Synthesis, Structure and Luminescence of Zn4.5Cu3 Heteronuclear Coordination Polymer Comprising Macrocyclic Oxamide and 5-Sulfosalicylic Ion

Abstract

Abstract: The complex [Zn_4.5(SSA)₃(CuL)₃(H₂O)₆]_n was synthesized and structurally determined, where SSA is fully deprotonated 5-sulfosalicylic acid(CuL, H₂L=2,3-dioxo-5,6,14,15-dibenzo-1,4,8,12-tetraazacyclo-pentadeca- 7,13-dien). The title complex crystallized in the triclinic system with space group P1, a=1.19788(17) nm, b=1.4253(2) nm, c=2.2890(4) nm, α=90.211(2)°, β=93.076(2)°, γ=90.600(2)°. The complex displayed a 1D ladderlike chain. All these 1D chains were further interlinked via hydrogen bonds, resulting in a 2D architecture. The luminescent property of the compound was also discussed.

Key words: Heteronuclear complex, Macrocyclic oxamide, Luminescence

SUN Ya-qiu*, WANG Jing, FAN Lan-lan and GAO Dong-zhao. Synthesis, Structure and Luminescence of Zn_4.5Cu₃ Heteronuclear Coordination Polymer Comprising Macrocyclic Oxamide and 5-Sulfosalicylic Ion[J]. Chemical Research in Chinese Universities, 2010, 26(4): 501-504.

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Synthesis, Structure and Luminescence of Zn_4.5Cu₃ Heteronuclear Coordination Polymer Comprising Macrocyclic Oxamide and 5-Sulfosalicylic Ion

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