Three-dimensional Pyrenyl Graphdiyne Supported Pd Nanoparticle as an Efficient and Easily Recyclable Catalyst for Reduction of 4-Nitrophenol

doi:10.1007/s40242-021-1323-z

Chemical Research in Chinese Universities ›› 2021, Vol. 37 ›› Issue (6): 1296-1300.doi: 10.1007/s40242-021-1323-z

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Three-dimensional Pyrenyl Graphdiyne Supported Pd Nanoparticle as an Efficient and Easily Recyclable Catalyst for Reduction of 4-Nitrophenol

RONG Xin, LU Xiuli, LU Tongbu

Institute for New Energy Materials & Low Carbon Technologies, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384, P. R. China

Received:2021-08-18 Revised:2021-09-30 Online:2021-11-23 Published:2021-11-23
Contact: LU Xiuli, LU Tongbu E-mail:luxiuli@email.tjut.edu.cn;lutongbu@tjut.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (Nos.21790052, 21805207, and 21931007) and the “111” Project of China (No.D17003).

Abstract

Abstract: The fabrication of highly active and easily recyclable Pd-based catalyst is meaningful for their practical application. Herein, a Pd-based dip-catalyst(Pd@Pyr-GDY) is fabricated on graphdiyne(Pyr-GDY) grown on copper foam, and applied in the reduction of nitroarenes. Specially, the as-formed Pd@Pyr-GDY shows good catalytic performance toward the reduction of 4-nitrophenol(4-NP) to 4-aminophenol(4-AP) by NaBH₄ with a rate constant k value of 3.84 min^-1, which is 12-fold higher than that of the commercial Pd/C. More importantly, Pd@Pyr-GDY could be easily and rapidly recovery from the reaction medium and no distinct inactivation was found after six cycles of the reaction. This work presents an easy way to design an efficient and easily recyclable Pd-based catalyst for practical use.

Key words: Pd-based catalyst, Dip-catalyst, Reduction of 4-nitrophenol, Recycling

RONG Xin, LU Xiuli, LU Tongbu. Three-dimensional Pyrenyl Graphdiyne Supported Pd Nanoparticle as an Efficient and Easily Recyclable Catalyst for Reduction of 4-Nitrophenol[J]. Chemical Research in Chinese Universities, 2021, 37(6): 1296-1300.

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Three-dimensional Pyrenyl Graphdiyne Supported Pd Nanoparticle as an Efficient and Easily Recyclable Catalyst for Reduction of 4-Nitrophenol

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