Hydrothermal Synthesis and Crystal Structure of a Highly Reduced Mixed Molybdenum-vanadium Polyoxometalate with Phosphorus-centered [Ni(phen)3]2H2·[Pmo4ⅤMo4ⅥV6ⅣM2M44]5-·4H2O(M=0.78MoⅤ+0.22VⅣ)

Chemical Research in Chinese Universities ›› 2005, Vol. 21 ›› Issue (3): 368-371.

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Hydrothermal Synthesis and Crystal Structure of a Highly Reduced Mixed Molybdenum-vanadium Polyoxometalate with Phosphorus-centered [Ni(phen)₃]2H₂·[Pmo₄^ⅤMo₄^ⅥV₆^ⅣM₂M₄₄]^5-·4H₂O(M=0.78Mo^Ⅴ+0.22V^Ⅳ)

SUN Ying-hua^1,2, DING Hong¹, XU Ji-qing¹, LI Yong¹, LI Guang-hua¹

1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130023, P. R. China;
2. Department of Chemistry, Baicheng Teacher′s College, Baicheng 137000, P. R. China

Received:2004-11-04 Online:2005-05-24 Published:2011-08-06
Supported by:
Supported by the State Key Basic Research Program of China(No.2001CB108906), the National Natural Science Foundation of China(Nos.20271021 and 20333070).

Abstract

SUN Ying-hua, DING Hong, XU Ji-qing, LI Yong, LI Guang-hua. Hydrothermal Synthesis and Crystal Structure of a Highly Reduced Mixed Molybdenum-vanadium Polyoxometalate with Phosphorus-centered [Ni(phen)₃]2H₂·[Pmo₄^ⅤMo₄^ⅥV₆^ⅣM₂M₄₄]^5-·4H₂O(M=0.78Mo^Ⅴ+0.22V^Ⅳ)[J]. Chemical Research in Chinese Universities, 2005, 21(3): 368-371.

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Hydrothermal Synthesis and Crystal Structure of a Highly Reduced Mixed Molybdenum-vanadium Polyoxometalate with Phosphorus-centered [Ni(phen)₃]2H₂·[Pmo₄^ⅤMo₄^ⅥV₆^ⅣM₂M₄₄]^5-·4H₂O(M=0.78Mo^Ⅴ+0.22V^Ⅳ)

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