Synthesis, Structure Characterization and Biological Activity of Layered Vanadium Oxides [NH3(CH2)2NH(CH2)2NH3][V6O14]

Chemical Research in Chinese Universities ›› 2005, Vol. 21 ›› Issue (5): 509-511.

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Synthesis, Structure Characterization and Biological Activity of Layered Vanadium Oxides [NH₃(CH₂)₂NH(CH₂)₂NH₃][V₆O₁₄]

FU Ping-ping^1,2, WANG Xin-long¹, WANG En-bo¹, QIN Chao¹, XU Lin¹

1. Institute of Polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun 130024, P. R. China;
2. China-Japan Union Hospital, Jilin University, Changchun 130024, P. R. China

Received:2004-12-30 Online:2005-09-23 Published:2011-08-06
Supported by:
Supported by the National Natural Science Foundation of China(No.20171010).

Abstract

Abstract: A new layered vanadium oxide [NH₃(CH₂)₂NH(CH₂)₂NH₃][V₆O₁₄](compound 1) was synthesized and characterized by elemental analysis, IR spectrometry and single crystal X ray diffraction. The compound crystallizes in a monoclinic space group P2(1)/n with a=1.0254(2) nm, b=0.6739(2) nm, c=1.2400(2) nm, β=93.88(3)°, V=0.8549(3) nm³, Z=2, R₁=0.0366, wR₂=0.1038. Compound 1 consists of two-dimensional mixed-valence vanadium oxide layers parallelling to the bc plane. The anti-tumor activity of the compound was estimated in three human tumor cell lines in vitro.

Key words: Polyoxometalate, Vanadium oxide, Crystal structure, Anti-tumor activity

FU Ping-ping, WANG Xin-long, WANG En-bo, QIN Chao, XU Lin. Synthesis, Structure Characterization and Biological Activity of Layered Vanadium Oxides [NH₃(CH₂)₂NH(CH₂)₂NH₃][V₆O₁₄][J]. Chemical Research in Chinese Universities, 2005, 21(5): 509-511.

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Synthesis, Structure Characterization and Biological Activity of Layered Vanadium Oxides [NH₃(CH₂)₂NH(CH₂)₂NH₃][V₆O₁₄]

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