Transformation of 1-D Chiral-chained Titanium Phosphate to 2-D Layer Structure Through a 1-D Zigzag Chain

Abstract

Abstract: The transformation of titanium phosphate from 1-D chiral- chain(JTP-A) to 2-D layer(TP-J1) has been carefully investigated. Through a hydrolysis-condensation self-assembly pathway, the crystals of TP-J1 can be obtained from the JTP-A phase under hydrothermal conditions. An intermediate material with zigzag chain during the transformation was observed by XRD characterization. A hypothesis of the transformation mechanism is also described in this article. It is noteworthy that ethylenediamine plays an important role in the transformation.

Key words: Transformation, Titanium phosphate, Mechanism, Rational design

CHEN Chao, YANG Yu-lin, LI Wei-sheng, LIU Yun-ling, YI Zhuo, GUO Yang-hong, PANG Wen-qin. Transformation of 1-D Chiral-chained Titanium Phosphate to 2-D Layer Structure Through a 1-D Zigzag Chain[J]. Chemical Research in Chinese Universities, 2005, 21(4): 411-414.

References

[1] Cheetham A. K., Férey G., Loiseau T., Angew. Chem. Int. Ed., 1999, 38, 3268 [2] Zhang D., Shi Z., Feng S. H., Chem. Res. Chinese Universities, 2001, 17(3), 249 [3] Feng S. H., Xu R. R., Acc. Chem. Res., 2001, 34, 239 [4] Meng H., Xing Y., Fu Y. L., et al., Chem. Res. Chinese Universities, 2004, 20(1), 1 [5] Oliver S., Kuperman A., Ozin G. A., Angew. Chem. Int. Ed., 1998, 37, 47 [6] Férey G., Chem. Mater., 2001, 13, 3084 [7] Férey G., J. Solid State Chem., 2000, 152, 37 [8] Serre C., Tanlelle F., Férey G., Chem. Commun., 2003, 2755 [9] Rao C. N. R., Natarajan S., Choudhury A., et al., Acc. Chem. Res., 2001, 34, 80 [10] Choudhury, A., Neeraj S., Natarajan S., et al., J. Mater. Chem., 2002, 12, 1044 [11] Choudhury A., Rao C. N. R., Chem. Commun., 2003, 366 [12] Jiao X. L., Chen D. R., Pang W. Q., et al., J. Mater. Chem., 1998, 8, 2831 [13] Christensen A. N., Andersen E. K., Andersen I. G. K., et al., Acta Chem. Scand., 1990, 44, 865 [14] Stuky G. D., Phillips M. L. F., Gier T. E., Chem. Mater., 1989, 1, 492 [15] Phillips M. L. F., Harrison W. T. A., Stuky G. D., et al., Chem. Mater., 1992, 4, 222 [16] Ekambaram S., Sevov S. C., Angew. Chem. Int. Ed., 1999, 38, 372 [17] Ekambaram S., Serre C., Férey G., et al., Chem. Mater., 2000, 12, 444 [18] Serre C., Férey G., J. Mater. Chem., 1999, 9, 579 [19] Serre C., Taulelle F., Férey G., Chem. Mater., 2002, 14, 998 [20] Liu Y. L., Shi Z., Zhang L. R., et al., Chem. Mater., 2001, 13, 2017 [21] Liu Y. L., Shi Z., Zhang L. R., et al., Chem. Mater., 2002, 14, 1555 [22] Fu Y. L., Liu Y. L., Shi Z., et al., J. Solid State Chem., 2001, 162, 96 [23] Guo Y. H., Shi Z., Yu J. H., et al., Chem. Mater., 2001, 13, 203 [24] Zhao Y. N., Zhu G. S., Jiao X. L., et al., J. Mater. Chem., 2000, 10, 463 [25] Guo Y. H., Shi Z., Ding H., et al., Chinese Chemical Letters, 2001, 12, 373