Late-model Ionic Clusters of KNO3 and Their Configurations

Chemical Research in Chinese Universities ›› 2005, Vol. 21 ›› Issue (5): 587-591.

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Late-model Ionic Clusters of KNO3 and Their Configurations

SHI Lei^1,2, YANG Zhi², LIU Zhi-qiang², LIU Shu-ying²

1. School of Public Health, Jilin University, Changchun 130021, P. R. China;
2. Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China

Received:2004-10-29 Online:2005-09-23 Published:2011-08-06
Supported by:
Supported by the National Natural Science Foundation of China(No.20173057).

Abstract

Abstract: Late-model ionic clusters of KNO₃ were formed under the conditions of electrospray ionization. A series of peaks of the ionic clusters could be observed in the electrospray ionization mass spectra(ESIMS). The general formulae of the ionic clusters were deduced to be K⁺(KNO₃)_n and NO₃^-(KNO₃)_m. By referring to the crystal structure of KNO₃, the possible configurations of these new typical ionic clusters were speculated based on the calculated data by means of the Gaussian-94^x computer program.

Key words: Cluster, KNO₃, Configuration, Gaussian-94^* computer program

SHI Lei, YANG Zhi, LIU Zhi-qiang, LIU Shu-ying. Late-model Ionic Clusters of KNO3 and Their Configurations[J]. Chemical Research in Chinese Universities, 2005, 21(5): 587-591.

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Late-model Ionic Clusters of KNO3 and Their Configurations

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