Highly Efficient Synthesis of Au130(SPh-Br)50 Nanocluster

doi:10.1007/s40242-018-8027-z

Chemical Research in Chinese Universities ›› 2018, Vol. 34 ›› Issue (5): 719-722.doi: 10.1007/s40242-018-8027-z

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Highly Efficient Synthesis of Au₁₃₀(SPh-Br)₅₀ Nanocluster

REN Xiuqing^1,2, FU Xuemei^2,3, LIN Xinzhang^2,3, LIU Chao², HUANG Jiahui², YAN Jinghui¹

1. School of Chemistry & Environmental Engineering, Changchun University of Science and Technology, Changchun 130022, P. R. China;
2. Gold Catalysis Research Center, State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, P. R. China;
3. University of Chinese Academy of Sciences, Beijing 100049, P. R. China

Received:2018-01-25 Revised:2018-05-03 Online:2018-10-01 Published:2018-06-11
Contact: LIU Chao,Email:chaoliu@dicp.ac.cn;YAN Jinghui,Email:yjh@cust.edu.cn E-mail:chaoliu@dicp.ac.cn;yjh@cust.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(No.21601178) and the "Strategic Priority Research Program" of the Chinese Academy of Sciences(No.XDA09030103).

Abstract

Abstract: We reported the synthesis of Au₁₃₀(SPh-Br)₅₀(Br-Ph-SH=4-bromothiophenol) nanocluster with high purity and high yield via "size focusing" and "ligand exchange" processes. The time of synthetic process was significantly reduced compared with previous synthetic routine. Au₁₃₀(SPh-Br)₅₀ was determined by UV-Vis absorption spectroscopy and matrix-assisted laser desorption ionization(MALDI) mass spectroscopy. Thermo-gravimetric analysis (TGA) and size-exclusion chromatogram(SEC) analyses confirmed the purity of Au₁₃₀(SPh-Br)₅₀. The yield of gold nanoclusters was 20% (based on HAuCl₄).

Key words: Au₁₃₀, Gold nanocluster, Thiolate ligand

REN Xiuqing, FU Xuemei, LIN Xinzhang, LIU Chao, HUANG Jiahui, YAN Jinghui. Highly Efficient Synthesis of Au₁₃₀(SPh-Br)₅₀ Nanocluster[J]. Chemical Research in Chinese Universities, 2018, 34(5): 719-722.

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Highly Efficient Synthesis of Au₁₃₀(SPh-Br)₅₀ Nanocluster

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