Polymerization of n-Hexyl Isocyanate Initiated by Novel Rare Earth Tris (2,6-di-tert-butyl-4-methylphenolate)

Chemical Research in Chinese Universities ›› 2005, Vol. 21 ›› Issue (2): 224-226.

• Articles • Previous Articles Next Articles

Polymerization of n-Hexyl Isocyanate Initiated by Novel Rare Earth Tris (2,6-di-tert-butyl-4-methylphenolate)

XU Xiao-yan, NI Xu-feng, XU Hong, SHEN Zhi-quan

Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, P. R. China

Received:2004-01-12 Online:2005-03-24 Published:2011-07-27
Supported by:
Supported by the Special Funds for Major Basic Research Projects(No.1999064801) and the National Natural Science Foundation of China (No.20074029, 20304011).

Abstract

Abstract: The polymerization of n-hexyl isocyanate(HNCO) was carried out in the presence of a novel single initiator, rare earth tris (2,6-di-tert-butyl-4-methylphenolate) [Ln (OAr)₃].The influences of reaction conditions such as the monomer concentration, the polymerization temperature and time, and the types of solvents on the polymerization of HNCO were studied.Polymerizations of phenyl, i-propyl, p-tolyl, n-butyl and n-octyl isocyanates with La(OAr)₃ were also examined.

Key words: n-Hexyl isocyanate, Polymerization, Rare earth tris (2,6-di-tert-butyl-4-methylphenolate)

XU Xiao-yan, NI Xu-feng, XU Hong, SHEN Zhi-quan. Polymerization of n-Hexyl Isocyanate Initiated by Novel Rare Earth Tris (2,6-di-tert-butyl-4-methylphenolate)[J]. Chemical Research in Chinese Universities, 2005, 21(2): 224-226.

[1]	GONG Li, ZHU Yuzhang, DONG Dianyu, ZHANG Yuping, GUI Liangliang, and JIN Jian. Polyamide Nanofiltration Membrane from Surfactant-assembly Regulated Interfacial Polymerization of 2-Methylpiperazine for Divalent Cations Removal [J]. Chemical Research in Chinese Universities, 2022, 38(3): 782-789.
[2]	NIU Junfeng, SUN Haiya, XIA Housheng, ZHU Yinbang, CHEN Jialing, ZHU Chengye, BAI Wei. Visualization of Bulk Polymerization by Fluorescent Probe with Aggregation-induced Emission Characteristics [J]. Chemical Research in Chinese Universities, 2022, 38(2): 500-504.
[3]	BIAN Xiangying, ZHANG Yuping, GONG Li, ZHU Yuzhang, JIN Jian. Calcium Ion Coordinated Polyamide Nanofiltration Membrane for Ultrahigh Perm-selectivity Desalination [J]. Chemical Research in Chinese Universities, 2021, 37(5): 1101-1109.
[4]	WANG Wen-Peng, ZHANG Juan, LI Xue-Ting, YIN Ya-Xia, XIN Sen, GUO Yu-Guo. Stabilizing the Electrochemistry of Lithium-Selenium Battery via In situ Gelated Polymer Electrolyte: A Look from Anode [J]. Chemical Research in Chinese Universities, 2021, 37(2): 298-303.
[5]	LIU Jie, CHEN Bo, ZHANG Jianjun. Preparation of pH-Responsive Doxorubicin Nanocapsules by Combining High-gravity Antisolvent Precipitation with In-situ Polymerization for Intracellular Anticancer Drug Delivery [J]. Chemical Research in Chinese Universities, 2020, 36(5): 927-933.
[6]	WANG Yanli, TAN Dexin. Synthesis, Thermal Degradation and Dielectric Properties of Poly[octyl(triphenylethynyl)]silane Resin [J]. Chemical Research in Chinese Universities, 2019, 35(6): 1076-1081.
[7]	YIN Meng, ZHANG Zhiqiang, XIONG Yujie, LIU Min, ZHANG Yan, MI Puke. Ethylene/1-Hexene Copolymerization with Modified Ziegler-Natta Catalyst [J]. Chemical Research in Chinese Universities, 2019, 35(6): 1089-1094.
[8]	WANG Ying, WANG Qiliao, HOU Liman, ZHOU Mingdong, DONG Dewen, ZHANG Ning. Functionalized Polyphosphoester via Living Ring-opening Polymerization and Photochemical Thiol-ene Click Reaction [J]. Chemical Research in Chinese Universities, 2019, 35(2): 340-344.
[9]	QIAO Yaping, YUAN Xiaoyan, ZHAO Yunhui, REN Lixia. Ceiling Degree of Polymerization for Brush Polymers Prepared via ROMP of Poly(tert-Butyl Acrylate) Macromonomers [J]. Chemical Research in Chinese Universities, 2018, 34(5): 828-832.
[10]	JIANG Tiechao, FAN Qingqiu, HUANG Chunying, LI Zhen, GUO Lijie, ZHOU Bing. Mechanical and Thermal Properties of Waterborne Polyurethane Films Modified by CaCO₃@TiO₂ Particles with UV Absorption Activity [J]. Chemical Research in Chinese Universities, 2017, 33(6): 1007-1011.
[11]	MA Yanhong, JIANG Yan, LIANG Yuan, ZHANG Weiwei, ZHANG Hongwen, ZHANG Rong. Preparation and Biocompatibility of Polyester Films Grafted with Functional mPEG Copolymers [J]. Chemical Research in Chinese Universities, 2017, 33(5): 847-852.
[12]	LIU Can, OUYANG Kunbing, YANG Nianfa. Synthesis of a Newly Modified Poly-H₈-BINOL Ligand and Its Applications in the Asymmetric Addition of Triethylaluminium to Aromatic Aldehydes [J]. Chemical Research in Chinese Universities, 2017, 33(5): 742-745.
[13]	YOU Aimei, CAO Yuhua, CAO Guangqun. Facile and Convenient Fabrication of Color-controlled Colloidal Magnetically Assembled Photonic Crystals [J]. Chemical Research in Chinese Universities, 2017, 33(4): 525-529.
[14]	LIU Bo, QIAO Wenqiang, WANG Zhi Yuan. Intense Near- and Mid-infrared Absorbing Films of Electrochemically Crosslinked Multinuclear Metallodithiolene Complex Polymers [J]. Chemical Research in Chinese Universities, 2016, 32(2): 296-301.
[15]	JIANG Yan, SUN Xu, LI Bin, REN Xiaojun, ZHANG Hongwen, ZHANG Rong. Synthesis and Characterization of Monodisperse Emulsion Copolymer [J]. Chemical Research in Chinese Universities, 2016, 32(1): 134-139.

Polymerization of n-Hexyl Isocyanate Initiated by Novel Rare Earth Tris (2,6-di-tert-butyl-4-methylphenolate)

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments