Fabrication and Photoelectrochemical Properties of [Ru(bpy)2dppz]2+ on ITO Electrode Associated with the Oxidation of Guanine

Abstract

Abstract: Electrochemical assembly of [Ru(bpy)₂dppz]²⁺{bpy=2,2′-bipyridine, dppz=dipyrido[3,2-a:2′,3′-c]phena- zine} on an ITO electrode in the presence of guanine and photoelectrochemical properties of the assembled layer were investigated. It has been found that [Ru(bpy)₂dppz]^3+/2+ can be assembled onto the ITO electrode by the method of repetitive voltammetric sweeping, and the assembly is enhanced by guanine. The peak currents of prewaves increase linearly up to a guanine concentration of 0.25 mmol/L. More importantly, upon illumination with 470 nm light source and at an applied potential of 0.2 V, cathodic current for the fabricated layer on the ITO electrode indicate a linear enhancement with the rise of guanine concentration. Meanwhile, [Ru(bpy)₂dppz]²⁺ can be served as an excellent mediator to prompt the oxidation of guanine, and the mediated peak current increases linearly with added guanine concentration from 0.01 to 0.25 mmol/L. In addition, the assembly mechanism of [Ru(bpy)₂dppz]²⁺ on the ITO electrode associated with the oxidation of guanine and the assistance of light irradiation were discussed.

Key words: Polypyridyl ruthenium(II) complex, Guanine, ITO, Assembly, Photoelectrochemistry

GUO Qing-yu, LI Hong*, YANG Hui-yi and SHAO Jiang-yang. Fabrication and Photoelectrochemical Properties of [Ru(bpy)₂dppz]²⁺ on ITO Electrode Associated with the Oxidation of Guanine[J]. Chemical Research in Chinese Universities, 2010, 26(4): 649-655.

References

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Fabrication and Photoelectrochemical Properties of [Ru(bpy)₂dppz]²⁺ on ITO Electrode Associated with the Oxidation of Guanine

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