Synthesis and Characterization of N-(2,3,4,6-Tetra-O-acetyl-β-D-glucopyranosyl)-thiocarbamic-4-hydroxy-benzoyl Hydrazine Dihydrate

Chemical Research in Chinese Universities ›› 2005, Vol. 21 ›› Issue (5): 545-548.

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Synthesis and Characterization of N-(2,3,4,6-Tetra-O-acetyl-β-D-glucopyranosyl)-thiocarbamic-4-hydroxy-benzoyl Hydrazine Dihydrate

ZHANG Shu-sheng, YE Su-juan, LI Xue-mei, GU Shan-shan, LIU Qing

College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, P. R. China

Received:2004-11-18 Online:2005-09-23 Published:2011-08-06
Supported by:
Supported by the Program for New Century Excellent Talents in Universities(No.NCET-04-0649) and the National Natural Science Foundation of China(Nos.20275020 and 20475030).

Abstract

Abstract: A new complex of N-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-thiocarbamic 4-hydroxy-benzoyl hydrazine dihydrate, C₂₂H₂₇N₃O₁₀S·2H₂O, was synthesized and its structure was determined by X-ray crystallography and TG/DTG methods. The compound belongs to the orthorhombic system, which crystallizes in space group P2₁2₁2₁, with a=1.0275(3), b=1.3419(4), c=2.0234(6), V=2.7899(16) nm³, and Z=4. The hexopyranosyl ring adopts a ^{4C₁ conformation. All the substituents are at equatorial positions. The molecules are linked into a three-dimensional framework via intermolecular interactions. Atoms O5 and O9 show positional disorders.}

Key words: N-(2,3,4,6-Tetra-O-acetyl-β-D-glucopyranose, Synthesis, Crystal structure, Characterization

ZHANG Shu-sheng, YE Su-juan, LI Xue-mei, GU Shan-shan, LIU Qing. Synthesis and Characterization of N-(2,3,4,6-Tetra-O-acetyl-β-D-glucopyranosyl)-thiocarbamic-4-hydroxy-benzoyl Hydrazine Dihydrate[J]. Chemical Research in Chinese Universities, 2005, 21(5): 545-548.

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Synthesis and Characterization of N-(2,3,4,6-Tetra-O-acetyl-β-D-glucopyranosyl)-thiocarbamic-4-hydroxy-benzoyl Hydrazine Dihydrate

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