Syntheses, Confirmation and Properties of Porphyrin Oligomers with Alkoxyl Linkages

Abstract

Abstract: A new and general synthesis of a porphyrinK(Ⅰ) with two alkoxyl linkages is described. The synthesis involves the reaction of dibromopropane with phenolic porphyrin to form ω-bromopropylporphyrin ether. This ether then reacts with another phenolic porphyrin to give the target compounds. The properties of the target compounds were confirmed by means of elemental analysis, UV-Vis, IR, and ¹H NMR spectroscopies. Their spectral properties and thermal stability were also studied.

Key words: Synthesis, Characterization, Porphyrin oligomers, Alkoxyl linkages

LI Xiang-qing, SHI Ying-yan, YU Lian-xiang, WANG Xing-qiao, LIU Guo-fa. Syntheses, Confirmation and Properties of Porphyrin Oligomers with Alkoxyl Linkages[J]. Chemical Research in Chinese Universities, 2005, 21(3): 253-257.

References

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