Carbamate Synthesis from Aromatic Amines and Dimethyl Carbonate Using Lead Acetate as Catalyst

Chemical Research in Chinese Universities ›› 2006, Vol. 22 ›› Issue (5): 669-670.doi:

• Research Notes • Previous Articles

Carbamate Synthesis from Aromatic Amines and Dimethyl Carbonate Using Lead Acetate as Catalyst

KANG Wu-kui^1,2, WANG Gong-ying¹ and YAO Jie¹

1. Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041, P. R. China;
2. Graduate School of Chinese Academy of Sciences, Beijing 100039, P. R. China

Received:2005-09-07 Revised:1900-01-01 Online:2006-09-25 Published:2006-09-25
Contact: WANG Gong-ying E-mail:gywang@cioc.ac.cn

Abstract

Abstract: In this work, we attempted the carbonylation of each of the aromatic amines with dimethyl carbonate to synthesize carbamates. We found that lead acetate is a very good catalyst for this carbonylation.

Key words: Carbamate, Amine, Dimethyl carbonate, Lead acetate, Carbamate, Amine, Dimethyl carbonate, Leadacetate

KANG Wu-kui , WANG Gong-ying , YAO Jie . Carbamate Synthesis from Aromatic Amines and Dimethyl Carbonate Using Lead Acetate as Catalyst
[J]. Chemical Research in Chinese Universities, 2006, 22(5): 669-670.

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Carbamate Synthesis from Aromatic Amines and Dimethyl Carbonate Using Lead Acetate as Catalyst

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