqing, ZHANG Fangrong, HUANG Jun. Aerobic Oxidation of 2,3,6-Trimethylphenol with Reusable Homogenized Copper Catalysts [J]. Chemical Research in Chinese Universities, 2021, 37(3): 751-756.